相关论文: Is there an Optimal Substrate Geometry for Wetting…
The wetting properties of solid substrates with macroscopic random roughness are considered as a function of the microscopic contact angle of the wetting liquid and its partial pressure in the surrounding gas phase. It is shown that Wenzel…
The wetting properties of solid substrates with customary (i.e., macroscopic) random roughness are considered as a function of the microscopic contact angle of the wetting liquid and its partial pressure in the surrounding gas phase.…
Conventional wetting theories on rough surfaces with Wenzel, Cassie-Baxter, and Penetrate modes suggest the possibility of tuning the contact angle by adjusting the surface texture. Despite decades of intensive study, there are still many…
he contact angle of a liquid droplet on a surface under partial wetting conditions differs for a nanoscopically rough or periodically corrugated surface from its value for a perfectly flat surface. Wenzel's relation attributes this…
Hypothesis Emerging energy-related technologies deal with multiscale hierarchical structures, intricate surface morphology, non-axisymmetric interfaces, and complex contact lines where wetting is difficult to quantify with classical…
Any solid surface is intrinsically rough on the microscopic scale. In this paper, we study the effect of this roughness on the wetting properties of hydrophilic substrates. Macroscopic arguments, such as those leading to the well-known…
We analyze theoretically complete wetting of a substrate supporting an array of parallel, vertical plates which can tilt elastically. The adsorbed liquid tilts the plates, inducing clustering, and thus modifies the substrate geometry. In…
The continuum model related to the Winterbottom problem, i.e., the problem of determining the equilibrium shape of crystalline drops resting on a substrate, is derived in dimension two by means of a rigorous discrete-to-continuum passage by…
The ability to control wettability is important for a wide range of technological applications in which precise microfluidic handling is required. It is known that predesigned roughness at a micro- or nano- scale enhances the wetting…
One of the most questionable issues in wetting is the vertical force balance that is excluded in Young's law. On soft deformable solids, such as biotic materials and synthetic polymers, the vertical force of liquid leads to a microscopic…
Young's law fails on soft solid and liquid substrates where there are substantial deformations near the contact line. On liquid substrates, this is captured by Neumann's classic analysis, which provides a geometrical construction for…
We investigate theoretically the possibility of a wetting transition induced by geometric roughness of a solid substrate for the case where the flat substrate does not show a wetting layer. Our approach makes use of a novel closed-form…
Complete wetting of geometrically structured substrates by one-component fluids with long-ranged interactions is studied. We consider periodic arrays of rectangular or parabolic grooves and lattices of cylindrical or parabolic pits. We show…
It is established that roughness and chemistry play a crucial role in the wetting properties of a substrate. Yet, few studies have analyzed systematically the effect of the non-uniformity in the distribution of texture and surface tension…
Hypothesis Understanding wetting behavior is of great importance for natural systems and technological applications. The traditional concept of contact angle, a purely geometrical measure related to curvature, is often used for…
We study the interfacial phenomenology of a fluid in contact with a microstructured substrate within the mean-field approximation. The sculpted substrate is a one-dimensional array of infinitely long grooves of sinusoidal section of…
An exact solution of a two dimensional RSOS model of wetting at a corrugated (periodic) wall is found using transfer matrix techniques. In contrast to mean-field analysis of the same problem the wetting transition remains second-order and…
The wetting and filling properties of a fluid adsorbed on a solid grooved substrate are studied by means of a microscopic density functional theory. The grooved substrates are modelled using a solid slab, interacting with the fluid…
Replica and functional renormalization group methods show that, with short range substrate forces or in strong fluctuation regimes, wetting of a self-affine rough wall in 2D turns first-order as soon as the wall roughness exponent exceeds…
When a drop of water is placed on a rough surface, there are two possible extreme regimes of wetting: the one called Cassie-Baxter (CB) with air pockets trapped underneath the droplet and the one characterized by the homogeneous wetting of…