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We employ effective interaction potentials to study the equilibrium structure and phase behavior of highly asymmetric mixtures of star polymers. We consider in particular the influence of the addition of a component with a small number of…

软凝聚态物质 · 物理学 2007-05-23 Christian Mayer , Christos N. Likos , Hartmut Löwen

The growing interest in the dynamical properties of colloidal suspensions, both in equilibrium and under an external drive such as shear or pressure flow, requires the development of accurate methods to correctly include hydrodynamic…

The density profile and surface tension for the interface of phase-separated colloid-polymer mixtures have been studied in the framework of the square gradient approximation for both ideal and interacting polymers in good solvent. The…

软凝聚态物质 · 物理学 2009-11-10 A. Moncho-Jorda , B. Rotenberg , A. A. Louis

All cool stars with outer convective zones have the potential to exhibit stochastically excited stellar oscillations. In this work, we explore the outer layers of stars less massive than the Sun. In particular, we have computed a set of…

太阳与恒星天体物理 · 物理学 2021-09-28 Ana Brito , Ilídio Lopes

We propose microscopic density functional theory for inhomogeneous star polymers. Our approach is based on fundamental measure theory for hard spheres, and on Wertheim's first- and second-order perturbation theory for the interparticle…

软凝聚态物质 · 物理学 2007-05-23 A. Malijevsky , P. Bryk , S. Sokolowski

Interparticle interactions in charge-stabilized colloidal suspensions, of arbitrary salt concentration, are described at the level of effective interactions in an equivalent one-component system. Integrating out from the partition function…

软凝聚态物质 · 物理学 2009-10-31 A. R. Denton

We examine the demixing transition in star polymer-colloid mixtures for star arm numbers f=2,6,16,32 and different star-colloid size ratios. Theoretically, we solve the thermodynamically self-consistent Rogers-Young integral equations for…

In this paper we study the shape characteristics of star-like polymers in various solvent quality using a mesoscopic level of modeling. The dissipative particle dynamics simulations are performed for the homogeneous and four different…

软凝聚态物质 · 物理学 2020-03-24 O. Kalyuzhnyi , J. M. Ilnytskyi , Yu. Holovatch , C. von Ferber

Soft materials, such as colloidal suspensions, polymer solutions, and biological systems, are typically multicomponent mixtures of macromolecules and simpler components (e.g., microions, monomers, solvent) that can assemble into complex…

软凝聚态物质 · 物理学 2015-05-13 Alan R. Denton

We report on the construction of colloidal stars: 1 micrometer polystyrene beads grafted with a dense brush of 1 micrometer long and 10 nm wide semi-flexible filamentous viruses. The pair interaction potentials of colloidal stars are…

软凝聚态物质 · 物理学 2009-11-13 F. Huang , K. Addas , A. Ward , N. T. Flynn , E. Velasco , M. F. Hagan , Z. Dogic , S. Fraden

The dynamics of star polymers has been investigated via extensive Molecular- and Brownian Dynamics simulations for a large range of functionality $f$ and packing fraction $\eta$. The calculated isodiffusivity curves display both minima and…

软凝聚态物质 · 物理学 2009-11-10 G. Foffi , F. Sciortino , P. Tartaglia , E. Zaccarelli , F. Lo Verso , L. Reatto , K . A. Dawson , C. N. Likos

The free energy cost of confining a star polymer where $f$ flexible polymer chains containing $N$ monomeric units are tethered to a central unit in a slit with two parallel repulsive walls a distance $D$ apart is considered, for good…

软凝聚态物质 · 物理学 2013-10-29 J. Paturej , A. Milchev , S. A. Egorov , K. Binder

We study conformations and dynamics of active star polymers. The analysis shows that active star polymers stretching behaviour is quite different from that of active linear chains. The visual inspection of conformations and bond-bond…

软凝聚态物质 · 物理学 2022-10-11 Prabha Chuphal , Vladimir V. Palyulin

We calculate the scattering intensity of dilute and semi-dilute solutions of star polymers. The star conformation is described by a model introduced by Daoud and Cotton. In this model, a single star is regarded as a spherical region of a…

软凝聚态物质 · 物理学 2009-10-30 C. M. Marques , T. Charitat , D. Izzo , E. Mendes

We show how to coarse grain polymers in a good solvent as single particles, interacting with density-independent or density-dependent interactions. These interactions can be between the centres of mass, the mid-points or end-points of the…

软凝聚态物质 · 物理学 2009-11-07 A. A. Louis , P. G. Bolhuis , R. Finken , V. Krakoviack , E. J. Meijer , J. P. Hansen

Compact stars consisting of fermions with arbitrary masses and interaction strengths are studied by solving the structure equation of general relativity, the Tolman-Oppenheimer-Volkoff equations. Scaling solutions are derived for a free and…

天体物理学 · 物理学 2008-11-26 Gaurav Narain , Jurgen Schaffner-Bielich , Igor N. Mishustin

We analyze the impact of a porous medium (structural disorder) on the scaling of the partition function of a star polymer immersed in a good solvent. We show that corresponding scaling exponents change if the disorder is…

软凝聚态物质 · 物理学 2017-08-23 V. Blavats'ka , C. von Ferber , Yu. Holovatch

We have used neutron scattering to investigate the influence of concentration on the conformation of a star polymer. By varying the contrast between the solvent and isotopically labeled stars, we obtain the distributions of polymer and…

We experimentally measure the osmotic pressures of linear polymers and three-, four-, and eight-arm star polymers in a good solvent via membrane osmometry. These results reveal that the osmotic equations of state in the star polymer…

软凝聚态物质 · 物理学 2023-03-20 Takashi Yasuda , Masanobu Ino , Takamasa Sakai , Naoyuki Sakumichi

We consider star polymers, consisting of two different polymer species, in a solvent subject to quenched correlated structural obstacles. We assume that the disorder is correlated with a power-law decay of the pair correlation function…

软凝聚态物质 · 物理学 2011-01-17 Viktoria Blavatska , Christian von Ferber , Yurij Holovatch