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相关论文: Superionicity in Ammonium Polyhydrides at Extreme …

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In the last decade, there has been great progress in predicting and synthesizing polyhydrides that exhibit superconductivity when squeezed. Dopants allow these compounds to become metals at pressures lower than those required to metallize…

材料科学 · 物理学 2024-05-21 Xiaoyu Wang , Nisha Geng , Kyla de Villa , Burkard Militzer , Eva Zurek

Ammonia is predicted to be one of the major components in the depths of the ice giant planets Uranus and Neptune. Their dynamics, evolution, and interior structure are insufficiently understood and models rely imperatively on data for…

High pressure structures, phase diagram and superconductivity of polonium hydrides have been systematically investigated through the first-principles calculations based on the density functional theory. With the increasing pressure, several…

Metallic hydrogen, existing in remarkably extreme environments, was predicted to exhibit long-sought room-temperature superconductivity. Although the superconductivity of metallic hydrogen has not been confirmed experimentally,…

超导电性 · 物理学 2024-06-12 Zihan Zhang , Wendi Zhao , Defang Duan , Tian Cui

Hydrogen and lithium, along with their compounds, are crucial materials for nuclear fusion research. High-pressure studies have revealed intricate structural transitions in all these materials. However, research on lithium hydrides beyond…

材料科学 · 物理学 2024-02-27 Fude Li , Hao Wang , Jinlong Li , Hua Y. Geng

We investigate via quantum molecular-dynamics simulations the thermophysical properties of shocked liquid ammonia up to the pressure 1.3 TPa and temperature 120000 K. The principal Hugoniot is predicted from wide-range equation of state,…

材料科学 · 物理学 2015-06-16 Dafang Li , Ping Zhang , Jun Yan

Superionic states are phases of matters that can simultaneously exhibit some of the properties of a fluid and of a solid. Superionic states of ice, H$_{3}$O, He-H$_{2}$O or He-NH$_{3}$ compounds have been reported in previous works.…

材料科学 · 物理学 2020-11-24 Tianxiao Liang , Zihan Zhang , Hongyu Yu , Tian Cui , Chris J. Pickard , Defang Duan

Metallic hydrogen is expected to exhibit remarkable physics. Of particular interest in this work is the possibility of high-temperature superconductivity. Comparing calculations of the superconducting critical temperatures of the solid…

超导电性 · 物理学 2021-07-02 Craig M. Tenney , Zachary F. Croft , Jeffrey M. McMahon

The theoretical exploration of the phase diagrams of binary hydrides under pressure using \emph{ab initio} crystal structure prediction techniques coupled with first-principles calculations has led to the \emph{in silico} discovery of…

超导电性 · 物理学 2019-02-25 Eva Zurek , Tiange Bi

Using density functional molecular dynamics simulations, we study the behavior of different hydrogen-oxygen compounds at megabar pressures and several thousands of degrees Kelvin where water has been predicted to occur in superionic form.…

材料科学 · 物理学 2018-08-01 Burkhard Militzer , Shuai Zhang

Understanding the behavior of the water-ammonia system at high pressure-high temperature conditions is important for modeling the internal dynamics of exoplanet icy mantles. Conventionally, mixtures of ammonia hemihydrate AHH (2:1…

Noble metals adopt close-packed structures at ambient pressure and rarely undergo structural transformation at high pressures. Platinum (Pt), in particular, is normally considered to be unreactive and is therefore not expected to form…

超导电性 · 物理学 2015-03-19 Duck Young Kim , Ralph H. Scheicher , Chris J. Pickard , R. J. Needs , R. Ahuja

The current search for room-temperature superconductivity is inspired by the unique properties of the electron-phonon interaction in metal superhydrides. Encouraged by the recently found highest-$T_C$ superconductor fcc-$LaH_{10}$, here we…

The only known compound of sodium and hydrogen is archetypal ionic NaH. Application of high pressure is known to promote states with higher atomic coordination, but extensive searches for polyhydrides with unusual stoichiometry remain…

We employed a machine-learning assisted approach to search for superconducting hydrides under ambient pressure within an extensive dataset comprising over 150 000 compounds. Our investigation yielded around 50 systems with transition…

超导电性 · 物理学 2024-03-21 Tiago F. T. Cerqueira , Yue-Wen Fang , Ion Errea , Antonio Sanna , Miguel A. L. Marques

Experiments and computer simulations have shown that the melt-ing temperature of solid hydrogen drops with pressure above about 65 GPa, suggesting that a liquid state might exist at low temperatures. It has also been suggested that this low…

High-pressure metal superhydrides have attracted intense scientific interest due to their remarkable superconducting properties. While superconductivity is known to be sensitive to material composition, compositional variability is often…

超导电性 · 物理学 2025-04-04 Xixi Jia , Haoran Chen , Xiaoqiu Ye , Jian Lv , Xitian Zhang , Hui Wang , Yansun Yao

Hydrogen exhibits unusual behaviors at megabar pressures, with consequences for planetary science, condensed matter physics and materials science. Experiments at such extreme conditions are challenging, often resulting in hard-to-interpret…

材料科学 · 物理学 2022-01-05 Bingqing Cheng , Guglielmo Mazzola , Michele Ceriotti

Metallic hydrogen is capable of showing room temperature superconductivity, but its experimental syntheses are extremely hard. Therefore, it is desirable to reduce the synthesis pressure of metallic hydrogen by adding other chemical…

超导电性 · 物理学 2022-11-23 Zhongyu Wan , Ruiqin Zhang

Water is abundant in natural environments but the form it resides in planetary interiors remains uncertain. We report combined synchrotron X-ray diffraction and optical spectroscopy measurements of H2O in the laser-heated diamond anvil cell…

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