相关论文: A gas-phase "top-down" chemical link between aldeh…
In recent years, organic molecules of increasing complexity have been found toward the prolific Galactic center source Sagittarius B2. We wish to explore the degree of complexity that the interstellar chemistry can reach in star-forming…
Gas-phase chemistry at extreme conditions (low densities and temperatures) is difficult, so the presence of interstellar grains is especially important for the synthesis of molecules that cannot form in the gas phase. Interstellar grains…
We report the detection of interstellar methoxymethanol (CH$_3$OCH$_2$OH) in ALMA Bands 6 and 7 toward the MM1 core in the high-mass star-forming region NGC 6334I at ~0.1" - 1" spatial resolution. A column density of 4(2) x $10^{18}$…
We have performed experimental investigations of methanol formation via the reactions of low energy $CH_{3}^{+}$ ions with an amorphous solid water (ASW) surface around 10 K. A newly developed experimental apparatus enabled irradiation of…
The detection of organic molecules with increasing complexity and potential biological relevance is opening the possibility to understand the formation of the building blocks of life in the interstellar medium. One of the families of…
Recent astronomical observations have shown that interstellar complex organic molecules (COMs) exist even in cold environments ($\sim$10 K), while various interstellar COMs have conventionally been detected in the hot gas ($\gtrsim$ 100 K)…
The reactivity of interstellar carbon atoms (C) on the water-dominated ices is one of the possible ways to form interstellar complex organic molecules (iCOMs). In this work, we report a quantum chemical study of the coupling reaction of C…
Ethylene oxide (c-C$_{2}$H$_{4}$O) and its isomer, acetaldehyde (CH$_{3}$CHO), are important complex organic molecules owing to their potential role in the formation of amino acids (R-CH(NH$_{2}$)-COOH) in ISM. The detection of…
The detection of complex organic molecules (COMs) toward dense, collapsing prestellar cores has sparked interest in the fields of astrochemistry and astrobiology, yet the mechanisms for COM formation are still debated. It was originally…
Methyl acetate (CH_3COOCH_3) has been recently observed by IRAM 30 m radio telescope in Orion though the presence of its deuterated isotopomers is yet to be confirmed. We therefore study the properties of various forms of methyl acetate,…
The gas-phase formation and spectroscopic characteristics of ethanimine have been re-investigated as a paradigmatic case illustrating the accuracy of state-of-the-art quantum-chemical (QC) methodologies in the field of astrochemistry.…
Methanol (CH$_3$OH) is at the root of organic ice chemistry in protoplanetary disks. However, its weak emission has made detections difficult. To date, gas-phase CH$_3$OH has been detected in only one Class II disk, TW Hya. We use the…
Mono-deuterated methanol is thought to form during the prestellar core stage of star formation. Observed variations in the CH2DOH/CH3OD ratio suggest that its formation is strongly dependent on the surrounding cloud conditions. Thus, it is…
Determining the level of chemical complexity within dense starless and gravitationally bound prestellar cores is crucial for constructing chemical models, which subsequently constrain the initial chemical conditions of star formation. We…
We present the first detection of ($Z$)-1,2-ethenediol, (CHOH)$_2$, the enol form of glycolaldehyde, in the interstellar medium towards the G+0.693-0.027 molecular cloud located in the Galactic Center. We have derived a column density of…
Methanol is formed via surface reactions on icy dust grains. Methanol is also detected in the gas-phase at temperatures below its thermal desorption temperature and at levels higher than can be explained by pure gas-phase chemistry. The…
Interstellar complex organic molecules (iCOMs) are assumed to be mainly formed on dust-grain surfaces. However, neutral gas-phase reactions in the interstellar medium (ISM) can play an important role. In this paper, by investigating the…
Methanol is one of the most abundant interstellar Complex Organic Molecules (iCOMs) and it represents a major building block for the synthesis of increasingly complex oxygen-containing molecules. The reaction between protonated methanol and…
The circumstellar environments of objects on the asymptotic giant branch and beyond are rich in molecular species. Nevertheless, methanol has never been detected in such an object, and is therefore often taken as a clear signpost for a…
Complex organic molecules (COMs) have been identified toward high- and low-mass protostars as well as molecular clouds, suggesting that these interstellar species originate from the early stage(s) of starformation. The reaction pathways…