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Coherence among rotational ion channels during photoionization is exploited to control the anisotropy of the resulting photoelectron angular distributions at specific photoelectron energies. The strategy refers to a robust and single…

化学物理 · 物理学 2019-09-11 R. Chamakhi , M. Telmini , O. Atabek , E. Charron

Photoelectron spectroscopy is a powerful method that provides insight into the quantum mechanical properties of a wide range of systems. The ionized electron wavefunction carries information on the structure of the bound orbital, the ionic…

Photoelectron spectroscopy in intense laser fields has proven to be a powerful tool for providing detailed insights into molecular structure. The ionizing molecular orbital, however, has not been reconstructed from the photoelectron…

原子物理 · 物理学 2023-04-14 XuanYang Lai , RenPing Sun , ShaoGang Yu , YanLan Wang , Wei Quan , André Staudte , XiaoJun Liu

Amplitude and phase of wavepackets encode the dynamics of quantum systems. However, the rapidity of electron dynamics on the attosecond timescale has precluded their complete measurement in the time domain. Here, we demonstrate that…

We demonstrate the breakdown of molecular-frame dynamics induced by the uncoupling of molecular rotation from electronic motion in molecular Rydberg states. We observe this non-Born-Oppenheimer regime in the time domain through…

原子与分子团簇 · 物理学 2017-07-05 Lucas J. Zipp , Adi Natan , Philip H. Bucksbaum

Realistic attosecond wave packets have complex profiles that, in dispersive conditions, rapidly broaden or split into multiple components. Such behaviors are encoded in sharp features of the wave packet spectral phase. Here, we exploit the…

Recently we reported a series of numerical simulations proving that it is possible in principle to create an electronic wave packet and subsequent electronic motion in a neutral molecule photoexcited by a UV pump pulse within a few…

原子与分子团簇 · 物理学 2016-10-24 P. Decleva , N. Quadri , A. Perveaux , D. Lauvergnat , F. Gatti , B. Lasorne , G. J. Halász , Á. Vibók

The scattering phase shift of an electron transferred through a quantum dot is studied within a model Hamiltonian, accounting for both the electron--electron interaction in the dot and a finite temperature. It is shown that, unlike in an…

凝聚态物理 · 物理学 2009-10-28 Yuval Oreg , Yuval Gefen

In a double-slit experiment with a bipartite system, the visibility of interference fringes depends on the availability of which-way information. Here, we report the formation of a Bell-like state of photoelectron and residual ion in the…

Pairs of photons entangled in their time-frequency degree of freedom are of great interest in quantum optics research and applications, due to their relative ease of generation and their high capacity for encoding information. Here we…

量子物理 · 物理学 2022-02-23 Sofiane Merkouche , Valérian Thiel , Brian J. Smith

Autoionization, which results from the interference between direct photoionization and photoexcitation to a discrete state decaying to the continuum by configuration interaction, is a well known example of the important role of electron…

Shape resonances in physics and chemistry arise from the spatial confinement of a particle by a potential barrier. In molecular photoionization, these barriers prevent the electron from escaping instantaneously, so that nuclei may move and…

Imaging in real time the complete dynamics of a process as fundamental as photoemission has long been out of reach due to the difficulty of combining attosecond temporal resolution with fine spectral and angular resolutions. Here, we…

The interference of matter waves is one of the intriguing features of quantum mechanics that has impressed researchers and laymen since it was first suggested almost a century ago. Nowadays, attosecond science tools allow us to utilize it…

化学物理 · 物理学 2021-11-03 Kasra Amini , Alexis Chacón , Sebastian Eckart , Benjamin Fetić , Matthias Kübel

We propose an imaging technique to follow core-hole wave-packet oscillations in the nitrogen molecule. In this scheme, an attosecond x-ray pulse core-ionizes the nitrogen molecule and a subsequent attosecond x-ray pulse probes the evolution…

化学物理 · 物理学 2019-08-15 Ludger Inhester , Loren Greenman , Artem Rudenko , Daniel Rolles , Robin Santra

Attosecond photoionisation time delays reveal information about the potential energy landscape an outgoing electron wavepacket probes upon ionisation. In this study we experimentally quantify, for the first time, the dependence of the time…

Quantum phase is not a direct observable and is usually determined by interferometric methods. We present a method to map complete electron wave functions, including internal quantum phase information, from measured single-state probability…

介观与纳米尺度物理 · 物理学 2008-03-19 Christopher R. Moon , Laila S. Mattos , Brian K. Foster , Gabriel Zeltzer , Wonhee Ko , Hari C. Manoharan

The electronic wavefunction is at the heart of physical phenomena, defining the frontiers of quantum materials research. While the amplitude of the electron wavefunction in crystals can be measured with state-of-the-art probes in…

The development of attosecond technology has enabled the real-time observation of coherent electron motion in atoms, molecules and condensed phases. Experimentally, it is now possible to generate laser pulses of durations of only a few tens…

化学物理 · 物理学 2017-05-18 David Ayuso

We analytically model a one-dimensional lattice with periodic impurities representing a photonic crystal from first principles. We then investigate bound states in the continuum by computing the transmission and reflection coefficients. It…

量子物理 · 物理学 2024-10-10 Benjamin Rempfer , Gonzalo Ordonez
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