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Recent studies highlight the scientific importance and broad application prospects of two-dimensional (2D) sliding ferroelectrics, which prevalently exhibit vertical polarization with suitable stackings. It is crucial to understand the…

材料科学 · 物理学 2024-07-23 Shihan Deng , Hongyu Yu , Junyi Ji , Changsong Xu , Hongjun Xiang

The emerging ferroelectric properties of two-dimensional (2D) heterostructures are at the forefront of science and prospective technology. In moir\'e bilayers, twisting or heterostructuring causes local atomic reconstruction, which even at…

材料科学 · 物理学 2025-03-18 Wilson Nieto Luna , Robin Smeyers , Cem Sevik , Lucian Covaci , Milorad V. Milošević

Sliding ferroelectricity is highly attractive for its low energy barriers and fatigue resistance. As the origin of these exotic properties, its unconventional switching dynamics remains poorly understood: how an electric field drives a…

材料科学 · 物理学 2025-05-30 Ziwen Wang , Shuai Dong

Twisted moir\'e supercells, which can be approximated as a combination of sliding bilayers and constitute various topologically nontrivial polarization patterns, attract extensive attention recently. However, because of the excessive size…

This study explores the world of across-layer sliding ferroelectricity in multilayer hexagonal boron nitride (hBN) and gallium nitride (hGaN), aiming to control out-of-plane polarization. By investigating the effects of sliding single or…

材料科学 · 物理学 2025-04-08 Sanber Vizcaya , Felipe Perez Riffo , Juan M. Florez , Eric Súarez Morell

When two BN layers are stacked in parallel in an AB or BA arrangement, a spontaneous out-of-plane electric polarization arises due to charge transfer in the out-of-plane B-N bonds. The ferroelectric switching from AB to BA (or BA to AB) can…

Sliding ferroelectricity is a unique type of polarity recently observed in a properly stacked van der Waals bilayer. However, electric-field control of sliding ferroelectricity is hard and could induce large coercive electric fields and…

Very recently, ferroelectric polarization in staggered bilayer hexagonal boron nitride (BBN) and its novel sliding inversion mechanism was reported experimentally (Science 2021, 372, 1458; 2021, 372, 1462), which paves a new way to realize…

材料科学 · 物理学 2021-12-07 Jie Yang , Jun Zhou , Jing Lu , Zhaochu Luo , Jinbo Yang , Lei Shen

The negatively charged boron vacancy ($\mathrm{V}_{\mathrm{B}}^-$) in hexagonal boron nitride (hBN) has garnered significant attention among defects in two-dimensional materials. This owes, in part, to its deterministic generation,…

With its atomically thin structure and intrinsic ferroelectric properties, heterodeformed bilayer hexagonal boron nitride (hBN) has gained prominence in next-generation non-volatile memory applications. However, studies to date have focused…

材料科学 · 物理学 2026-03-25 Md Tusher Ahmed , Chenhaoyue Wang , Amartya S. Banerjee , Nikhil Chandra Admal

From monolayers composed of different atoms, we can build structures with spontaneous vertical polarization by conveniently stacking multiple layers. We have studied, using first-principles methods and based on modern polarization theory, a…

材料科学 · 物理学 2023-02-24 Emilio A. Cortés , Juan M. Florez , Eric Suárez Morell

Although most two-dimensional (2D) materials are non-ferroelectric with highly symmetric lattices, symmetry breaking may take place in their bilayers upon certain stacking order, giving rise to so-called sliding ferroelectricity where the…

介观与纳米尺度物理 · 物理学 2023-04-10 Liu Yang , Menghao Wu

We undertook an ab-initio study of hexagonal boron nitride (hBN) sandwiched between Ni(111) layers to examine the interface of this material structure. We considered Ni(111)/hBN/Ni(111) with a slab with three Ni atomic layers to determine…

介观与纳米尺度物理 · 物理学 2022-04-15 Halimah Harfah , Yusuf Wicaksono , Muhammad Aziz Majidi , Koichi Kusakabe

Despite progress in HfO2 thin-film ferroelectrics, issues like high coercive fields persist, and the dynamics of twisted ferroelectricity remain largely unexplored. Here, we explore how sliding and twisting in bilayer HfO2 enables low…

材料科学 · 物理学 2025-12-05 Jie Sun , Yiheng Shen , Tengfei Cao , Li-Min Liu

Light-induced sliding ferroelectricity in two-dimensional van der Waals materials enables polarization control via relative layer motion. However, polarization switching occurs on the time scale of shear modes (tens of ps) and requires very…

材料科学 · 物理学 2026-05-26 Xiangzhou Zhu , Stefano Mocatti , Matteo Calandra

In binary compound 2D insulators/semiconductors such as hexagonal boron nitride (hBN), the different electron affinities of atoms can give rise to out-of-plane electric polarizations across inversion asymmetric van der Waals interface of…

介观与纳米尺度物理 · 物理学 2023-09-04 Hongyi Yu , Ziheng Zhou , Wang Yao

When two-dimensional crystals are brought into close proximity, their interaction results in strong reconstruction of electronic spectrum and local crystal structure. Such reconstruction strongly depends on the twist angle between the two…

介观与纳米尺度物理 · 物理学 2025-10-27 C. R. Woods , P. Ares , H. Nevison-Andrews , M. J. Holwill , R. Fabregas , F. Guinea , A. K. Geim , K. S. Novoselov , N. R. Walet , L. Fumagalli

Here, by making use of medium and high resolution autocorrected off-axis electron holography, we directly probe the electrostatic potential as well as in-plane and out-of-plane charge delocalization at edges and steps in multilayer…

The discovery of two-dimensional (2D) ferroelectrics with switchable out-of-plane polarization such as monolayer $\alpha$-In$_2$Se$_3$ offers a new avenue for ultrathin high-density ferroelectric-based nanoelectronics such as ferroelectric…

材料科学 · 物理学 2021-12-01 Jing Wu , Liyi Bai , Jiawei Huang , Liyang Ma , Jian Liu , Shi Liu

Hexagonal boron nitride (hBN) has emerged as a promising two-dimensional platform for quantum sensing, due to its optically addressable spin defects, such as the negatively charged boron vacancy ($V_{\text{B}}^-$). Despite hBN being…

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