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A Trickiness of the High-Temperature Limit for Number Density Correlation Functions in Classical Coulomb Fluids

Statistical Mechanics 2009-11-13 v1

Abstract

The Debye-H\"uckel theory describes rigorously the thermal equilibrium of classical Coulomb fluids in the high-temperature β0\beta\to 0 regime (β\beta denotes the inverse temperature). It is generally believed that the Debye-H\"uckel theory and the systematic high-temperature expansion provide an adequate description also in the region of small {\em strictly positive} values of β>0\beta>0. This hypothesis is tested in the present paper on a two-dimensional Coulomb gas of pointlike +/+/- unit charges interacting via a logarithmic potential which is equivalent to an integrable sine-Gordon field model. In particular, we apply a form factor method to obtain the exact asymptotic large-distance behavior of particle correlation functions, considered in the charge and number density combinations. We first determine the general forms of the leading and subleading asymptotic terms at strictly positive β>0\beta>0 and then evaluate their high-temperature β0\beta\to 0 forms. In the case of the {\em charge} correlation function, the leading asymptotic term at a strictly positive β>0\beta>0 is also the leading one in the high-temperature β0\beta\to 0 regime. On the contrary, the β0\beta\to 0 behavior of the {\em number density} correlation function is accompanied by an interference between the first two asymptotic terms. Consequently, the large-distance behavior of this function exhibits a discontinuity when going from strictly positive values of β>0\beta>0 to the Debye-H\"uckel limit β0\beta\to 0. This is the crucial conclusion of the paper: the large-distance asymptotics and the high-temperature limit do not commute for the density correlation function of the two-dimensional Coulomb gas.

Keywords

Cite

@article{arxiv.0705.1406,
  title  = {A Trickiness of the High-Temperature Limit for Number Density Correlation Functions in Classical Coulomb Fluids},
  author = {L. Samaj},
  journal= {arXiv preprint arXiv:0705.1406},
  year   = {2009}
}

Comments

18 pages, to appear in J. Stat. Phys