Surface Tension of an Ideal Dielectric - Electrolyte Boundary: Exactly Solvable Model
Abstract
The model under consideration is a semi-infinite two-dimensional two-component plasma (Coulomb gas), stable against bulk collapse for the dimensionless coupling constant , in contact with a dielectric wall of dielectric constant . The model is mapped onto an integrable sine-Gordon theory with a ``free'' Neumann boundary condition. Using recent results on a reflection relationship between the boundary Liouville and sine-Gordon theories, an explicit expression is derived for the surface tension at a rectilinear dielectric -- Coulomb gas interface. This expression reproduces the Debye-H\"uckel limit and the exact result at the bulk collapse border, the free-fermion point , where the surface tension keeps a finite value. The surface collapse, identified with the divergence of the surface tension, occurs at .
Cite
@article{arxiv.cond-mat/0101044,
title = {Surface Tension of an Ideal Dielectric - Electrolyte Boundary: Exactly Solvable Model},
author = {L. Šamaj},
journal= {arXiv preprint arXiv:cond-mat/0101044},
year = {2007}
}
Comments
17 pages, Latex