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The dynamics of vibrational wave packets excited in K$_2$ dimers attached to superfluid helium nanodroplets is investigated by means of femtosecond pump-probe spectroscopy. The employed resonant three-photon-ionization scheme is studied in…

原子与分子团簇 · 物理学 2009-11-11 P. Claas , G. Droppelmann , C. P. Schulz , M. Mudrich , F. Stienkemeier

The dynamics of vibrational wave packets in triplet states of rubidium dimers (Rb2) formed on helium nanodroplets are studied using femtosecond pump-probe photoionization spectroscopy. Due to fast desorption of the excited Rb2 molecules off…

原子与分子团簇 · 物理学 2011-12-19 M. Mudrich , Ph. Heister , T. Hippler , Ch. Giese , O. Dulieu , F. Stienkemeier

Femtosecond pump-probe spectroscopy has been used to study vibrational dynamics of potassium dimers attached to superfluid helium nanodroplets. Comparing the measured data with theoretical results based on dissipative quantum dynamics we…

原子与分子团簇 · 物理学 2009-09-28 Martin Schlesinger , Marcel Mudrich , Frank Stienkemeier , Walter T. Strunz

In this article, recent developments in HElium NanoDroplet Isolation (HENDI) spectroscopy are reviewed, with an emphasis on the infrared region of the spectrum. Topics discussed include experimental details, comparison of radiation sources,…

化学物理 · 物理学 2009-11-07 Carlo Callegari , Kevin K. Lehmann , Roman Schmied , Giacinto Scoles

The vibrational wave-packet dynamics of diatomic rubidium molecules (Rb2) in triplet states formed on the surface of superfluid helium nanodroplets is investigated both experimentally and theoretically. Detailed comparison of experimental…

We thoroughly investigate vibrational quantum dynamics of dimers attached to He droplets motivated by recent measurements with K-2 [1]. For those femtosecond pump-probe experiments, crucial observed features are not reproduced by gas phase…

化学物理 · 物理学 2012-03-15 Martin Schlesinger , Walter. T. Strunz

The desorption of excited rubidium (Rb) atoms off the surface of helium (He) nanodroplets is studied in detail using femtosecond time-resolved photoion and photoelectron imaging spectroscopy in combination with quantum wave packet…

原子与分子团簇 · 物理学 2018-10-17 N. V. Dozmorov , J. von Vangerow , J. A. M. Fordyce , F. Stienkemeier , A. V. Baklanov , M. Mudrich

Superfluid helium nanodroplets are often considered as transparent and chemically inert nanometer-sized cryo-matrices for high-resolution or time-resolved spectroscopy of embedded molecules and clusters. On the other hand, when the helium…

The relaxation dynamics of superexcited superfluid He nanodroplets is thoroughly investigated by means of extreme-ultraviolet (XUV) femtosecond electron and ion spectroscopy complemented by time-dependent density functional theory (TDDFT).…

This article provides a review of recent work in the field of helium nanodroplet spectroscopy with emphasis on the dynamical aspects of the interactions between molecules in helium as well as their interaction with this unique quantum…

化学物理 · 物理学 2009-11-11 Frank Stienkemeier , Kevin K Lehmann

Much of our knowledge about dynamics and functionality of molecular systems has been achieved with femtosecond time-resolved spectroscopy. Despite extensive technical developments over the past decades, some classes of systems have eluded…

化学物理 · 物理学 2020-03-25 Bernhard Thaler , Miriam Meyer , Pascal Heim , Markus Koch

The ionization dynamics of helium droplets in a wide size range from 220 to 10^6 He atoms irradiated with intense femtosecond extreme ultraviolet (XUV) pulses of 10^9 {\div} 10^{12} W/cm2 power density is investigated in detail by…

The predissociation dynamics of lithium iodide (LiI) in the first excited A-state is investigated for molecules in the gas phase and embedded in helium nanodroplets, using femtosecond pump-probe photoionization spectroscopy. In the gas…

The evolution of electron wavepackets determines the course of many physical and chemical phenomena and attosecond spectroscopy aims to measure and control such dynamics in real-time. Here, we investigate radial electron wavepacket motion…

原子物理 · 物理学 2015-09-04 Niranjan Shivaram , Xiao-Min Tong , Henry Timmers , Arvinder Sandhu

Highly excited states of rubidium (Rb) atoms attached to helium (He) nanodroplets are studied by two-photon ionization spectroscopy in combination with electron and ion imaging. Photoion spectra and angular distributions are in good…

原子与分子团簇 · 物理学 2017-08-23 L. Fechner , B. Gruener , A. Sieg , C. Callegari , F. Ancilotto , F. Stienkemeier , M. Mudrich

We provide a detailed quantum treatment of the spectral characteristics and of the dynamics of nondispersive two-electron wave packets along the periodically driven, collinear frozen planet configuration of helium. These highly correlated,…

原子物理 · 物理学 2009-11-07 Peter Schlagheck , Andreas Buchleitner

Two-component nanoplasmas generated by strong-field ionization of doped helium nanodroplets are studied in a pump-probe experiment using few-cycle laser pulses in combination with molecular dynamics simulations. High yields of helium ions…

Homo- and heteronuclear alkali quartet trimers of the type K_{3-n}Rb_{n} (n=0,1,2,3) formed on helium nanodroplets are probed by one-color femtosecond photoionization spectroscopy. The obtained requencies are assigned to vibrations in…

原子与分子团簇 · 物理学 2017-09-13 Christian Giese , Frank Stienkemeier , Marcel Mudrich , Andreas W. Hauser , Wolfgang E. Ernst

Recent work applying multidimentional coherent electronic spectroscopy at dilute samples in the gas phase is reviewed. The development of refined phase-cycling approaches with improved sensitivity has opened-up new opportunities to probe…

原子与分子团簇 · 物理学 2019-09-12 Lukas Bruder , Ulrich Bangert , Marcel Binz , Daniel Uhl , Frank Stienkemeier

The dynamics following the photoexcitation of Na and Li atoms located on the surface of helium nanodroplets has been investigated in a joint experimental and theoretical study. Photoelectron spectroscopy has revealed that excitation of the…

原子与分子团簇 · 物理学 2017-08-23 Alberto Hernando , Manuel Barranco , Martí Pi , Evgeniy Loginov , Marina Langlet , Marcel Drabbels
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