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A self-interacting polymer with one end attached to a sticky surface has been studied by means of a flat-histogram stochastic growth algorithm known as FlatPERM. We examined the four-dimensional parameter space of the number of monomers up…

统计力学 · 物理学 2009-11-10 J. Krawczyk , A. L. Owczarek , T. Prellberg , A. Rechnitzer

An infinite hierarchy of layering transitions exists for model polymers in solution under poor solvent or low temperatures and near an attractive surface. A flat histogram stochastic growth algorithm known as FlatPERM has been used on a…

统计力学 · 物理学 2009-11-10 J. Krawczyk , A. L. Owczarek , T. Prellberg , A. Rechnitzer

Lattice model of directed self avoiding walk is used to investigate adsorption properties of a semiflexible sequential copolymer chain on an impenetrable curved surface on a hexagonal lattice in two dimensions. Walks of the copolymer chains…

统计力学 · 物理学 2010-06-02 Pramod Kumar Mishra

Polymer chains undergoing a continuous adsorption-desorption transition are studied through extensive computer simulations. A three-dimensional self-avoiding walk lattice model of a polymer chain grafted onto a surface has been treated for…

统计力学 · 物理学 2018-05-30 P. H. L. Martins , J. A. Plascak , M. Bachmann

We use the lattice model of directed walks to investigate the conformational as well as the adsorption properties of a semiflexible homopolymer chain immersed in a good solvent in two and three dimensions. To account for the stiffness in…

统计力学 · 物理学 2009-11-07 P. K. Mishra , S. Kumar , Y. Singh

We study uniform 3-star polymers with one branch tethered to an attractive surface and another branch pulled by a force away from the surface. Each branch of the 3-star lattice is modelled as a self-avoiding walk on the simple cubic lattice…

统计力学 · 物理学 2019-05-30 C J Bradly , A L Owczarek

We consider a model of self-avoiding walk on a lattice with on-site repulsion and an attraction for every vertex of the walk visited on the surface to study force-induced desorption of a linear polymer chain adsorbed on an attractive…

统计力学 · 物理学 2007-05-23 P. K. Mishra , Sanjay Kumar , Yashwant Singh

We consider the force on the end of a polymer chain being pulled through a network at velocity $v$, using computer simulations. We develop algorithms for measuring the force on the end of the chain using lattice models of polymers. Our…

凝聚态物理 · 物理学 2009-10-22 J. M. Deutsch , Hyoungsoo Yoon

Using molecular dynamic simulation, we study the stretching of an adsorbed homopolymer in a poor solvent with one end held at a distance $z_e$ from the substrate. We measure the vertical force $f$ on the end of the chain as a function of…

软凝聚态物质 · 物理学 2009-11-10 Franck Celestini , Thoma Frisch , Xabier Oyharcabal

We examine the phase transition of polymer adsorption as well as the underlying kinetics of polymer binding from dilute solutions on a structureless solid surface. The emphasis is put on the properties of regular multiblock copolymers,…

软凝聚态物质 · 物理学 2009-09-03 A. Milchev , V. Rostiashvili , S. Bhattacharya , T. Vilgis

We consider the properties of a self-avoiding polymer chain, adsorbed on a solid attractive substrate which is attached with one end to a pulling force. The conformational properties of such chain and its phase behavior are treated within a…

软凝聚态物质 · 物理学 2009-04-01 S. Bhattacharya , V. G. Rostiashvili , A. Milchev , T. A. Vilgis

A phase diagram for a surface-interacting long flexible polymer chain in a two-dimensional poor solvent where the possibility of collapse exists is determined using exact enumeration method. A model of a self-attracting self avoiding walk…

统计力学 · 物理学 2007-05-23 Yashwant Singh , Debaprasad Giri , Sanjay Kumar

Lattice model of directed self avoiding walk has been solved analytically to investigate adsorption desorption phase transition behaviour of a semiflexible sequential copolymer chain on a two dimensional impenetrable surface perpendicular…

统计力学 · 物理学 2010-02-23 Pramod Kumar Mishra

We consider a self-avoiding walk model of polymer adsorption where the adsorbed polymer can be desorbed by the application of a force, concentrating on the case of the square lattice. Using series analysis methods we investigate the…

统计力学 · 物理学 2015-06-17 Anthony J. Guttmann , Iwan Jensen , Stu G. Whittington

The thermally assisted detachment of a self-avoiding polymer chain from an adhesive surface by an external force applied to one of the chain ends is investigated. We perform our study in the "fixed height" statistical ensemble where one…

软凝聚态物质 · 物理学 2009-08-13 S. Bhattacharya , A. Milchev , V. G. Rostiashvili , T. A. Vilgis

We analyse the conformational behaviour of a linear semiflexible homo-polymer chain confined by two geometrical constraints under a good solvent condition in two dimensions. The constraints are stair shaped impenetrable surfaces. The…

软凝聚态物质 · 物理学 2014-07-14 Pramod Kumar Mishra

We study the adsorption of polymer chains on a fluctuating surface. Physical examples are provided by polymer adsorption at the rough interface between two non-miscible liquids, or on a membrane. In a mean-field approach, we find that the…

凝聚态物理 · 物理学 2009-10-22 T. Garel , Mehran Kardar , H. Orland

A phase diagram for a surface interacting long flexible partially directed polymer chain in a two-dimensional poor solvent where the possibility of collapse in the bulk exists is determined using exact enumeration method. We used a model of…

统计力学 · 物理学 2020-12-29 Pramod K Mishra , Yashwant Singh

Adsorption of polymers to surfaces is crucial for understanding many fundamental processes in nature. Recent experimental studies indicate that the adsorption dynamics is dominated by non-equilibrium effects. We investigate the adsorption…

软凝聚态物质 · 物理学 2009-05-12 Debabrata Panja , Gerard T. Barkema , Anatoly B. Kolomeisky

We analyze the structural behavior of a single polymer chain grafted to an attractive, flexible surface. Our model is composed of a coarse-grained bead-and-spring polymer and a tethered membrane. By means of extensive parallel tempering…

软凝聚态物质 · 物理学 2011-09-26 Steffen Karalus , Wolfhard Janke , Michael Bachmann
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