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The magnetic properties of the two isostructural molecule-based magnets, Ni(NCS)$_{2}$(thiourea)$_{2}$, $S$ = 1, [thiourea = SC(NH$_2$)$_2$] and Co(NCS)$_{2}$(thiourea)$_{2}$, $S$ = 3/2, are characterised using several techniques in order…

We report temperature dependent magnetization and neutron diffraction measurements on the corundum related magnetoelectric antiferromagnet Mn$_{4}$Ta$_{2}$O$_{9}$. Measurements performed on a single crystalline specimen reveal that the…

强关联电子 · 物理学 2021-01-20 Soumendra Nath Panja , Pascal Manuel , Sunil Nair

Three different CrNi2 complexes were synthesized. They differ from each other by the nature of the terminal ligand and of the counter anion : [Cr(CN)4[CN-Ni(tetren)]2]Cl, that crystallizes in two different crystallographic systems and…

介观与纳米尺度物理 · 物理学 2009-09-29 Raluca Tiron , Wolfgang Wernsdorfer , Fabien Tuyeras , Ariane Scuiller , Valerie Marvaud , Michel Verdaguer

Substantial amounts of the transition metals Mn, Fe, Co, and Ni can be substituted for Li in single crystalline Li$_2$(Li$_{1-x}T_x$)N. Isothermal and temperature-dependent magnetization measurements reveal local magnetic moments with…

材料科学 · 物理学 2015-06-09 A. Jesche , L. Ke , J. L. Jacobs , B. Harmon , R. S. Houk , P. C. Canfield

Magnetic properties of a tetrahedral "Ni_4" molecule are discussed in terms of the Heisenberg model, with magnetic anisotropy terms included, and on the basis of first-principle calculations within the density functional theory. It is shown…

材料科学 · 物理学 2007-05-23 A. V. Postnikov , M. Brueger , J. Schnack

Magnetic anisotropy phenomena in bimetallic antiferromagnets Mn$_2$Au and MnIr are studied by first-principles density functional theory calculations. We find strong and lattice-parameter dependent magnetic anisotropies of the ground state…

The electronic and magnetic properties of Mn coordinated to 1,2,4,5-tetracyanobenzene (TCNB) in the Mn-TCNB 2D metal-ligand networks have been investigated by combining scanning tunneling microscopy and X-ray magnetic circular dichroism…

We present a detailed theoretical investigation on the magnetic properties of small single-layered Fe, Co and Ni clusters deposited on Ir(111), Pt(111) and Au(111). For this a fully relativistic {\em ab-initio} scheme based on density…

材料科学 · 物理学 2015-06-04 S. Bornemann , O. Šipr , S. Mankovsky , S. Polesya , J. B. Staunton , W. Wurth , H. Ebert , J. Minár

The magnetic and structural properties of polycrystalline Co$_{4-x}$ Ni$_x$ Nb$_2$ O$_9$ (x=1,2) have been investigated by neutron powder diffraction, magnetization and heat capacity measurements, and density functional theory (DFT)…

We report the synthesis, crystal structure and magnetic properties of the S=1 2-leg spin-ladder compound Na_2Ni_2(C_2O_4)_3(H_2O)_2. The magnetic properties were examined by magnetic susceptibility and pulsed high field magnetization…

We present detailed investigations in single crystals of two recently reported quaternary intermetallic compounds EuRhAl$_4$Si$_2$ and EuIrAl$_4$Si$_2$ employing magnetization, electrical resistivity in zero and applied fields, heat…

强关联电子 · 物理学 2014-11-04 Arvind Maurya , P. Bonville , A. Thamizhavel , S. K. Dhar

The influence of magnetic anisotropy on nanosecond magnetization reversal in coupled FeNi/Cu/Co trilayers was studied using a photoelectron emission microscope combined with x-ray magnetic circular dicroism. In quasi-isotropic samples the…

High-field electron paramagnetic resonance (HFEPR) spectra were collected at several frequencies for single crystal [Zn3.91Ni0.09(hmp)4(dmb)4Cl4] (1), where dmb is 3,3-dimethyl-1-butanol and hmp is the monoanion of 2-hydroxymethylpyridine.…

介观与纳米尺度物理 · 物理学 2007-05-23 En-Che Yang , Cem Kirman , Jon Lawrence , Lev N. Zakharov , Arnold L. Rheingold , Stephen Hill , David N. Hendrickson

The magnetic anisotropy and exchange coupling between spins localized at the positions of 3d transition metal atoms forming two-dimensional metal-organic coordination networks (MOCNs) grown on the Au(111) metal surface are studied. In…

Entanglement, magnetization and magnetic susceptibility for 1D antiferromagnetic spin 1 and spin 3/2 Heisenberg XXX model with Dzyaloshinskii-Moriya interaction, single-ion anisotropy and external magnetic field on the finite chain are…

统计力学 · 物理学 2022-12-22 Nerses Ananikian , Vladimir V. Papoyan

The magnetic state and magnetic coupling of individual atoms in nanoscale structures relies on a delicate balance between different interactions with the atomic-scale surrounding. Using scanning tunneling microscopy, we resolve the…

介观与纳米尺度物理 · 物理学 2015-06-12 T. R. Umbach , M. Bernien , C. F. Hermanns , A. Krüger , V. Sessi , I. Fernandez-Torrente , P. Stoll , J. I. Pascual , K. J. Franke , W. Kuch

Materials composed of spin-1 antiferromagnetic (AFM) chains are known to adopt complex ground states which are sensitive to the single-ion-anisotropy (SIA) energy ($D$), and intrachain ($J_{0}$) and interchain ($J'_{i}$) exchange energy…

The local magnetic anisotropy of a typical crystalline compound is usually attributed to the combined effect of crystal electric fields and spin-orbit coupling. We show that this simple local picture is transformed in heavy-fermion…

强关联电子 · 物理学 2025-08-05 Ewan Scott , Michal Kwasigroch

The magnetocrystalline anisotropy energies (MAEs) of the ferromagnetic metals bcc Fe, fcc and hcp Co, and fcc Ni have been calculated by using the {\it ab initio} tight-binding method. Disentangling the strong correlation among the $d$…

材料科学 · 物理学 2009-11-10 Yuannan Xie , John A. Blackman

Although low-dimensional $S = 1$ antiferromagnets remain of great interest, difficulty in obtaining high-quality single crystals of the newest materials hinders experimental research in this area. Polycrystalline samples are more readily…

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