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This paper presents the current state of mathematical modelling of the electrochemical behaviour of lithium-ion batteries as they are charged and discharged. It reviews the models developed by Newman and co-workers, both in the cases of…

化学物理 · 物理学 2020-02-04 Giles W Richardson , Jamie M Foster , Rahifa Ranom , Colin P Please , Angel M Ramos

The pseudo-4D Doyle-Fuller-Newman (DFN) model enables predictive simulation of lithium-ion batteries with three-dimensional electrode architectures and particle-scale diffusion, extending the standard pseudo-2D (P2D) formulation to fully…

Li-ion rechargeable batteries have enabled the wireless revolution transforming global communication. Future challenges, however, demands distributed energy supply at a level that is not feasible with the current energy-storage technology.…

The Doyle-Fuller-Newman (DFN) model is a common mechanistic model for lithium-ion batteries. The reaction rate constant and diffusivity within the DFN model are key parameters that directly affect the movement of lithium ions, thereby…

系统与控制 · 电气工程与系统科学 2025-04-15 Marc D. Berliner , Minsu Kim , Xiao Cui , Vivek N. Lam , Patrick A. Asinger , Martin Z. Bazant , William C. Chueh , Richard D. Braatz

Recently, considerable efforts have been made on research and improvement for Ni-rich lithium-ion batteries to meet the demand from vehicles and grid-level large-scale energy storage. Development of next-generation high-performance…

A full lithium-ion-sulfur cell with a remarkable cycle life was achieved by combining an environmentally sustainable biomass-derived sulfur-carbon cathode and a pre-lithiated silicon oxide anode. X-ray diffraction, Raman spectroscopy,…

Designing lithium-ion batteries for long service life remains a challenge, as most cells are optimized for beginning-of-life metrics such as energy density, often overlooking how design and operating conditions shape degradation. This work…

An important objective of designing lithium-ion rechargeable battery cells is to maximize their rate performance without compromising the energy density, which is mainly achieved through computationally expensive numerical simulations at…

材料科学 · 物理学 2020-05-05 Fan Wang , Ming Tang

Charge unbalance is one of the key issues for series-connected Lithium-ion cells. Within this context, model-based optimization strategies have proven to be the most effective. In the present paper, an ad-hoc electrochemical model, tailored…

系统与控制 · 计算机科学 2019-02-07 Andrea Pozzi , Massimo Zambelli , Antonella Ferrara , Davide Martino Raimondo

We build a transient multidimensional multiphysical model based on continuum theories, involving the coupled mechanical, thermal and electrochemical phenomena occurring simultaneously in the discharge or charge of lithium-ion batteries. The…

数值分析 · 数学 2024-03-26 Jaime Mora-Paz

DandeLiion (available at dandeliion.com) is a robust and extremely fast solver for the Doyle Fuller Newman (DFN) model, the standard electrochemical model for (dis)charge of a planar lithium-ion cell. DandeLiion conserves lithium, uses a…

应用物理 · 物理学 2021-08-20 Ivan Korotkin , Smita Sahu , Simon O'Kane , Giles Richardson , Jamie M. Foster

We propose fabrication of the fiber-shaped lithium ion batteries assembled by twisting a cathode filament together with an anode filament. The cathode filament is fabricated by depositing a LiFePO4 (LFP)-composite layer onto a steel-filled…

应用物理 · 物理学 2018-01-16 Hang Qu , Xin Lu , Maksim Skorobogatiy

Electrolyte filling is a time-critical step during battery manufacturing that also affects the battery performance. The underlying physical phenomena during filling mainly occur on the pore scale and are hard to study experimentally. In…

The unified 3D phase-field model for the description of the lithium-ion cell as a whole is developed. The model takes into account the realistic distribution of particles in porous electrodes, percolative transport of ions, and the…

无序系统与神经网络 · 物理学 2021-05-11 Pavel E. L'vov , Mikhail Yu. Tikhonchev , Renat T. Sibatov

Inspired by a freshly synthesized two-dimensional biphenylene carbon network, which features a captivating combination of hexagonal, square, and octagonal rings, we explored a similar biphenylene network composed of boron, carbon, and…

材料科学 · 物理学 2024-10-14 Ajay Kumar Prakash Parida

Lithium-air batteries have been considered as ultimate solutions for the power source of long-range electrified transportation, but state-of-the-art prototypes still suffer from short cycle life, low efficiency and poor power output. Here,…

化学物理 · 物理学 2016-03-24 Peng Bai , Martin Z. Bazant

Distributions of potential and lithium content inside lithium ion batteries highly affects their performance and durability. An increased heterogeneity of the lithium distribution is expected in thick electrodes with high energy densities…

A Li-conversion alpha-Fe2O3@C nanocomposite anode and a high-voltage LiNi0.5Mn1.5O4 cathode are synthesized in parallel, characterized, and combined in a Li-ion battery. alpha-Fe2O3@C is prepared via annealing of maghemite iron oxide and…

化学物理 · 物理学 2021-10-27 Shuangying Wei , Daniele Di Lecce , Riccardo Messini D'Agostini , Jusef Hassoun

Fast charging of lithium-ion batteries is limited by lithium plating, which occurs when the anode potential drops below 0 V vs Li/Li+. Model-based control aims to maximize charging current while maintaining anode potentials above this…

系统与控制 · 电气工程与系统科学 2026-05-19 Alessio Alberto Lodge , Alessio Lombardo Pontillo , Feye S. J. Hoekstra , Robinson Medina , Steven Wilkins , Ilenia Battiato

Currently, the characterization of electric energy storage units used for power system operation and planning models relies on two major assumptions: charge and discharge efficiencies, and power limits are constant and independent of the…

系统与控制 · 电气工程与系统科学 2024-12-20 Alvaro Gonzalez-Castellanos , David Pozo , Aldo Bischi
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