English

Criticality in confined ionic fluids

Statistical Mechanics 2009-11-07 v1 Soft Condensed Matter

Abstract

A theory of a confined two dimensional electrolyte is presented. The positive and negative ions, interacting by a 1/r1/r potential, are constrained to move on an interface separating two solvents with dielectric constants ϵ1\epsilon_1 and ϵ2\epsilon_2. It is shown that the Debye-H\"uckel type of theory predicts that the this 2d Coulomb fluid should undergo a phase separation into a coexisting liquid (high density) and gas (low density) phases. We argue, however, that the formation of polymer-like chains of alternating positive and negative ions can prevent this phase transition from taking place.

Keywords

Cite

@article{arxiv.cond-mat/0103036,
  title  = {Criticality in confined ionic fluids},
  author = {J. E. Flores-Mena and Marcia C. Barbosa and Yan Levin},
  journal= {arXiv preprint arXiv:cond-mat/0103036},
  year   = {2009}
}

Comments

RevTex, no figures, in press Phys. Rev. E