相关论文: The Chemistry of the Early Universe
We study the formation of first molecules, negative Hydrogen ions and molecular ions in model of the Universe with cosmological constant and cold dark matter. The cosmological recombination is described in the framework of modified model of…
We have reviewed the chemistry and cooling behaviour of low-density (n<10^4 cm^-3) primordial gas and devised a cooling model wich involves 19 collisional and 9 radiative processes and is applicable for temperatures in the range (1 K < T <…
Within the precise cosmological framework provided by the Lambda-Cold Dark Matter model and standard Big Bang nucleosynthesis, the chemical evolution of the pregalactic gas can now be followed with accuracy limited only by the uncertainties…
We examine the processes of formation and destruction of LiH molecules in the primordial gas at temperatures T \leq 5000 K in the framework of standard Friedmann cosmological models and we compute the optical depth of the Universe due to…
The relative efficiencies of the chemical pathways that can lead to the destruction of LiH and LiH+ molecules, conjectured to be present in the primordial gas and to control molecular cooling processes in the gravitational collapse of the…
(abridged) We use large cosmological simulations to study the origin of primordial star-forming clouds in a Lambda CDM universe, by following the formation of dark matter halos and the cooling of gas within them. To model the physics of…
We present the results of quantum calculations based on entirely ab initio methods for a variety of molecular processes and chemical reactions involving the LiHe$^+$ ionic polar molecule. With the aid of these calculations we derive…
Cooling of primordial gas plays a crucial role in the birth of the first structures in our Universe. Due to the low fractional abundance of molecular species at high redshifts, spontaneous emission rather than collisions represents the most…
We use a non-equilibrium chemical network to revisit and study the effect of H_{2}, HD and LiH molecular cooling on a primordial element of gas. We solve both the thermal and chemical equations for a gas element with an initial temperature…
The thermochemistry of H2 and HD in non-collapsed, non-reionized primordial gas up to the end of the dark age is investigated with recent radiation-matter and chemical reaction rates taking into account the efficient coolant HD, and the…
We study the formation of molecular hydrogen, after the epoch of re-ionization, in the context of canonical galaxy formation theory due to hierarchical clustering. There is an initial epoch of $H_2$ production in the gas phase through the…
After the recombination of Hydrogen, primordial molecules such as H_2, $HD$ can be formed.The formation of structures in the post-recombination gaseous medium is commonly explained by primordial density fluctuations. In a self-gravitating…
Cosmic gas makes up about 90% of baryonic matter in the Universe and H$_2$ is the closest molecule to star formation. In this work we study cold neutral gas and its H$_2$ component at different epochs, exploiting state-of-the-art…
It is now well known that a primordial chemistry, involving light elements produced during the nucleosynthesis period, might develop during the hydrogen post-recombination era. In particular, molecular ions and primordial molecules such as…
Over the last decade, observations of the cool interstellar medium in distant galaxies via molecular and atomic fine structure line emission has gone from a curious look into a few extreme, rare objects, to a mainstream tool to study galaxy…
Molecular hydrogen (H$_2$) and hydrogen deuteride (HD) are key coolants in primordial gas and regulate the formation of the first stars and proto-galaxies. Recent results from the James Webb Space Telescope provide striking insights into…
We study formation of molecules in primordial prestellar clumps and evaluate the line luminosities to assess detectability by next-generation facilities. If the initial H_2 fraction is sufficiently high, HD becomes an important coolant in…
We study the formation and destruction of the first molecules at the epochs of the Dark Ages and Cosmic Dawn to evaluate the luminosity of the protogalaxy clumps (halos) in the molecular lines. The cosmological recombination is described…
We present results from self-consistent 3D numerical simulations of cosmic structure formation with a multi-frequency radiative transfer scheme and non-equilibrium molecular chemistry of 13 primordial species (e-, H, H+, H-, He, He+, He++,…
Many questions in physical cosmology regarding the thermal history of the intergalactic medium, chemical enrichment, reionization, etc. are thought to be intimately related to the nature and evolution of pregalactic structure. In particular…