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Residual entropy, which reflects the degrees of freedom in a system at absolute zero temperature, is crucial for understanding quantum and classical ground states. Despite its key role in explaining low-temperature phenomena and ground…

统计力学 · 物理学 2025-02-20 Zenan Dai , Xiao Yan Xu

Properties that are necessarily formulated within pure (symmetric) expectation values are difficult to calculate for projector quantum Monte Carlo approaches, but are critical in order to compute many of the important observable properties…

计算物理 · 物理学 2015-06-23 Catherine Overy , George H. Booth , N. S. Blunt , James Shepherd , Deidre Cleland , Ali Alavi

In order to find the equilibrium geometries of molecules and solids and to perform ab initio molecular dynamics, it is necessary to calculate the forces on the nuclei. We present a correlated sampling method to efficiently calculate…

凝聚态物理 · 物理学 2009-10-31 Claudia Filippi , C. J. Umrigar

Modern quantum Monte Carlo (QMC) methods often capture electron correlation through both explicitly correlating Jastrow factors and small to mid-sized configuration interaction (CI) expansions. Here, we study the additional optimization…

化学物理 · 物理学 2023-02-08 Scott M. Garner , Eric Neuscamman

Quantum impurity models describe an atom or molecule embedded in a host material with which it can exchange electrons. They are basic to nanoscience as representations of quantum dots and molecular conductors and play an increasingly…

Many-electron problems pose some of the greatest challenges in computational science, with important applications across many fields of modern science. Fermionic quantum Monte Carlo (QMC) methods are among the most powerful approaches to…

The new {\em ab initio} quantum path integral Monte Carlo approach has been developed and applied for the entropy difference calculations for the strongly coupled degenerated uniform electron gas (UEG), a well--known model of simple metals.…

等离子体物理 · 物理学 2021-07-28 Vladimir Filinov , Pavel Levashov , Alexander Larkin

Quantum Monte Carlo (QMC) methods represent a powerful family of computational techniques for tackling complex quantum many-body problems and performing calculations of stationary state properties. QMC is among the most accurate and…

材料科学 · 物理学 2025-01-08 Alfonso Annarelli , Dario Alfè , Andrea Zen

Neutron matter, through its connection to neutron stars as well as systems like cold atom gases, is one of the most interesting yet computationally accessible systems in nuclear physics. The Configuration-Interaction Monte Carlo (CIMC)…

核理论 · 物理学 2023-04-19 Pierre Arthuis , Carlo Barbieri , Francesco Pederiva , Alessandro Roggero

We recently proposed a novel approach to converging electronic energies equivalent to high-level coupled-cluster (CC) computations by combining the deterministic CC($P$;$Q$) formalism with the stochastic configuration interaction (CI) and…

化学物理 · 物理学 2021-03-23 J. Emiliano Deustua , Jun Shen , Piotr Piecuch

We show how to use the multiple histogram method to combine canonical ensemble Monte Carlo simulations made at different temperatures and densities. The method can be applied to study systems of particles with arbitrary interaction…

统计力学 · 物理学 2009-10-31 A. L. Ferreira , M. A. Barroso

In recent years, the combination of precise quantum Monte Carlo (QMC) methods with realistic nuclear interactions and consistent electroweak currents, in particular those constructed within effective field theories (EFTs), has lead to new…

核理论 · 物理学 2019-09-04 J. E. Lynn , I. Tews , S. Gandolfi , A. Lovato

During the past years several variance reduction techniques for Monte Carlo electron transport have been developed in order to reduce the electron computation time transport for absorbed dose distribution. We have implemented the Macro…

医学物理 · 物理学 2009-11-13 L. A. Perles , A. de Almeida

We extend correlated sampling from classical auxiliary-field quantum Monte Carlo to the quantum-classical (QC-AFQMC) framework, enabling accurate nuclear force computations crucial for geometry optimization and reaction dynamics. Stochastic…

Quantum Monte Carlo belongs to the most accurate simulation techniques for quantum many-particle systems. However, for fermions, these simulations are hampered by the sign problem that prohibits simulations in the regime of strong…

计算物理 · 物理学 2020-10-28 A. Yilmaz , K. Hunger , T. Dornheim , S. Groth , M. Bonitz

Monte Carlo methods are widely used importance sampling techniques for studying complex physical systems. Integrating these methods with deep learning has significantly improved efficiency and accuracy in high-dimensional problems and…

无序系统与神经网络 · 物理学 2024-12-24 Yixiong Ren , Jianhui Zhou

Although liquid water is ubiquitous in chemical reactions at roots of life and climate on the earth, the prediction of its properties by high-level ab initio molecular dynamics simulations still represents a formidable task for quantum…

化学物理 · 物理学 2015-04-22 Andrea Zen , Ye Luo , Guglielmo Mazzola , Leonardo Guidoni , Sandro Sorella

We present a novel Monte Carlo algorithm which enhances equilibrization of low-temperature simulations and allows sampling of configurations over a large range of energies. The method is based on a non-Boltzmann probability weight factor…

凝聚态物理 · 物理学 2009-10-30 Ulrich H. E. Hansmann , Yuko Okamoto

Recent years have witnessed a surge of experimental and theoretical interest in controlling the properties of matter, such as its chemical reactivity, by confining it in optical cavities, where the enhancement of the light-matter coupling…

Monte Carlo methods play a central role in particle physics, where they are indispensable for simulating scattering processes, modeling detector responses, and performing multi-dimensional integrals. However, traditional Monte Carlo methods…

量子物理 · 物理学 2025-10-14 Heechan Yi , Kayoung Ban , Myeonghun Park , Kyoungchul Kong