相关论文: Evidence for the S=9 excited state in Mn12-bromoac…
We present a detailed investigation of the temperature and frequency dependence of the anomalous EPR transitions first observed in Mn12-acetate by Hill et al. [Phys. Rev. Lett. 80, 2453 (1998)]. The most dominant of these transitions…
We present detailed angle-dependent single crystal electron paramagnetic resonance (EPR) data for field rotations in the hard plane of the S=10 single molecule magnet Mn12-acetate. A clear four-fold variation in the resonance positions may…
Multi-high-frequency electron paramagnetic resonance(EPR) spectrum for a supermolecular dimer $[ Mn_4]_2$ of single-molecule magnets recently reported [S. Hill, R. S. Edwards, N. Aliaga-Alcalde and G. Christou(HEAC), Science 302, 1015…
High Frequency electron paramagnetic resonance has been used to observe the magnetic dipole, $\Delta$ M$_s$ = $\pm$ 1, transitions in the $S = 9$ excited state of the single molecule magnet Fe$_8$Br$_8$. A Boltzmann analysis of the measured…
Mn2+ ion doping is used as an electron paramagnetic resonance (EPR) probe to investigate the influence of low-coordination structural defects such as step edges at the surface of terraced (001) MgO nanoparticles on the electronic…
We study the effects of 10% Cr substitution in Mn sites of Bi0.5Sr0.5MnO3 on the antiferromagnetic (AFM) (TN ~ 110 K) transition using structural, magnetic and electron paramagnetic resonance (EPR) techniques. Field cooled (FC) and zero…
We study theoretically Electron Paramagentic Resonance (EPR) linewidths for single crystals of the molecular magnets Fe$_8$ and Mn$_{12}$ as functions of energy eigenstates $M_s$, frequency, and temperature when a magnetic field along the…
We report perturbed angular correlation measurements with 111mCd/111Cd and 111In/111Cd probes, at the ISOLDE-CERN facility, in the manganite compounds BaMnO3 , with the 6H and 15R polymorphs, and SrMnO3 , with the 4H polymorph. The electric…
We employ electron paramagnetic resonance (EPR) of the spin probe Mn2+ to study the paraelectric ferroelectric transition in DMAMnF and Mn2 doped DMZnF, which are considered to be model metal organic frameworks (MOF) with a Pb free…
Presented are magnetization measurements on a crystal of Fe8 single-molecule magnets using a Hall probe magnetometer. Irradiation with microwaves at frequencies of 92 and 110-120 GHz leads to the observation of electron paramagnetic…
It is shown that our multi-high-frequency (40-200 GHz) resonant cavity technique yields distortion-free high field EPR spectra for single crystal samples of the uniaxial and biaxial spin S = 10 single molecule magnets (SMMs)…
High-Sensitivity Electron Paramagnetic Resonance experiments have been carried out in fresh and stressed Mn12-Acetate single crystals for frequencies ranging from 40 GHz up to 110 GHz. The high number of crystal dislocations formed in the…
Using electron spin resonance, lattice position and dynamic properties of Mn2+ ions were studied in 0.5 and 2 % manganese doped SrTiO3 ceramics prepared by conventional mixed oxide method. The measurements showed that Mn2+ ions substitute…
Electron paramagnetic resonance (EPR) is a valuable tool for physics, chemistry, biology and medicine, providing complementary spectroscopic information to NMR. It has long been known that EPR at high magnetic fields offers greater spectral…
The local magnetic field distribution on the subsurface of a single-molecule magnet crystal, SMM, above blocking temperature (T >> Tb) detected for a very short time interval (~ 10-10 s), has been investigated. Electron Paramagnetic…
A high-frequency (95 GHz) EPR study is reported on single crystals of the planar tetranuclear complex Fe4(OCH3)6(dpm)6 (where Hdpm = dipivaloylmethane), which has been previously shown to present typical single-molecule magnet behaviour.…
High-frequency electron paramagnetic resonance (EPR) studies of the antiferromagnetic Mn-$[3\times 3]$ molecular grid clearly reveal a breaking of the $\Delta S = 0$ selection rule, providing direct evidence for the mixing of spin…
Broadening of the electron paramagnetic resonance (EPR) line of the paramagnetic probe decorated on the superconducting system surface was detected at the temperature T>Tc. The source of the anomaly and the conditions of its emergence were…
We herein estimate the effect of lattice defects on the line shape of electron paramagnetic resonance (EPR) signals from a single crystal of the S=10 single-molecule magnet Mn$_{12}$ with the external magnetic field along the crystal c…
Crystals of the molecular magnet Mn12-acetate are known to contain a small fraction of low- symmetry (minor) species with a small anisotropy barrier against spin reversal. The lower barrier leads to faster magnetic relaxation and lower…