相关论文: Compact Sum-Over-States Expression without Dipolar…
The generalized Thomas-Kuhn sum rules are used to eliminate the explicit dependence on dipolar terms in the traditional sum-over-states (SOS) expression for the second hyperpolarizability to derive a new, yet equivalent, SOS expression.…
The nonlinear oscillator model is useful to basically understand the most important properties of nonlinear optical processes. It has been shown to give the correct asymptotic behaviour and to provide the general feature of harmonic…
The Thomas Kuhn Reich sum rules and the sum-over-states (SOS) expression for the hyperpolarizabilities are truncated when calculating the fundamental limits of nonlinear susceptibilities. Truncation of the SOS expression can lead to an…
It is explicitly shown, for optical processes arbitrarily comprising two-, three- or four-photon interactions, that the sum over all matter states of any optical susceptibility is exactly zero. The result remains true even in frequency…
The definition and computation of the topological susceptibility in non-abelian gauge theories is complicated by the presence of non-integrable short-distance singularities. Recently, alternative representations of the susceptibility were…
Partial sum rules are widely used in physics to separate low- and high-energy degrees of freedom of complex dynamical systems. Their application, though, is challenged in practice by the always finite spectrometer bandwidth and is often…
Using sum rules and a new dipole-free sum-over-states expression, we calculate the fundamental limits of the dispersion of the real and imaginary parts of all electronic nonlinear-optical susceptibilities. As such, these general results can…
The off-resonant hyperpolarizability is calculated using the dipole-free sum-over-stats expression from a randomly chosen set of energies and transition dipole moments that are forced to be consistent with the sum rules. The process is…
This paper assumes a robust, in general not dominated, probabilistic framework and provides necessary and sufficient conditions for a bipolar representation of subsets of the set of all quasi-sure equivalence classes of non-negative random…
The linear and nonlinear dynamical susceptibilities of a two level system are calculated as it undergoes a transition to a decoherent state. Analogously to the Glover-Tinkham-Ferrell sum rule of superconductivity, spectral weight in the…
The calculation of the third order susceptibility still is a long standing fundamental problem of particular importance in nonlinear nanooptics: Indeed, cancellation of size-dependent terms coming from uncorrelated excitations is expected,…
Truncated sum rules have been used to calculate the fundamental limits of the nonlinear susceptibilities; and, the results have been consistent with all measured molecules. However, given that finite-state models result in inconsistencies…
Using the sum-rules, the sum-over-states expression for the diagonal term of first hyperpolarizability can be expressed as the sum of three-state interaction terms. We study the behavior of a generic three-state term to show that is…
We propose a method for the decomposition of modal formulae on processes with nondeterminism and probability with respect to Structural Operational Semantics. The purpose is to reduce the satisfaction problem of a formula for a process to…
A generic physical situation is considered where Im $\Pi$, the imaginary part of polarization operator (generalized susceptibility), can be measured on a finite interval and the high frequency asymptotics (up to a few orders) of $\Pi$ can…
By considering the quantum-mechanically minimum allowable energy interval, we exactly count number of states (NOS) and introduce discrete density of states (DOS) concept for a particle in a box for various dimensions. Expressions for…
We introduce sparse polynomial zonotopes, a new set representation for formal verification of hybrid systems. Sparse polynomial zonotopes can represent non-convex sets and are generalizations of zonotopes, polytopes, and Taylor models.…
This work presents a sum-of-squares (SOS) based framework to perform data-driven stabilization and robust control tasks on discrete-time linear systems where the full-state observations are corrupted by L-infinity bounded input,…
While nonlinear optical spectroscopy is becoming more commonly used to study the excited states of nonlinear-optical systems, a general theory of inhomogeneous broadening is rarely applied in lieu of either a simple Lorentzian or Gaussian…
This paper proposes a method for set-valued state estimation of nonlinear, discrete-time systems. This is achieved by combining graphs of functions representing system dynamics and measurements with the hybrid zonotope set representation…