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We investigate the quantum dynamics of energy and charge transfer in a wheel-shaped artificial photosynthetic antenna-reaction center complex.This complex consists of six light-harvesting chromophores and an electron-acceptor fullerene. To…

生物物理 · 物理学 2015-05-28 Pulak Kumar Ghosh , Anatoly Yu. Smirnov , Franco Nori

Photochromic molecular structures constitute a unique platform for constructing molecular switches, sensors and memory devices. One of their most promising applications is as light-switchable electron acceptor or donor units. Here, we…

化学物理 · 物理学 2020-07-21 Jakub K. Sowa , Emily A. Weiss , Tamar Seideman

Research into the efficiency of photosynthetic light harvesting has focused on two factors: (1) entanglement of chromophores, and (2) environmental noise. While chromophores are conjugated $\pi$-bonding molecules with strongly correlated…

生物物理 · 物理学 2013-03-29 David A. Mazziotti

Advancing the debate on quantum effects in light-initiated reactions in biology requires clear identification of non-classical features that these processes can exhibit and utilise. Here we show that in prototype dimers present in a variety…

量子物理 · 物理学 2014-01-10 Edward J. O'Reilly , Alexandra Olaya-Castro

We report here the experimental observation of a dynamical quantum phase transition in a strongly interacting open photonic system. The system studied, comprising a Jaynes-Cummings dimer realized on a superconducting circuit platform,…

量子物理 · 物理学 2016-04-07 James Raftery , Darius Sadri , Sebastian Schmidt , Hakan E. Türeci , Andrew A. Houck

Precise synchronization between transmitter and receiver is crucial for quantum communication protocols, such as Quantum Key Distribution (QKD), to efficiently correlate the transmitted and received signals and increase the signal-to-noise…

A Hamiltonian based approach using spatially localized projection operators is introduced to give precise meaning to the chemically intuitive idea of the electronic energy on a quantum subsystem. This definition facilitates the study of…

量子物理 · 物理学 2015-06-11 Yaser R. Khan , Paul Brumer

Several recent studies of energy transfer in photosynthetic light harvesting complexes have revealed a subtle interplay between coherent and decoherent dynamic contributions to the overall transfer efficiency in these open quantum systems.…

量子物理 · 物理学 2015-05-14 Mohan Sarovar , Yuan-Chung Cheng , K. Birgitta Whaley

Ultrafast photoinduced dynamics of electronic excitation in molecular dimers is drastically affected by the dynamic reorganization of inter- and intra- molecular nuclear configuration modeled by a quantized nuclear degree of freedom [Cina…

数学物理 · 物理学 2009-11-10 Dmitri S. Kilin , Yuri V. Pereversev , Oleg V. Prezhdo

We explore the environment-induced synchronization phenomenon in two-level systems in contact with a thermal dissipative environment. We first discuss the conditions under which synchronization emerges between a pair of two-level particles.…

量子物理 · 物理学 2020-04-24 G. Karpat , İ. Yalçınkaya , B. Çakmak

In natural light harvesting systems, the sequential quantum events of photon absorption by specialized biological antenna complexes, charge separation, exciton formation and energy transfer to localized reaction centers culminates in the…

量子物理 · 物理学 2014-11-25 A. Thilagam

Understanding the mechanism through which an open quantum system exchanges information with an environment is central to the creation and stabilization of quantum states. This theme has been explored recently, with attention mostly focused…

量子物理 · 物理学 2023-02-22 R. Gutiérrez-Jáuregui , A. Asenjo-Garcia , G. S. Agarwal

In this paper, we delve into the issue of Quantum Synchronization in a driven two-level (qubit) system situated within a structured environment. Our findings have practical implications as we discover that adding a time-dependent periodic…

量子物理 · 物理学 2024-12-19 Amir Hossein Houshmand Almani , Ali Mortezapour , Alireza Nourmandipour

To investigate the effect of quantum coherence on electronic energy transfer, which is the subject of current interest in photosynthesis, we solve the problem of transport for the simplest model of an aggregate of monomers interacting…

量子物理 · 物理学 2015-03-19 J. S. Briggs , A. Eisfeld

The conversion of an absorbed photon from the exciton energy into the reaction centre in the photosynthetic complex has a near unit efficiency. It is becoming clear that any classical model, where the exciton hopping is modeled by a…

量子物理 · 物理学 2010-06-21 Vlatko Vedral , Tristan Farrow

The question of how quantum coherence facilitates energy transfer has been intensively debated in the scientific community. Since natural and artificial light-harvesting units operate under the stationary condition, we address this question…

化学物理 · 物理学 2020-07-22 Pei-Yun Yang , Jianshu Cao

Transport phenomena in photosynthetic systems have attracted a great deal of attention due to their potential role in devising novel photovoltaic materials. In particular, energy transport in light-harvesting complexes is considered quite…

Transport of excitons through transfer networks is a unique example where the interplay between quantum coherence and environment-induced dephasing leads to non-trivial effects. One exciting example is the "environment-assisted quantum…

生物物理 · 物理学 2020-05-12 Elinor Zerah-Harush , Yonatan Dubi

We describe vacuum fluctuations and photon-field correlations in interacting quantum mechanical light-matter systems, by generalizing the application of mixed quantum-classical dynamics techniques. We employ the multi-trajectory…

量子物理 · 物理学 2019-06-26 Norah M. Hoffmann , Christian Schäfer , Angel Rubio , Aaron Kelly , Heiko Appel

Diffusional dynamics of the donor-acceptor distance in electron-transfer reactions are responsible for the appearance of a new time scale of diffusion over the distance of falloff of electronic tunneling. The distance dynamics compete with…

生物物理 · 物理学 2022-09-21 Dmitry V. Matyushov