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We synthesized powder samples of Na$_{x}$CoO$_{2}\cdot y$H$_{2}$O changing the volume of the water in the hydration process, then investigated their superconducting properties,. It was proved that the volume of water is one of key…

超导电性 · 物理学 2009-11-10 H. Sakurai , K. Takada , T. Sasaki , E. Takayama-Muromachi

Water can be transitioned to an enhanced heat-conducting phase by supercooling only the water at the bottom of a container. The temperature gradient across the 4 cm in the center of an 8 cm long column of water with a 397 mW heat source at…

流体动力学 · 物理学 2011-04-07 James D. Brownridge

The use of proton exchange membrane (PEM) electrolyzers is the method of choice for the conversion of solar energy when frequently occurring changes of the current load are an issue. However, this technique requires electrolytes with low…

We report 23Na NMR studies of the polycrystalline samples of double-layer hydrated cobalt oxides NaxCoO2.yH2O (x ~ 0.35 and y ~ 1.3) with the superconducting transition temperatures Tc < 1.8K and ~4.5K, and the dehydrated NaxCoO2 (x ~…

超导电性 · 物理学 2009-11-11 H. Ohta , Y. Itoh , C. Michioka , K. Yoshimura

We apply first principles computational techniques to analyze the two-electron, multi-step, electrochemical reduction of CO2 to CO in water using cobalt porphyrin as a catalyst. Density Functional Theory calculations with hybrid functionals…

化学物理 · 物理学 2011-01-06 Kevin Leung , Ida M. B. Nielsen , Na Sai , Craig J. Medforth , J. A. Shelnutt

Cobalt-porphyrin catalyzed reductive decomposition of CO2 to CO is investigated based on Koper's water facilitated CO2 reduction mechanism using a simple but accurate protocol based on thermodynamics. In our protocol, accurate predictions…

介观与纳米尺度物理 · 物理学 2019-05-06 Kaito Miyamoto , Ryoji Asahi

High overpotentials, particularly an issue of common anode materials, hamper the process of water electrolysis for clean energy generation. Thanks to immense research efforts up to date oxygen evolution electrocatalysts based on…

The superconducting property of recently discovered sodium cobalt oxyhydrate, Na$_{0.35}$CoO$_2$1.3H$_2$O ($T_c=4.5$ K), has been studied by means of muon spin rotation/relaxation ($\mu$SR) down to 2 K. It was found that the zero-field muon…

In order to investigate the role of the water molecules in Na$_{0.35}$CoO$_{2}\cdot$1.3H$_{2}$O, we synthesized superconducting Na$_{0.35}$CoO$_{2}\cdot$1.3H$_{2}$O and nonsuperconducting Na$_{0.35}$CoO$_{2}\cdot$0.7H$_{2}$O, and measured…

超导电性 · 物理学 2009-11-10 H. Sakurai , K. Takada , F. Izumi , D. A. Dilanian , T. Sasaki , E. Takayama-Muromachi

Single phase, uniform size (~9 nm) Cobalt Ferrite (CFO) nanoparticles have been synthesized by hydrothermal synthesis using oleic acid as a surfactant. The as synthesized oleic acid coated CFO (OA-CFO) nanoparticles were well dispersible in…

材料科学 · 物理学 2017-01-06 Sandeep Munjal , Neeraj Khare

The structural properties of NaxCoO2 and NaxCoO2yH2O have been investigated. The NaxCoO2yH2O samples in general show up the superconducting transitions at around 3.5K. EDAX analyses suggest our samples have the average composition of…

超导电性 · 物理学 2009-11-10 Y. G. Shi , J. Q. Li , H. C. Yu , Y. Q. Zhou , H. R. Zhang , C. Dong

We report a precise $^{59}$Co nuclear quadrupolar resonance (NQR) measurement on the recently discovered cobalt oxyhydrate Na$_{0.35}$CoO$_{2}$$\cdot y$H$_{2}$O superconductor from $T$=40 K down to 0.2 K. We find that in the normal state…

超导电性 · 物理学 2009-11-10 T. Fujimoto , G. -q. Zheng , Y. Kitaoka , R. L. Meng , J. Cmaidalka , C. W. Chu

We report 23Na NMR studies of the polycrystalline samples of bilayer hydrated cobalt oxides Na0.35CoO2-1.3H2O with the superconducting transition temperatures Tc < 1.8 and ~ 4.5 K. The magnitude of the 23Na nuclear spin-lattice relaxation…

超导电性 · 物理学 2007-05-23 H. Ohta , Y. Itoh , C. Michioka , K. Yoshimura

We propose that unconventional superconductivity in hydrated sodium cobaltate $Na_xCoO_2$ results from an interplay of electronic correlations and electron-phonon interactions. On the basis of the $t-V$ model plus phonons we found evidences…

超导电性 · 物理学 2009-11-10 A. Foussats , A. Greco , M. Bejas , A. Muramatsu

We have used electron and neutron powder diffraction to elucidate the structural properties of superconducting \NaD. Our measurements show that our superconducting sample exhbits a number of supercells ranging from ${1/3}a^{*}$ to…

Studies of the NMR Knight shift K of Na0.3CoO2.yH2O have been carried out in detail. The suppression of K by the occurrence of the superconductivity reported previously by the present authors in both magnetic field directions perpendicular…

超导电性 · 物理学 2009-11-11 Yoshiaki Kobayashi , Taketo Moyoshi , Hidekazu Watanabe , Mai Yokoi , Masatoshi Sato

Superconductivity with zero resistance transition temperature (Tc) up to 8.4 K and 8.3 K can be obtained by doping cobalt and sodium in alfa-FeSe with the nominal composition of Fe0.92Co0.08Se and Na0.1FeSe, respectively. The electrical…

超导电性 · 物理学 2008-08-14 Zhanqiang Liu , Aihua Fang , Fuqiang Huang , Mianheng Jiang

We suggest that Cobalt-Oxychalcogenide layers constructed by vertex sharing CoA$_2$O$_2$ (A=S,Se,Te) tetrahedra, such as BaCoAO, are strongly correlated multi-orbital electron systems that can provide important clues on the cause of…

强关联电子 · 物理学 2017-05-19 Congcong le , Shengshan Qin , Jiangping Hu

Single phase cobalt ferrite (CoFe2O4, CFO) nanoparticles of a controlled size (~ 6 nm) exhibiting superparamagnetic properties have been synthesized by hydrothermal technique using oleic acid (OA) as surfactant. The oleic acid coated CFO…

材料科学 · 物理学 2017-01-06 Sandeep Munjal , Neeraj Khare , Chetan Nehate , Veena Koul

Current approaches for electric power generation from nanoscale conducting or semi-conducting layers in contact with moving aqueous droplets are promising as they show efficiencies of around 30 percent, yet, even the most successful ones…