English

Surface Tension of an Ideal Dielectric - Electrolyte Boundary: Exactly Solvable Model

Statistical Mechanics 2007-05-23 v1 High Energy Physics - Theory

Abstract

The model under consideration is a semi-infinite two-dimensional two-component plasma (Coulomb gas), stable against bulk collapse for the dimensionless coupling constant β<2\beta<2, in contact with a dielectric wall of dielectric constant =0=0. The model is mapped onto an integrable sine-Gordon theory with a ``free'' Neumann boundary condition. Using recent results on a reflection relationship between the boundary Liouville and sine-Gordon theories, an explicit expression is derived for the surface tension at a rectilinear dielectric -- Coulomb gas interface. This expression reproduces the Debye-H\"uckel β0\beta \to 0 limit and the exact result at the bulk collapse border, the free-fermion point β=2\beta =2, where the surface tension keeps a finite value. The surface collapse, identified with the divergence of the surface tension, occurs at β=3\beta =3.

Keywords

Cite

@article{arxiv.cond-mat/0101044,
  title  = {Surface Tension of an Ideal Dielectric - Electrolyte Boundary: Exactly Solvable Model},
  author = {L. Šamaj},
  journal= {arXiv preprint arXiv:cond-mat/0101044},
  year   = {2007}
}

Comments

17 pages, Latex