相关论文: Local distortion in LaCoO3 and PrCoO3: EXAFS, XRD …
Room temperature Mn K-edge extended x-ray absorption fine structure (EXAFS) studies were carried out on La$_{1-x}$Sr$_x$MnO$_{3+\delta}$ (x = 0.1 to 0.9) compounds. It is found from the detailed EXAFS analysis that the local structure…
We report the electronic and local structural investigation of double pervoskites Sr$_{2-x}$La$_x$CoNbO$_6$ ($x=$ 0--1) using x-ray absorption near edge structure (XANES) and extended x-ray absorption fine structures (EXAFS) at the Nb, Co,…
We use x-ray absorption spectroscopy to investigate the local structure and electronic properties of bulk La$_{1-y}$Sr$_{y}$Co$_{1-x}$Nb$_x$O$_3$ ($y=$ 2$x$ as LSCNO and $y=$ 0 as LCNO) samples. The x-ray absorption near-edge spectra…
The combined local structure techniques, extended x-ray absorption fine structure (EXAFS) and neutron pair distribution function analysis, have been used for temperatures 4 <= T <= 330 K to rule out a large Jahn-Teller (JT) distortion of…
We present K-edge XAFS (X-Ray Absorption Fine Structure) data for various concentrations of Pr in Y$_{1- x}$Pr$_{x}$Ba$_{2}$Cu$_{3}$O$_{7}$. The character of the Pr K-edge XAFS data indicate that most of the Pr substitutes onto the Y site…
We report on an angular resolved X-ray Absorption Spectroscopy study of $La_{0.7}Sr_{0.3}MnO_{3}$ thin films epitaxially grown by pulsed laser deposition on slightly mismatched substrates which induce tensile or compressive strains. XANES…
Neutron diffraction for a polycrystalline sample of LaCo$_{0.8}$Rh$_{0.2}$O$_{3}$ and synchrotron x-ray diffraction for polycrystalline samples of LaCo$_{0.9}$Rh$_{0.1}$O$_{3}$ and LaCo$_{0.8}$Rh$_{0.2}$O$_{3}$ have been carried out in…
We combine infrared reflectivity and EXAFS (Extended X-ray Absorption Fine Structure) techniques to study the solid solution La0.67Ca0.33MnO3 prepared by different methods yielding samples with different insulator-metal transition…
Local structure of REOFeAs (RE=La, Pr, Nd, Sm) system has been studied as a function of chemical pressure varied due to different rare-earth size. Fe K-edge extended X-ray absorption fine structure (EXAFS) measurements in the fluorescence…
We have used high-resolution Extended X-ray Absorption Fine-Structure and diffraction techniques to measure the local structure of strained La$_{0.5}$Sr$_{0.5}$CoO$_3$ films under compression and tension. The lattice mismatch strain in…
A theoretically supported experimental study of the (1-x)LaFeO3.xLaMnO3 (LFO-LMO) solid solution is being reported for the first time which reveals a phase transformation from the Pbnm and R3-c phase at a chemical composition of x=0.625.…
The local atomic disorder and the electronic structure in the environment of manganese atoms in LaMnO_3 has been studied by x-ray absorption spectroscopy, over a temperature range (300K to 870K) covering the orbital ordering transition…
We report the experimental results of temperature dependent polarized As K-edge extended x-ray absorption fine structure (EXAFS) of LaFe1-xCoxAsO (x=0.0 and 0.11) single-crystals. By aligning the Fe-As bond direction in the direction of the…
We have used the XAFS (x-ray-absorption fine structure) technique to investigate the local structure about the Cu, Ba, and Tl atoms in orthorhombic Tl-2201 with a superconducting transition temperature T$_c$=60 K. Our results clearly show…
A thorough investigation of local structure, influencing macroscopic properties of the solid is of potential interest. We investigated the local structure of GaN nanowires (NWs) with different native defect concentration synthesized by the…
Structural investigation on $Co_{3-x}Mn_xTeO_6$; ($0 \lt x \le 2$) solid solutions as a function of Mn concentration using Synchrotron X-ray diffraction (SXRD) and XANES measurements are presented. Phase diagram obtained from Rietveld…
The electron paramagnetic resonance (EPR) g factors g_x, g_y and g_z of the orthorhombic Cu^{2+}(1) site in fresh PrBa_{2}Cu_{3}O_{6+x} powders are theoretically investigated using the perturbation formulas of the g factors for a 3d^9 ion…
The crystal structures of the Sr1-xCaxRuO3 perovskites are investigated using both long range and local structural probes. High resolution synchrotron powder X-ray diffraction characterization at ambient temperature shows that the materials…
The structural properties of Er-doped AlNO epilayers grown by radio frequency magnetron sputtering were studied by Extended X-ray Absorption Fine Structure (EXAFS) spectra recorded at the Er L 3 edge. The analysis revealed that Er…
The effect of rare-earth ion size on the octahedral distortions in rare-earth chromites (RCrO3, R = Lu, Tb, Gd, Eu, Sm) crystallizing in the orthorhombic structure has been studied using Raman scattering and synchrotron powder x-ray…