Simple Theory of Ionic Activity in Concentrated Electrolytes
Chemical Physics
2017-09-12 v1 Statistical Mechanics
Abstract
The Debye-H\" uckel formula for ionic activity coefficients is extended for concentrated solutions by solving a simple model of many-body Coulomb correlations and adding the Born solvation energy. Given the bulk permittivity, our formula is able to fit activity data for diverse electrolytes with only one parameter to adjust the correlation length, which interpolates between the Bjerrum length and the mean ion spacing. The results show that ionic activity in most electrolytes is dominated by three types of electrostatic forces: (i) mean-field charge screening, (ii) solvation, and (iii) Coulomb correlations, both "over-screening" (charge oscillations) and "under-screening" (extending beyond the Debye screening length).
Cite
@article{arxiv.1709.03106,
title = {Simple Theory of Ionic Activity in Concentrated Electrolytes},
author = {Sven Schlumpberger and Martin Z. Bazant},
journal= {arXiv preprint arXiv:1709.03106},
year = {2017}
}
Comments
5 pages, 3 figures