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We investigate condensation of a long confined chiral nematic polymer inside a spherical enclosure, mimicking condensation of DNA inside a viral capsid. The Landau-de Gennes nematic free energy {\sl Ansatz} appropriate for nematic polymers…

软凝聚态物质 · 物理学 2015-06-11 Daniel Svenšek , Rudolf Podgornik

Directed motion up a concentration gradient is crucial for the survival and maintenance of numerous biological systems, such as sperms moving towards an egg during fertilization or ciliates moving towards a food source. In these systems,…

We show that chiral symmetry can be broken spontaneously in one-component systems with isotropic interactions, i.e. many-particle systems having maximal a priori symmetry. This is achieved by designing isotropic potentials that lead to…

材料科学 · 物理学 2012-05-16 Erik Edlund , Oskar Lindgren , Martin Nilsson Jacobi

Imprinting of cholesteric textures in a polymer network is a method of preserving a macroscopically chiral phase in a system with no molecular chirality. By modifying the elastics properties of the network, the resulting stored helical…

软凝聚态物质 · 物理学 2009-11-11 S. Courty , A. R. Tajbakhsh , E. M. Terentjev

Liquid crystal mesophases of achiral molecules are normally achiral, yet in a few materials they spontaneously segregate and form right- and left-handed chiral domains. One mechanism that drives chiral segregation is molecular shape…

软凝聚态物质 · 物理学 2026-01-16 Matthew J. Deutsch , Robin L. B. Selinger , Paul van der Schoot

A phase transition can drive the spontaneous emergence of chiral orders in crystals below a critical temperature. However, selecting either a right- or a left-handed phase with the aid of electromagnetic fields is challenging, particularly…

材料科学 · 物理学 2025-03-11 Mauro Fava , Aldo H. Romero , Eric Bousquet

An autocatalytic pattern matching polymer system is studied as an abstract model for chemical ecosystem evolution. Highly ordered populations with particular sequence patterns appear spontaneously out of a vast number of possible states.…

分子网络 · 定量生物学 2015-06-17 Shinpei Tanaka , Harold Fellermann , Steen Rasmussen

In equilibrium liquid crystals, chirality leads to a variety of spectacular three-dimensional structures, but chiral and achiral phases with the same broken continuous symmetries have identical long-time, large-scale dynamics. In this…

软凝聚态物质 · 物理学 2021-06-23 S. J. Kole , Gareth P. Alexander , Sriram Ramaswamy , Ananyo Maitra

Chirality is ubiquitous in nature and fundamental in science, from particle physics to metamaterials.The most established technique of chiral discrimination - photoabsorption circular dichroism - relies on the magnetic properties of a…

We review the existing mathematical models which describe physicochemical mechanisms capable of producing a symmetry-breaking transition to a state in which one chirality dominates the other. A new model is proposed, with the aim of…

生物大分子 · 定量生物学 2010-07-20 Jonathan AD Wattis

We study, experimentally, the dynamics of a binary mixture of air-fluidized disks. The disks are chiral since they incorporate a set of blades with constant tilt. Both species are identical except for their blades tilt angle, which is…

软凝聚态物质 · 物理学 2022-10-05 Miguel Ángel López-Castaño , Álvaro Rodríguez-Rivas , Francisco Vega Reyes

Chiral polymers are ubiquitous in nature and in the cellular context they are often found in association with membranes. Here we show that surface bound polymers with an intrinsic twist and anisotropic bending stiffness can exhibit a sharp…

软凝聚态物质 · 物理学 2016-04-26 David A. Quint , Ajay Gopinathan , Gregory M. Grason

From the beginning of molecular theory, the interplay of chirality and magnetism has intrigued scientists. There is still the question if enantiospecific adsorption of chiral molecules occurs on magnetic surfaces. Enantiomer discrimination…

Chiral molecules can selectively transport electrons of a particular spin orientation, yet the underlying mechanism remain poorly understood. Here, we present theoretical evidence that electrons propagating through chiral materials with…

材料科学 · 物理学 2024-03-01 Xiaoming Wang , Yeming Xian , Yanfa Yan

We investigate the interaction between a chirally imprinted network and a solvent of chiral molecules. We find, a liquid crystalline polymer network is preferentially swollen by one component of a racemic solvent. This ability to separate…

软凝聚态物质 · 物理学 2009-11-07 Y. Mao , M. Warner

We experimentally investigate the chiral optical response of an individual nanostructure consisting of three equally sized spherical nanoparticles made of different materials and arranged in \ang{90} bent geometry. Placing the nanostructure…

光学 · 物理学 2019-07-30 Sergey Nechayev , René Barczyk , Uwe Mick , Peter Banzer

A system formed by a crowded environment of catalytic obstacles and complex oscillatory chemical reactions is inquired. The obstacles are static spheres of equal radius, which are placed in a random way. The chemical reactions are carried…

Chirality and chiral molecules are key elements in modern chemical and biochemical industries. Individual addressing, and the eventual separation of chiral enantiomers has been and still is an important elusive task in molecular physics and…

Detection of chiral molecules requires amplification of chirality to measurable levels. Typically, amplification mechanisms are considered at the microscopic scales of individual molecules and their aggregates. Here we demonstrate chirality…

软凝聚态物质 · 物理学 2015-07-28 Chenhui Peng , Oleg D. Lavrentovich

The question of the onset of the homochirality on prebiotic Earth still remains a fundamental question in the quest for the origin of life. Recent works in this field introduce the concept of recycling, rather than the traditional open-flow…

分子网络 · 定量生物学 2011-05-23 Raphael Plasson