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The photogalvanic effect (PGE) occurring in noncentrosymmetric materials enables the generation of a dc photocurrent at zero bias with a high polarization sensitivity, which makes it very attractive in photodetection. However, the magnitude…

应用物理 · 物理学 2021-06-28 Liyu Qian , Juan Zhao , Yiqun Xie

Ferroelectric photovoltaics (FPVs) have drawn much attention owing to their high stability, environmental safety, anomalously high photovoltages, coupled with reversibly switchable photovoltaic responses. However, FPVs suffer from extremely…

Structurally chiral materials hosting multifold fermions with large topological number have attracted considerable attention because of their naturally long surface Fermi arcs and bulk quantized circular photogalvanic effect (CPGE).…

材料科学 · 物理学 2019-12-25 Yang Zhang , Fernando de Juan , Adolfo G. Grushin , Claudia Felser , Yan Sun

The connection between noncentrosymmetric materials' structure, electronic structure, and bulk photovoltaic performance remains not well understood. In particular, it is still unclear which photovoltaic (PV) mechanism(s) are relevant for…

材料科学 · 物理学 2015-05-20 Fenggong Wang , Andrew M. Rappe

Shift current---a photocurrent induced by light irradiating noncentrosymmetric materials in the absence of any bias voltage or built-in electric field---is one of the mechanisms of the so-called bulk photovoltaic effect. It has been…

介观与纳米尺度物理 · 物理学 2019-03-28 U. Bajpai , B. S. Popescu , P. Plechac , B. K. Nikolic , L. E. F. Foa Torres , H. Ishizuka , N. Nagaosa

Ferroelectrics with suitable band gaps have recently attracted attention as candidate solar absorbing materials for photovoltaics. The inversion symmetry breaking may promote the separation of photo-excited carriers and allow voltages…

材料科学 · 物理学 2017-12-06 Yuwei Li , David J. Singh

Photogalvanic effect (PGE) occurring in noncentrosymmetric materials enables the generation of the open-circuit voltage that is much larger than the bandgap, making it rather attractive in solar cells. However, the magnitude of the PGE…

应用物理 · 物理学 2020-08-11 Juan Zhao , Yibin Hu , Yiqun Xie , Lei Zhang , Yin Wang

Integrated photodetectors are crucial for their high speed, sensitivity, and efficient power consumption. In these devices, photocurrent generation is primarily attributed to the photovoltaic (PV) effect, driven by electron hole…

Broadband, efficient and fast conversion of light to electricity is crucial for sensing and clean energy. Here we reveal the largest observed bulk photo-voltaic effect (BPVE), an intrinsic mechanism predicted to be ultrafast and exceed the…

The rectified bulk photovoltaic effect (BPVE) in noncentrosymmetric semiconductors, also called shift current, is considered promising for optoelectronic devices, terahertz emission and possibly solar energy harvesting. A clear…

材料科学 · 物理学 2025-02-11 Urmimala Dey , Jeroen van den Brink , Rajyavardhan Ray

We report nearly single phase Pb(Zr0.14Ti0.56Ni0.30)O3-delta(PZTNi30) ferroelectric having large remanent polarization (15-30 {\mu}C/cm2), 0.3-0.4 V open circuit voltage (VOC), reduced band gap (direct 3.4 eV, and indirect 2.9 eV), large ON…

材料科学 · 物理学 2014-03-04 Shalini Kumari , Nora Ortega , Ashok Kumar , J. F. Scott , R. S. Katiyar

Q. Ma et al.[1] recently reported a strong photocurrent associated with charge neutrality in graphene devices with non-uniform geometries, which they interpreted as an intrinsic photoresponse enhanced by the momentum non-relaxing nature of…

介观与纳米尺度物理 · 物理学 2020-02-26 Michael S. Fuhrer , Nikhil V. Medhekar

The bulk photovoltaic effect (BPVE), a manifestation of broken centrosymmetry, has attracted interest as a probe of the symmetry and quantum geometry of materials, and for use in novel optoelectronic devices. Despite its bulk nature, the…

Two-dimensional (2D) ferroelectrics offer the potential for ultrathin flexible nanoelectronics, typically utilizing a metal-ferroelectric-metal sandwich structure as the functional unit. Electrodes can either contribute free carriers to…

材料科学 · 物理学 2023-11-17 Jiawei Huang , Changming Ke , Zhuang Qian , Shi Liu

This paper presents a study of dc photocurrents in biased insulators to the third order in the electric field. We find three photocurrents which are characterized by physical divergences of the third-order free-electron polarization…

介观与纳米尺度物理 · 物理学 2019-08-07 Benjamin M. Fregoso

The bulk photovoltaic effect (BPVE) is a phenomenon which creates a net electrical current from sunlight in a polar noncentrosymmetric material possessing a moderate band gap. This effect is being explored as an alternative to traditional…

材料科学 · 物理学 2018-02-14 John A. Brehm

Through stacking engineering of two-dimensional (2D) materials, a switchable interface polarization can be generated through interlayer sliding, so called sliding ferroelectricity, which is advantageous over the traditional ferroelectricity…

材料科学 · 物理学 2024-08-01 Qingrong Liang , Guozhong Zheng , Liu Yang , Shoujun Zheng

Halide perovskites have emerged as promising materials for next-generation photovoltaics, laser sources and X-ray detectors. There is intense debate as to whether some photoactive halide perovskites exhibit ferroelectric behaviour and…

材料科学 · 物理学 2026-01-21 Weilun Li , Qimu Yuan , Michael B. Johnston , Joanne Etheridge

Optimal materials to induce bulk photovoltaic effects should lack inversion symmetry and have an optical gap matching the energies of visible radiation. Ferroelectric perovskite oxides such as BaTiO$_3$ and PbTiO$_3$ exhibit substantial…

材料科学 · 物理学 2017-08-21 Hanghui Chen , Andrew J. Millis

Recently, two-dimensional materials and in particular transition metal dichalcogenides (TMDs) were extensively studied because of their strong light-matter interaction and the remarkable optoelectronic response of their field-effect…