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Morphological transformations of amphiphilic AB diblock copolymers in mixtures of a common solvent (S1) and a selective solvent (S2) for the B block are studied using the simulated annealing method. We focus on the morphological…

软凝聚态物质 · 物理学 2017-03-28 Zheng Wang , Yuhua Yin , Run Jiang , Baohui Li

We study a single statistical amphiphilic copolymer chain AB in a selective solvent (e.g.water). Two situations are considered. In the annealed case, hydrophilic (A) and hydrophobic (B) monomers are at local chemical equilibrium and both…

凝聚态物理 · 物理学 2009-10-22 T. Garel , L. Leibler , H. Orland

We use molecular dynamics simulations to study the static properties of a single linear multiblock copolymer chain under poor solvent conditions varying the block length $N$, the number of blocks $n$, and the solvent quality by variation of…

软凝聚态物质 · 物理学 2015-03-19 N. G. Fytas , P. E. Theodorakis

Isoporous membranes made from diblock copolymers have numerous applications, including water treatment and protein separation, and are successfully produced at a laboratory scale under controlled conditions. However, achieving optimal…

软凝聚态物质 · 物理学 2023-04-11 Nicolas Moreno , Suzana Nunes , Victor Calo

The structure of lamellar phases of symmetric $AB$ diblock copolymers in a thin film is investigated. We quantitatively compare the composition profiles and profiles of individual segments in self-consistent field calculations with Monte…

统计力学 · 物理学 2009-10-31 Thorsten Geisinger , Marcus Mueller , Kurt Binder

The properties of diluted symmetric A-B diblock copolymers at the interface between A and B homopolymer phases are studied by means of Monte Carlo (MC) simulations of the bond fluctuation model. We calculate segment density profiles as well…

化学物理 · 物理学 2015-06-26 A. Werner , F. Schmid , K. Binder , M. Mueller

Using the Gaussian Ansatz for the monomer-monomer correlation functions we derive a set of the self-consistent equations for determination of the conformational state in the bead-and-spring copolymer model. The latter is based on the…

软凝聚态物质 · 物理学 2007-05-23 Yu. A. Kuznetsov , E. G. Timoshenko

The phase diagram of star polymer solutions in a good solvent is obtained over a wide range of densities and arm numbers by Monte Carlo simulations. The effective interaction between the stars is modeled by an ultrasoft pair potential which…

软凝聚态物质 · 物理学 2009-10-31 M. Watzlawek , C. N. Likos , H. Loewen

The structure of polymer coils near interfaces between coexisting phases of symmetrical polymer mixtures (AB) is discussed, as well as the structure of symmetric diblock copolymers of the same chain length N adsorbed at the interface. The…

软凝聚态物质 · 物理学 2015-06-25 K. Binder , M. Mueller , F. Schmid , A. Werner

Conformations of isolated homo- dendrimers of G=1-7 generations with D=1-6 spacers have been studied in the good and poor solvents, as well as across the coil-to-globule transition, by means of a version of the Gaussian self-consistent…

软凝聚态物质 · 物理学 2009-11-07 E. G. Timoshenko , Yu. A. Kuznetsov , R. Connolly

Strongly interacting systems of dipolar bosons in three dimensions confined by harmonic traps are analyzed using the exact Path Integral Ground State Monte Carlo method. By adding a repulsive two-body potential, we find a narrow window of…

量子气体 · 物理学 2016-11-15 A. Macia , J. Sánchez-Baena , J. Boronat , F. Mazzanti

A mesoscopic model of a diblock copolymer is used to study the stability of a uniform lamellar phase under a reciprocating shear flow. Approximate viscosity contrast between the microphases is allowed through a linear dependence of the…

软凝聚态物质 · 物理学 2009-11-07 Peilong Chen , Jorge Vinals

We study the relationship between topological defect formation and ground-state packings in a model of repulsions in external confining potentials. Specifically we consider screened 2D Coulombic repulsions, which conveniently parameterizes…

软凝聚态物质 · 物理学 2021-10-04 Qingyou Meng , Gregory M. Grason

The presence of nanoparticles in a diblock copolymer leads to changes in the morphology and properties of the matrix and can produce highly organized hybrid materials. The resulting material properties depend not only on the polymer…

软凝聚态物质 · 物理学 2018-05-30 Javier Diaz , Marco Pinna , Andrei Zvelindovsky , Adelchi Asta , Ignacio Pagonabarraga

Vesicles self-assembled from amphiphilic diblock copolymers exhibit a wide diversity of behavior upon electroporation, due to competitions between edge, surface and bending energies that drive the system, while different viscous dissipation…

软凝聚态物质 · 物理学 2009-11-07 Harry Bermudez , Helim Aranda-Espinoza , Daniel A. Hammer , Dennis E. Discher , .

Based on large-scale Monte Carlo simulations on lattice the energy probability distribution functions are investigated for a large set of primary sequences in distinct models of copolymers at low temperatures below transitions to compacted…

软凝聚态物质 · 物理学 2007-05-23 Edward G. Timoshenko , Yuri A. Kuznetsov , Roman N. Basovsky

Star-like microgels have recently emerged as a promising class of thermoresponsive soft colloids, that have an internal architecture similar to that of star polymers. Here, we perform extensive monomer-resolved simulations to theoretically…

软凝聚态物质 · 物理学 2026-04-29 Tommaso Papetti , Elisa Ballin , Francesco Brasili , Emanuela Zaccarelli

A spherically symmetric hydrodynamic stellar core collapse under gravity is time-dependent and may become unstable once disturbed. Specifically for a homologously collapse of stellar core characterized by a polytropic exponent \Gamma=4/3,…

太阳与恒星天体物理 · 物理学 2013-10-10 Yu-Qing Lou , Biao Lian

The structural and dynamical properties of ultra-soft colloids - star polymers - exposed to a uniform external force field are analyzed applying the multiparticle collision dynamics approach, a hybrid coarse-grain mesoscale simulation…

软凝聚态物质 · 物理学 2018-03-09 Sunil P. Singh , Gerhard Gompper , Roland G. Winkler

We investigate the dynamics of an ensemble of inelastic hard spheres confined between two horizontal plates separated a distance smaller than twice the diameter of the particles, in such a way that the system is quasi-two-dimensional. The…

统计力学 · 物理学 2019-03-27 P. Maynar , M. I. García de Soria , J. Javier Brey