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Numerical calculations of the sensitivity coefficients, Q_mu, of microwave molecular transitions in the ground torsion-rotation state of deuterated methanol (CH3OD, CD3OH, and CD3OD) to small variations in the fundamental physical constant…

We report on the using of torsion-rotational transitions in the CH3OH and (13)CH3OH molecules to evaluate possible variations of the physical constant mu=m_e/m_p - the electron-to-proton mass ratio - from spectral observations of emission…

Microwave and submillimeter molecular transition frequencies between nearly degenerated rotational levels, tunneling transitions, and mixed tunneling-rotational transitions show an extremely high sensitivity to the values of the…

We determine the sensitivity to a possible variation of the proton-to-electron mass ratio \mu for torsion-wagging-rotation transitions in the ground state of methylamine (CH3NH2). Our calculation uses an effective Hamiltonian based on a…

The possible cosmological variation of the proton-to-electron mass ratio was estimated by measuring the H_2 wavelengths in the high-resolution spectrum of the quasar Q~0347-382. Our analysis yielded an estimate for the possible deviation of…

Aims. To validate the Einstein equivalence principle (local position invariance) by limiting the fractional changes in the electron-to-proton mass ratio, mu = m_e/m_p, measured in Galactic plane objects. Methods. High resolution spectral…

We estimate sensitivity coefficients Q_\mu to variation of the electron-to-proton mass ratio \mu for microwave transitions in partly deuterated ammonia NH2D and ND2H. Because of the mixing between rotational and inversion degrees of freedom…

The Standard Model of particle physics assumes that the so-called fundamental constants are universal and unchanging. Absorption lines arising in molecular clouds along quasar sightlines offer a precise test for variations in the…

In this paper, we show that methanol (CH3OH) torsional-rotational transitions, which have increased sensitivity to small variations of mu - the electron-to-proton mass ratio, are shifted relative to less sensitive transitions in the…

We report on new tests that improve our previous (2009-2010) estimates of the electron-to-proton mass ratio variation, mu = m_e/m_p. Subsequent observations (2011-2013) at the Effelsberg 100-m telescope of a sample of eight molecular cores…

A limit on a possible cosmological variation of the proton-to-electron mass ratio $\mu$ is derived from methanol (CH$_3$OH) absorption lines in the benchmark PKS1830$-$211 lensing galaxy at redshift $z = 0.89$ observed with the Effelsberg…

The variation of the dimensionless fundamental physical constant mu=m_p/m_e can be checked through observation of Lyman and Werner lines of molecular hydrogen in the spectra of distant QSOs. Our intention is to asses the accuracy of the…

Near (~100 pc) and far (~8.7 kpc) relative to the Galactic center, the molecular clouds SgrB2(N) and Orion-KL exhibit different values of the fundamental physical constant mu=m_e/m_p - the electron-to-proton mass ratio. Measured frequency…

Ethylene glycol in its ground conformation has tunneling transition with the frequency about 7 GHz. This leads to a rather complicated tunneling-rotational spectrum. Because tunneling and rotational energies have different dependence on the…

We present a strong constraint on variation of the proton-to-electron mass ratio, mu, over cosmological time scales using molecular hydrogen transitions in optical quasar spectra. Using high quality spectra of quasars Q0405-443, Q0347-383…

The possibility of using astrophysical observations of rotational transitions in the methanol molecule to measure, or constrain temporal and spatial variations in the proton-to-electron mass ratio (mu) has recently been investigated by…

Torsion-rotation transitions in molecules exhibiting hindered internal rotation possess enhanced sensitivities to a variation of the proton-to-electron mass ratio. This enhancement occurs due to a cancellation of energies associated with…

Exotic cosmologies predict variability of the fundamental physical constants over the cosmic time. Using the VLT/UVES high resolution spectra of the quasar Q0347-3819 and unblended electronic - vibrational - rotational lines of the H2…

Transitions in atoms and molecules provide an ideal test ground for constraining or detecting a possible variation of the fundamental constants of nature. In this Perspective, we review molecular species that are of specific interest in the…

Spatial and temporal variations in the electron-to-proton mass ratio, mu, and in the fine-structure constant, alpha, are predicted in non-Standard models aimed to explain the nature of dark energy. Among them the so-called chameleon-like…