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We compute the ab-initio electron density beyond the strict Born-Oppenheimer approximation in crystalline LiH and LiD with density functional methods. By taking into account the quantum mechanical nature of the nuclei, an aspect absent in…

材料科学 · 物理学 2026-03-13 Ville J. Härkönen

In heavy atoms and molecules, on the distances $a \gg Z^{-1}$ from all of the nuclei (with a charge $Z_m$) we prove that $\rho_\Psi (x)$ is approximated in $L^p$-norm, by the Thomas-Fermi density.

谱理论 · 数学 2020-04-02 Victor Ivrii

It is known that the asymptotic decay of the electron density outside a molecule is informative about its first ionization potential. It has recently become clear that the special circumstance that the Kohn-Sham (KS) highest-occupied…

化学物理 · 物理学 2018-08-01 Paola Gori-Giorgi , Evert Jan Baerends

Large-angle elastic scattering of alpha-particle and strongly-bound light nuclei at a few tens MeV/nucleon has shown the pattern of rainbow scattering. This interesting process was shown to involve a significant overlap of the two colliding…

核理论 · 物理学 2007-05-23 Dao T. Khoa , W. von Oertzen , H. G. Bohlen , H. S. Than

In heavy atoms and molecules, on the distances $a \ll Z^{-1/3}$ from one of the nuclei (with a charge $Z_m$) we prove that $\rho_\Psi (x)$ is approximated in $L^p$-norm, by the electronic density for a single atom in the model with no…

数学物理 · 物理学 2020-04-02 Victor Ivrii

In the present paper, we study sharp C^{1;\alpha} regularity results with boundary Neumann condition for viscosity solutions for a class of degenerate fully non-linear elliptic equations with Neumann boundary conditions.

偏微分方程分析 · 数学 2020-08-12 G. C. Ricarte

Many molecular "quantum" theories, like "quantum chemistry", conceal that they are actually quantum-classical approaches---they treat one set of molecular degrees of freedom classically while the remaining degrees of freedom follow the laws…

化学物理 · 物理学 2021-04-07 Thomas Grohmann

We consider non-autonomous wave equations \[ \left\{ \begin{aligned} \&\ddot u(t) + \B(t)\dot u(t) + \A(t)u(t) = f(t) \quad t\text{-a.e.}\\ \&u(0)=u_0,\, \dot u(0) = u_1. \end{aligned} \right. \] where the operators $\A(t)$ and $\B(t)$ are…

偏微分方程分析 · 数学 2013-11-11 Dominik Dier , El Maati Ouhabaz

Inspired by the recent debate as to whether the proton drip-line nucleus 22Al demonstrates a halo structure in its ground state and in order to assess such a possibility, we have analyzed theoretical results obtained within the relativistic…

核理论 · 物理学 2025-01-15 Panagiota Papakonstantinou , Myeonghwan Mun , Cong Pan , Kaiyuan Zhang

In the framework of a recently developed alpha-cluster model a nucleus is represented as a core (alpha-cluster liquid drop with dissolved excess neutron pairs in it) and a nuclear molecule on its surface. From analysis of experimental…

核理论 · 物理学 2010-09-01 G. K. Nie

We study functions $f$ on $\mathbb Q$ which statisfy a ``quantum modularity'' relation of the shape $$ f(x+1)=f(x), \qquad f(x) - |x|^{-k} f(-1/x) = h(x) $$ where $h:\mathbb R_{\neq 0} \to \mathbb C$ is a function satisfying various…

数论 · 数学 2022-10-25 Sandro Bettin , Sary Drappeau

The properties of nuclei embedded in an electron gas are studied within the relativistic mean-field approach. These studies are relevant for nuclear properties in astrophysical environments such as neutron-star crusts and supernova…

核理论 · 物理学 2008-11-26 Thomas J. Buervenich , Igor N. Mishustin , Walter Greiner

We explore the existence and behaviour of holomorphic restricted Hartree-Fock (h-RHF) solutions for two-electron problems. Through algebraic geometry, the exact number of solutions with $n$ basis functions is rigorously identified as…

化学物理 · 物理学 2018-01-15 Hugh G. A. Burton , Mark Gross , Alex J. W. Thom

We prove sharp regularity estimates for viscosity solutions of fully nonlinear parabolic equations of the form \begin{equation}\label{Meq}\tag{Eq} u_t- F(D^2u, Du, X, t) = f(X,t) \quad \mbox{in} \quad Q_1, \end{equation} where $F$ is…

偏微分方程分析 · 数学 2016-01-25 João Vitor da Silva , Eduardo V. Teixeira

This work contributes in two areas, with sharp results, to the current investigation of regularity of solutions of heat equations (*) $Pu+\partial_tu=f$ on $\Omega\times I $, where $P$ is a nonlocal operator, and $\Omega \subset R^n$,…

偏微分方程分析 · 数学 2018-01-03 Gerd Grubb

Point-proton density distributions are deduced for 130 stable nuclei from $^{7}\mathrm{Li}$ to $^{232}\mathrm{Th}$ from nuclear charge densities determined in elastic electron scattering. There are 171 cases are presented in model-dependent…

核理论 · 物理学 2025-05-09 Tianyu Wu , Baohua Sun , Huihui Xie , Junyao Xu , Ge Guo

We study the bending of rectangular atomic monolayers along different directions from first principles. Specifically, choosing the phosphorene, GeS, TiS$_3$, and As$_2$S$_3$ monolayers as representative examples, we perform Kohn-Sham…

材料科学 · 物理学 2022-12-21 Shashikant Kumar , Phanish Suryanarayana

Interference terms between monopole and quadrupole Coulomb form factors that contribute to the cross-section of electron scattering from polarized nuclei are studied within the plane wave Born approximation. By experimentally exploring the…

核理论 · 物理学 2024-02-14 Pedro Sarriguren

Eight pairs of rare earth normally deformed nuclei around the isobaric nuclei with A = 164 and have identical values of F-spin have been studied. These pairs of identical bands cover 16 mass units and are classified. We suggested a…

核理论 · 物理学 2023-02-01 M. A. Abdelsalam , H. A. Ghanim , M. Kotb , A. M. Khalaf

We have performed a systematic first-principles investigation to calculate the structural, electronic, and magnetic properties of PbCrO$_{3}$, CrPbO$_{3}$ as well as their equiproportional combination. The local density approximation…

强关联电子 · 物理学 2012-01-25 Bao-Tian Wang , Wen Yin , Wei-Dong Li , Fangwei Wang