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Magnetic properties of a tetrahedral "Ni_4" molecule are discussed in terms of the Heisenberg model, with magnetic anisotropy terms included, and on the basis of first-principle calculations within the density functional theory. It is shown…

材料科学 · 物理学 2007-05-23 A. V. Postnikov , M. Brueger , J. Schnack

The tetrameric Ni(II) spin cluster Ni4Mo12 has been studied by INS. The data were analyzed extensively in terms of a very general spin Hamiltonian, which includes antiferromagnetic Heisenberg interactions, biquadratic 2-spin and 3-spin…

介观与纳米尺度物理 · 物理学 2010-06-11 J. Nehrkorn , M. Höck , M. Brüger , H. Mutka , J. Schnack , O. Waldmann

We report temperature dependent magnetization and neutron diffraction measurements on the corundum related magnetoelectric antiferromagnet Mn$_{4}$Ta$_{2}$O$_{9}$. Measurements performed on a single crystalline specimen reveal that the…

强关联电子 · 物理学 2021-01-20 Soumendra Nath Panja , Pascal Manuel , Sunil Nair

We study the behavior of the magnetization and the magnetic susceptibility of molecular magnets with complex bridging structure. Our computations are based on a post-Hartree-Fock method accounting for the intricate network of interatomic…

强关联电子 · 物理学 2020-03-30 M. Georgiev , H. Chamati

We have studied the magnetic behavior of dextran-coated magnetite (Fe$_3$O$_4$) nanoparticles with median particle size $\left<d\right>=8$ $nm$. Magnetization curves and in-field M\"ossbauer spectroscopy measurements showed that the…

材料科学 · 物理学 2007-05-23 E. Lima , A. L. Brandl , A. D. Arelaro , G. F. Goya

We present results of inelastic neutron scattering experiments performed for the compound Magnetic and neutron spectroscopic properties of the tetrameric nickel compound $[Mo_{12}O_{28}(\mu_2-OH)_9(\mu_3-OH)_3{Ni(H_2O)_3}_4] $\cdot$…

强关联电子 · 物理学 2015-05-18 A. Furrer , K. W. Krämer , Th. Strässle , D. Biner , J. Hauser , H. -U. Güdel

Recent magnetic measurements on tetra-nickel molecular magnets [Ni(hmp)(ROH)Cl]$_4$, where R=CH$_3$, CH$_2$CH$_3$, or (CH$_2$)$_2$C(CH$_3$)$_3$ and hmp$^-$ is the monoanion of 2-hydroxymethylpyridine, revealed a strong exchange bias prior…

材料科学 · 物理学 2009-11-10 Kyungwha Park , En-Che Yang , David N. Hendrickson

The low-lying magnetic excitations in the dimer of single-molecule magnets (Mn4)2 are studied by inelastic neutron scattering as a function of hydrostatic pressure. The anisotropy parameters D and B04, which describe each Mn4 subunit, are…

We report the magnetic properties of magnetic nano-composite, consisting of different quantity of NiFe2O4 nanoparticles in polymer matrix. The nanoparticles exhibited a typical magnetization blocking, which is sensitive on the variation of…

材料科学 · 物理学 2015-05-13 A. Poddar , R. N. Bhowmik , Amitabha De , Pintu Sen

We develop a structured theoretical framework used in our recent articles [Eur. Phys. J. B 92, 93 (2019) and Phys. Rev. B 101, 094427 (2020)] to characterize the unusual behavior of the magnetic spectrum, magnetization and magnetic…

强关联电子 · 物理学 2022-05-19 M. Georgiev , H. Chamati

Magnetic molecules are a class of compounds that is also investigated in view of their magnetocaloric properties. The isothermal entropy change and the adiabatic temperature change are key figures of merit for magnetocaloric performance.…

化学物理 · 物理学 2026-02-23 D. Westerbeck , J. Schnack

Electron spin resonance and magnetization data in magnetic fields up to 55 T of a novel multicenter paramagnetic molecular complex [L_2Ni_4(N_3)(O_2C Ada)_4](Cl O_4) are reported. In this compound, four Ni centers each having a spin S = 1…

Although low-dimensional $S = 1$ antiferromagnets remain of great interest, difficulty in obtaining high-quality single crystals of the newest materials hinders experimental research in this area. Polycrystalline samples are more readily…

We examine the anisotropic properties of the exchange stiffness constant, $\mathcal{A}$, for rare-earth permanent magnet, Nd$_2$Fe$_{14}$B, by connecting analyses with two different scales of length, i.e., Monte Carlo (MC) method with an…

材料科学 · 物理学 2018-08-22 Yuta Toga , Masamichi Nishino , Seiji Miyashita , Takashi Miyake , Akimasa Sakuma

The dielectric properties of Fe$_{3}$O$_{4}$ magnetic nanoparticles with an insulating coating layer of SiO$_{2}$ were investigated. At high temperatures, the changes of the dielectric constant and loss induced by the magnetic field are…

材料科学 · 物理学 2011-03-18 C. -C. Chang , L. Zhao , M. -K. Wu

Cubic spinel GeNi2O4 exhibits intriguing magnetic properties with two successive antiferromagnetic phase transitions (TN1 12.1 and TN2 11.4 K) with the absence of any structural transition. We have performed detailed heat capacity and…

强关联电子 · 物理学 2020-12-02 T. Basu , T. Zou , Z. Dun , C. Q. Xu , C. R. Dela Cruz , Tao Hong , H. B. Cao , K. M. Taddei , H. D. Zhou , X. Ke

Low-energy magnon excitations in magnetoelectric LiFePO$_4$ have been investigated by high-frequency high-field electron spin resonance spectroscopy in magnetic fields up to B = 58 T and frequencies up to f = 745 GHz. For magnetic fields…

强关联电子 · 物理学 2021-05-06 J. Werner , C. Neef , C. Koo , A. Ponomaryov , S. Zvyagin , R. Klingeler

We study the dynamics of paramagnetic molecular superrotors in an external magnetic field. Optical centrifuge is used to create dense ensembles of oxygen molecules in ultra-high rotational states. It is shown for the first time, that the…

量子物理 · 物理学 2015-06-10 A. A. Milner , A. Korobenko , J. Floß , I. Sh. Averbukh , V. Milner

To identify the possible mechanism of coercivity (Hc) degradation of Nd-Fe-B sintered magnets, we study the roles of the exchange field acting on the 4f electrons in Nd ions and theoretically investigate how the variation of the exchange…

材料科学 · 物理学 2015-06-23 Ryo Sasaki , Daisuke Miura , Akimasa Sakuma

We use a microscopic Slater-Koster tight-binding model with short-range exchange and atomic spin-orbit interactions that realistically captures generic features of ferromagnetic metal nanoparticles to address the mesoscopic physics of…

凝聚态物理 · 物理学 2009-11-07 A. Cehovin , C. M. Canali , A. H. MacDonald
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