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We discuss the general link between mode-coupling like equations (which serve as the basis of some recent theories of supercooled liquids) and the dynamical equations governing mean-field spin-glass models, or the dynamics of a particle in…

凝聚态物理 · 物理学 2015-06-25 Jean-Philippe Bouchaud , Leticia Cugliandolo , Jorge Kurchan , Marc Mézard

In active microrheology the mechanical properties of a material are tested by adding probe particles which are pulled by an external force. In case of supercooled liquids, strong forcing leads to a thinning of the host material which…

软凝聚态物质 · 物理学 2016-01-20 Carsten F. E. Schroer , Andreas Heuer

We study the temperature dependence of static and dynamic responses of Coulomb interacting particles in two-dimensional traps across the thermal crossover from an amorphous solid- to liquid-like behaviors. While static correlations, that…

无序系统与神经网络 · 物理学 2017-10-11 Biswarup Ash , J. Chakrabarti , Amit Ghosal

Data-driven approaches to inferring the local structures responsible for plasticity in amorphous materials have made substantial contributions to our understanding of the failure, flow, and rearrangement dynamics of supercooled fluids. Some…

软凝聚态物质 · 物理学 2023-08-22 Tomilola M. Obadiya , Daniel M. Sussman

We introduce a new measure of the structure of a liquid which is the softness of the mean-field potential developed by us earlier. We find that this softness is sensitive to small changes in the structure. We then study its correlation with…

软凝聚态物质 · 物理学 2021-05-26 Manoj Kumar Nandi , Sarika Maitra Bhattacharyya

We develop a framework for understanding the difference between strong and fragile behavior in the dynamics of glass-forming liquids from the properties of the potential energy landscape. Our approach is based on a master equation…

无序系统与神经网络 · 物理学 2015-05-30 Sumilan Banerjee , Chandan Dasgupta

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

软凝聚态物质 · 物理学 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

A molecular theory of the glass transition of network forming liquids is developed using a combination of self-consistent phonon and liquid state approaches. Both the dynamical transition and the entropy crisis characteristic of random…

凝聚态物理 · 物理学 2009-11-07 Randall W. Hall , Peter G. Wolynes

We present molecular dynamics simulations of a model glass-forming liquid (the binary Kob-Anderson Lennard-Jones model) and consider the distributions of inherent energies and metabasins during aging. In addition to the typical protocol of…

无序系统与神经网络 · 物理学 2016-08-14 Christian Rehwald , Nicoletta Gnan , Andreas Heuer , Thomas Schrøder , Jeppe C. Dyre , Gregor Diezemann

In a recent study we have found that for a large number of systems the configuration entropy at pair level, $S_{c2}$, which is primarily determined by the structural information, vanishes at the mode coupling transition temperature $T_{c}$.…

软凝聚态物质 · 物理学 2018-01-03 Manoj Kumar Nandi , Atreyee Banerjee , Chandan Dasgupta , Sarika Maitra Bhattacharyya

Supercooled liquids are metastable states realized by suppressing crystallization below the melting temperature. While it is well established that their dynamics slow down dramatically and become spatially heterogeneous upon cooling, the…

软凝聚态物质 · 物理学 2026-04-07 Norihiro Oyama , Yusuke Hara , Takeshi Kawasaki , Kang Kim

Controversy exists regarding the possible existence of a transition between the liquid and glassy states of water. Here we use experimental measurements of the entropy, specific heat, and enthalpy of both liquid and glassy water to…

凝聚态物理 · 物理学 2007-05-23 Francis W. Starr , C. Austen Angell , Robin J. Speedy , H. Eugene Stanley

Super-cooled liquids are characterized by their fragility: the slowing down of the dynamics under cooling is more sudden and the jump of specific heat at the glass transition is generally larger in fragile liquids than in strong ones.…

无序系统与神经网络 · 物理学 2014-01-14 Le Yan , Gustavo Düring , Matthieu Wyart

We introduce a supercooled liquid model and obtain parameter-free quantitative predictions that are in excellent agreement with numerical simulations, notably in the hard low-temperature region characterized by strong deviations from…

无序系统与神经网络 · 物理学 2020-05-19 Tommaso Rizzo , Thomas Voigtmann

The potential energy landscape, PEL, theory stands as one of the most successful frameworks for understanding supercooled liquids and glassy systems. A central element of this theory is the configurational entropy, Sc, which is…

统计力学 · 物理学 2026-01-01 Hongqin Liu

We present a quantitative description of the thermodynamics in a supercooled binary Lennard Jones liquid via the evaluation of the degeneracy of the inherent structures, i.e. of the number of potential energy basins in configuration space.…

统计力学 · 物理学 2009-10-31 F. Sciortino , W. Kob , P. Tartaglia

We investigate numerically the low temperature equilibration of glassy systems via non-local Monte Carlo methods. We re-examine several systems that have been studied previously and investigate new systems in order to test the performance…

软凝聚态物质 · 物理学 2007-05-23 Yisroel Brumer , David R. Reichman

Computer simulations of a model glass-forming system are presented, which are particularly sensitive to the correlation between the dynamics and the topography of the potential energy landscape. This analysis clearly reveals that in the…

软凝聚态物质 · 物理学 2009-10-31 Stephan Buechner , Andreas Heuer

The thermodynamic entropy of coarse-grained (CG) models stands as one of the most important properties for quantifying the missing information during the CG process and for establishing transferable (or extendible) CG interactions. However,…

化学物理 · 物理学 2024-04-10 Jaehyeok Jin , David R. Reichman

Predicting the local dynamics of supercooled liquids based purely on local structure is a key challenge in our quest for understanding glassy materials. Recent years have seen an explosion of methods for making such a prediction, often via…

软凝聚态物质 · 物理学 2021-08-25 Emanuele Boattini , Frank Smallenburg , Laura Filion