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We report experimental discovery of tantalum polyhydride superconductor. It was synthesized at high pressure and high temperature conditions using diamond anvil cell combined with in-situ high pressure laser heating techniques. The…

Hydrides have long been considered promising candidates for achieving room-temperature superconductivity; however, the extremely high pressures typically required for high critical temperatures remain a major challenge in experiment. Here,…

Lanthanum hydrides, containing hydrogen framework structures under compression, display a superconducting state with a high observed critical temperature. However, this phenomenon has so far only been observed at very high pressures. Here,…

超导电性 · 物理学 2023-06-16 Hao Song , Zihan Zhang , Tian Cui2 , Chris J. Pickard , Vladimir Z. Kresin , Defang Duan

Evolutionary searches predicted a number of ternary phases that could be synthesized at pressures of 100-300~GPa. $P6_3/mmc$ CaSH$_2$, $Pnma$ CaSH$_2$, $Cmc2_1$ CaSH$_6$, and $I\bar{4}$ CaSH$_{20}$ were composed of a Ca-S lattice along with…

超导电性 · 物理学 2021-01-01 Yan Yan , Tiange Bi , Nisha Geng , Xiaoyu Wang , Eva Zurek

For seven decades by A-15 superconductors we meant metallic $A_3B$ alloys (where A is a transition metal, and B is groups IIIB and IVB element) discovered by Hardy and Hulm (Phys. Rev. 89, 884 (1953)). Nb3Ge exhibited the highest…

超导电性 · 物理学 2024-08-20 E. F. Talantsev , V. V. Chistyakov

In the search for high-temperature superconductivity in hydrides, a plethora of multi-hydrogen superconductors have been theoretically predicted, and some have been synthesized experimentally under ultrahigh pressures of several hundred…

Covalent and ionic polyhydrides have become the two main camps in searching for the high-temperature superconductors under pressure. They have been considered as important platforms for exploring ternary or multiple hydrides in order to…

超导电性 · 物理学 2023-05-31 Wuhao Chen , Xiaoli Huang , Dmitrii V. Semenok , Su Chen , Kexin Zhang , Artem R. Oganov , Tian Cui

Milestone experimental discovery of superconductivity above 200 K in highly-compressed sulphur hydride by Drozdov (Nature 525, 73 (2015)) sparked experimental and theoretical investigations of metallic hydrides. Since then, a dozen of…

超导电性 · 物理学 2021-11-16 E. F. Talantsev

Room temperature superconductivity has been achieved under high pressure in an organically derived carbonaceous sulfur hydride with a critical superconducting transition temperature (Tc) of 288 kelvin. This development is part of a new…

The discovery of superconductivity in $\mathrm{YH_{9}}$ with a critical temperature of approximately $T_c\sim 243 \ K$ has opened a new window toward room temperature superconductivity. In this work, we employ the lowest order constrained…

超导电性 · 物理学 2025-10-14 M. A. Rastkhadiv

Hydrogen-based superconductors provide a route to the long-sought goal of room-temperature superconductivity, but the high pressures required to metallize these materials limit their immediate application. For example, carbonaceous sulfur…

The measurement of superconductivity at above 200K in compressed samples of hydrogen sulfide and lanthanum hydride at 250K is reinvigorating the search for conventional high temperature superconductors. At the same time it exposes a…

超导电性 · 物理学 2019-10-02 Chris J. Pickard , Ion Errea , Mikhail I. Eremets

At present, hydrogen-based compounds constitute one of the most promising classes of materials for applications as a phonon-mediated high-temperature superconductors. Herein, the behavior of the superconducting phase in tellurium hydride…

The discovery of a record high superconducting transition temperature (Tc) of 288 K in a pressurized hydride inspires new hope to realize ambient condition superconductivity. Here, we give a perspective on the theoretical and experimental…

超导电性 · 物理学 2021-12-21 Dong Wang , Yang Ding , Ho-Kwang Mao

Crystal structure searching and ab initio calculations have been used here to explore low-energy structures of boron carbides under high pressure. Under pressures of 85-110 GPa, a metastable B6C with R-3m symmetry is found to be…

材料科学 · 物理学 2018-01-01 Kang Xia , Mengdong Ma , Cong Liu , Hao Gao , Qun Chen , Julong He , Jian Sun , Hui-Tian Wang , Yongjun Tian , Dingyu Xing

In recent years, the resistance signature of the high temperature superconductivity above 250 K in highly compressed hydrides (more than 100 GPa) has garnered significant attention within the condensed matter physics community. This has…

The discovery of novel high-temperature superconductor materials holds transformative potential for a wide array of technological applications. However, the combinatorially vast chemical and configurational search space poses a significant…

超导电性 · 物理学 2025-02-25 Xiaoyang Wang , Chengqian Zhang , Zhenyu Wang , Hanyu Liu , Jian Lv , Han Wang , Weinan E , Yanming Ma

Recently a big number of works devoted to search for new hydrides with record high-temperature superconductivity and at the same time the successful synthesis of potential high-TC superconducting FeH5 was reported. We present a systematic…

超导电性 · 物理学 2018-02-20 Alexander G. Kvashnin , Ivan A. Kruglov , Dmitrii V. Semenok , Artem R. Oganov

Hydrogen-rich compounds hold promise as high-temperature superconductors under high pressures. Recent theoretical hydride structures on achieving high-pressure superconductivity are composed mainly of H2 fragments. Through a systematic…

计算物理 · 物理学 2012-04-30 Hui Wang , John S. Tse , Kaori Tanaka , Toshiaki Iitaka , Yanming Ma

Searching for superconducting hydrides has so far largely focused on finding materials exhibiting the highest possible critical temperatures ($T_c$). This has led to a bias towards materials stabilised at very high pressures, which…

超导电性 · 物理学 2020-04-29 Michael J. Hutcheon , Alice M. Shipley , Richard J. Needs