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Dynamic surface-enhanced Raman spectroscopy (SERS) is nowadays one of the most interesting applications of SERS, in particular for single molecule studies. In fact, it enables the study of real-time processes at the molecular level. This…

The review is devoted to explanation of SERS in terms of the dipole and quadrupole light-molecule interactions arising in surface fields strongly varying in space in the region of the strongly irregular surface roughness. The main SERS…

化学物理 · 物理学 2013-10-01 A. M. Polubotko

Single-molecule detection with chemical specificity is a powerful and much desired tool for biology, chemistry, physics, and sensing technologies. Surface-enhanced spectroscopies enable single molecule studies, yet reliable substrates of…

介观与纳米尺度物理 · 物理学 2008-02-22 D. R. Ward , N. K. Grady , C. S. Levin , N. J. Halas , Y. Wu , P. Nordlander , D. Natelson

Surface Enhanced Raman Spectroscopy (SERS) is a well-established technique for enhancing Raman signals. Recently photonic integrated circuits have been used, as an alternative to microscopy based excitation and collection, to probe SERS…

We report on the observation of the natural isotopic spread of carbon from single-molecule Surface Enhanced Raman Spectroscopy (SM-SERS). By choosing a dye molecule with a very localized Raman active vibration in a cyano bond (C$\equiv$N…

软凝聚态物质 · 物理学 2008-11-04 P. G. Etchegoin , E. C. Le Ru , M. Meyer

The interaction between molecules is commonly ignored in surface-enhanced Raman scattering (SERS). Under this assumption, the total SERS signal is described as the sum of the individual contributions of each molecule treated independently.…

光学 · 物理学 2020-01-08 Yuan Zhang , Javier Aizpurua , Ruben Esteban

Surface-enhanced Raman scattering (SERS) combines analyte-specificity and single-molecule sensitivity, but its potential is limited by slow readout where sophisticated nanosensors are analysed in a serial fashion, one particle at a time. We…

The long-range action of surface-enhanced Raman scattering (SERS) is probed via distance-dependent measurements of molecular Raman spectra. To this end, identical SERS substrates composed of irregular silver nanoisland arrays were covered…

材料科学 · 物理学 2015-06-12 V. I. Kukushkin , A. B. Van'kov , I. V. Kukushkin

Surface-enhanced Raman spectroscopy (SERS) allows single-molecule detection due to the strong field localization occurring at sharp bends or kinks of the metal-vacuum interface. An important question concerns the limits of the signal…

光学 · 物理学 2008-06-19 Sanshui Xiao , Niels Asger Mortensen , Antti-Pekka Jauho

In Surface Enhanced Raman Scattering (SERS) the problem of drawing molecules to the places where surface plasmon resonance enhancements will produce signals is one of the most basic ones, and the initial obstacle to every application of the…

化学物理 · 物理学 2008-11-03 Paul D. Lacharmoise , Eric C. Le Ru , Pablo G. Etchegoin

Surface-enhanced Raman spectroscopy (SERS) is a sensitive label-free optical method that can provide fingerprint Raman spectra of biomolecules such as DNA, amino acids and proteins. While SERS of single DNA molecule has been recently…

Stimulated Raman scattering (SRS) microscopy allows for high-speed label-free chemical imaging of biomedical systems. The imaging sensitivity of SRS microscopy is limited to ~10 mM for endogenous biomolecules. Electronic pre-resonant SRS…

Surface-Enhanced Raman Scattering (SERS) allows for detection and identification of molecular vibrational fingerprints in minute sample quantities. The SERS process can be also exploited for optical manipulation of molecular vibrations. We…

Surface enhanced Raman spectroscopy (SERS) was used to probe the surface chemistry of chlorine-terminated silicon nanocrystal (Si-NC) surfaces in an air-free environment. SERS effect was observed from the thin films of Ag$_x$O using 514 nm…

材料科学 · 物理学 2016-06-28 İlker Doğan , Ryan Gresback , Tomohiro Nozaki , Mauritius C. M. van de Sanden

Surface enhanced Raman spectroscopy, is a technique of fundamental importance to analytical science and technology where the amplified Raman spectrum of analytes is used for chemical fingerprinting. Here, we showcase an engineered…

应用物理 · 物理学 2021-06-08 K N Prajapati , Anoop A Nair , S Ravi P Silva , J Mitra

Surface Enhanced Raman Spectroscopy (SERS) is a highly sensitive and selective technique that greatly enhances the signal of an analyte, compared with its signal from classical Raman Spectroscopy, due to its interaction with a substrates…

材料科学 · 物理学 2025-10-20 Jan Komeda , Antonio Cammarata , Tomas Polcar

We present an in-depth analysis of the experimental estimation of cross sections in Surface Enhanced Raman Scattering (SERS) by vibrational pumping. The paper highlights the advantages and disadvantages of the technique, pinpoints the main…

化学物理 · 物理学 2007-05-23 R. C. Maher , L. F. Cohen , E. C. Le Ru , P. G. Etchegoin

We provide the theoretical framework to understand the phenomenology and statistics of single-molecule (SM) signals arising in Surface-Enhanced Raman Scattering (SERS) under the presence of so-called electromagnetic hot-spots (HS's). We…

化学物理 · 物理学 2009-11-13 E. C. Le Ru , P. G. Etchegoin , M. Meyer

The present approach to SERS does not rely on a hihj electrical conductivity substrate or admixture to enable the SERS process. The novelty of our method is to create an artificial periodic electron distribution on a surface by illumination…

材料科学 · 物理学 2007-10-22 Martin S. Piltch , Perry C. Gray , Michael Manley

Surface enhanced Raman scattering (SERS) effects on tin dioxide in the form of bulk material, nanostructured thin films and colloidal solutions were investigated. Raman spectra are characterized by the three Raman scattering peaks at 478,…

材料科学 · 物理学 2015-06-03 Enza Fazio , Fortunato Neri , Salvatore Savasta , Salvatore Spadaro , Sebastiano Trusso
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