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A phase diagram for a surface interacting long flexible partially directed polymer chain in a two-dimensional poor solvent where the possibility of collapse in the bulk exists is determined using exact enumeration method. We used a model of…

统计力学 · 物理学 2020-12-29 Pramod K Mishra , Yashwant Singh

A phase diagram for a surface-interacting long flexible polymer chain in a two-dimensional poor solvent where the possibility of collapse exists is determined using exact enumeration method. A model of a self-attracting self avoiding walk…

统计力学 · 物理学 2007-05-23 Yashwant Singh , Debaprasad Giri , Sanjay Kumar

Lattice model of directed self avoiding walk has been solved analytically to investigate adsorption desorption phase transition behaviour of a semiflexible sequential copolymer chain on a two dimensional impenetrable surface perpendicular…

统计力学 · 物理学 2010-02-23 Pramod Kumar Mishra

We use the lattice model of directed walks to investigate the conformational as well as the adsorption properties of a semiflexible homopolymer chain immersed in a good solvent in two and three dimensions. To account for the stiffness in…

统计力学 · 物理学 2009-11-07 P. K. Mishra , S. Kumar , Y. Singh

Polymer chains undergoing a continuous adsorption-desorption transition are studied through extensive computer simulations. A three-dimensional self-avoiding walk lattice model of a polymer chain grafted onto a surface has been treated for…

统计力学 · 物理学 2018-05-30 P. H. L. Martins , J. A. Plascak , M. Bachmann

We consider a self-avoiding walk model of polymer adsorption where the adsorbed polymer can be desorbed by the application of a force, concentrating on the case of the square lattice. Using series analysis methods we investigate the…

统计力学 · 物理学 2015-06-17 Anthony J. Guttmann , Iwan Jensen , Stu G. Whittington

A polymer chain tethered to a surface may be compact or extended, adsorbed or desorbed, depending on interactions with the surface and the surrounding solvent. This leads to a rich phase diagram with a variety of transitions. To investigate…

软凝聚态物质 · 物理学 2009-11-13 Jutta Luettmer-Strathmann , Federica Rampf , Wolfgang Paul , Kurt Binder

We examine the phase transition of polymer adsorption as well as the underlying kinetics of polymer binding from dilute solutions on a structureless solid surface. The emphasis is put on the properties of regular multiblock copolymers,…

软凝聚态物质 · 物理学 2009-09-03 A. Milchev , V. Rostiashvili , S. Bhattacharya , T. Vilgis

Lattice model of directed self avoiding walk is used to investigate adsorption properties of a semiflexible sequential copolymer chain on an impenetrable curved surface on a hexagonal lattice in two dimensions. Walks of the copolymer chains…

统计力学 · 物理学 2010-06-02 Pramod Kumar Mishra

We consider the properties of a self-avoiding polymer chain, adsorbed on a solid attractive substrate which is attached with one end to a pulling force. The conformational properties of such chain and its phase behavior are treated within a…

软凝聚态物质 · 物理学 2009-04-01 S. Bhattacharya , V. G. Rostiashvili , A. Milchev , T. A. Vilgis

We consider the phase diagram of self-avoiding walks (SAW) on the simple cubic lattice subject to surface and bulk interactions, modeling an adsorbing surface and variable solvent quality for a polymer in dilute solution, respectively. We…

统计力学 · 物理学 2019-06-19 C J Bradly , A L Owczarek , T Prellberg

The subject of this work is the adsorption transition of a long flexible self-avoiding polymer chain onto a rigid thin rod. The rod is represented by a cylinder of radius R with a short-ranged attractive surface potential for the chain…

统计力学 · 物理学 2009-11-11 Andreas Hanke

We study analytically a model of a two dimensional, partially directed, flexible or semiflexible polymer, attached to an attractive wall which is perpendicular to the preferred direction. In addition, the polymer is stretched by an…

统计力学 · 物理学 2015-05-13 Pui-Man Lam , Yi Zhen , Haijun Zhou , Jie Zhou

The conformational behavior of a coarse-grained finite polymer chain near an attractive spherical surface was investigated by means of multicanonical Monte Carlo computer simulations. In a detailed analysis of canonical equilibrium data…

软凝聚态物质 · 物理学 2018-01-03 Handan Arkin , Wolfhard Janke

We investigate the phase diagram of a self-avoiding walk model of a 3-star polymer in two dimensions, adsorbing at a surface and being desorbed by the action of a force. We show rigorously that there are four phases: a free phase, a…

统计力学 · 物理学 2019-05-14 C J Bradly , E J Janse van Rensburg , A L Owczarek , S G Whittington

The process of adsorption on a planar repulsive, "marginal" and attractive wall of long-flexible polymer chains with excluded volume interactions is investigated. The performed scaling analysis is based on formal analogy between the polymer…

软凝聚态物质 · 物理学 2009-10-08 Z. Usatenko

We have performed multicanonical chain-growth simulations of a polymer interacting with an adsorbing surface. The polymer, which is not explicitly anchored at the surface, experiences a hierarchy of phase transitions between conformations…

统计力学 · 物理学 2009-11-11 Michael Bachmann , Wolfhard Janke

In this paper we present simulations of a surface-adsorbed polymer subject to an elongation force. The polymer is modelled by a self-avoiding walk on a regular lattice. It is confined to a half-space by an adsorbing surface with attractions…

统计力学 · 物理学 2007-05-23 J. Krawczyk , T. Prellberg , A. Rechnitzer , A. L. Owczarek

We analyse the conformational behaviour of a linear semiflexible homo-polymer chain confined by two geometrical constraints under a good solvent condition in two dimensions. The constraints are stair shaped impenetrable surfaces. The…

软凝聚态物质 · 物理学 2014-07-14 Pramod Kumar Mishra

Recently it has been shown that a two-dimensional model of self-attracting polymers based on attracting segments with the addition of stiffness displays three phases: a swollen phase, a globular, liquid-like phase, and an anisotropic…

软凝聚态物质 · 物理学 2015-06-23 J. Krawczyk , A. L. Owczarek , T. Prellberg
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