English

Metal to insulator quantum-phase transition in few-layered ReS$_2$

Mesoscale and Nanoscale Physics 2016-01-20 v1

Abstract

In ReS2_2 a layer-independent direct band-gap of 1.5 eV implies a potential for its use in optoelectronic applications. ReS2_2 crystallizes in the 1T^{\prime}-structure which leads to anisotropic physical properties and whose concomitant electronic structure might host a non-trivial topology. Here, we report an overall evaluation of the anisotropic Raman response and the transport properties of few-layered ReS2_2 field-effect transistors. We find that ReS2_2 exfoliated on SiO2_2 behaves as an nn-type semiconductor with an intrinsic carrier mobility surpassing μi\mu_i ~30 cm2^2/Vs at T=300T = 300 K which increases up to ~350 cm2^2/Vs at 2 K. Semiconducting behavior is observed at low electron densities nn, but at high values of n the resistivity decreases by a factor > 7 upon cooling to 2 K and displays a metallic T2T^2-dependence. This indicates that the band structure of 1T^{\prime}-ReS2_2 is quite susceptible to an electric field applied perpendicularly to the layers. The electric-field induced metallic state observed in transition metal dichalcogenides was recently claimed to result from a percolation type of transition. Instead, through a scaling analysis of the conductivity as a function of TT and nn, we find that the metallic state of ReS2_2 results from a second-order metal to insulator transition driven by electronic correlations. This gate-induced metallic state offers an alternative to phase engineering for producing ohmic contacts and metallic interconnects in devices based on transition metal dichalcogenides.

Keywords

Cite

@article{arxiv.1510.02128,
  title  = {Metal to insulator quantum-phase transition in few-layered ReS$_2$},
  author = {Nihar R. Pradhan and Amber McCreary and Daniel Rhodes and Zhengguang Lu and Simin Feng and Efstratios Manousakis and Dmitry Smirnov and Raju Namburu and Madan Dubey and Angela R. Hight Walker and Humberto Terrones and Mauricio Terrones and Vladimir Dobrosavljevic and Luis Balicas},
  journal= {arXiv preprint arXiv:1510.02128},
  year   = {2016}
}

Comments

25 pages, 5 figures