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Rb2SnCu3F12 has been studied using synchrotron powder X-ray diffraction, powder neutron diffraction and single crystal X-ray diffraction at a range of temperatures (100 to 500 K). A broad but clear phase transition, possibly of re-entrant…

强关联电子 · 物理学 2013-08-22 Lewis J. Downie , Stephen P. Thompson , Chiu C. Tang , Simon Parsons , Philip Lightfoot

A Raman scattering spectroscopy study is reported through all four phases of a (K0.5Na0.5)NbO3 crystal and ((K0.5Na0.5)1-xLix)NbO3 for x=0.02 and 0.03. The transitions among the ferroelectric phases in the Li-free crystal are homogeneous…

材料科学 · 物理学 2009-11-13 H. J. Trodahl , N. Klein , D. Damjanovic , N. Setter , B. Ludbrook , D. Rytz , M. Kuball

The structural phase transformations of 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 (PMN-30%PT) have been studied using x-ray diffraction (XRD) and neutron scattering as a function of temperature and electric field. We observe the phase transformational…

材料科学 · 物理学 2009-11-10 Feiming Bai , Naigang Wang , Jiefang Li , D. Viehland , P. M. Gehring , Guangyong Xu , G. Shirane

Pure electronic Raman spectra with no phonon structures superimposed to the electronic continuum, are reported, in optimally doped HgBa_{2}CaCu_{2}O_{6+\delta } single crystals (T_{c }=126 K). As a consequence, the spectra in the A_{1g },…

超导电性 · 物理学 2009-10-28 A. Sacuto , R. Combescot , N. Bontemps , P. Monod , V. Viallet , D. Colson

The polarized Raman scattering spectra from freshly cleaved $ab$, $ac$, and $bc$ surfaces of high quality twin free YBa$_2$Cu$_3$O$_{6.5}$ (Ortho-II) single crystals ($T_c$=57.5 K and $\Delta T = 0.6$ K) were studied between 80 and 300 K.…

超导电性 · 物理学 2008-03-14 M. N. Iliev , V. G. Hadjiev , S. Jandl , D. Le Boeuf , V. N. Popov , D. Bonn , R. Liang , W. N. Hardy

We report on an inelastic (Raman) light scattering study of the local structure of amorphous GeTe films. A detailed analysis of the temperature-reduced Raman spectra has shown that appreciable structural changes occur as a function of…

In the present study, structural changes due to gradual doping of Sr in BaTiO3 were investigated by both x-ray and neutron powder diffraction techniques. Ba1-xSrxTiO3 (x=0.0, 0.5 and 1.0) samples were synthesized by PVA evaporation method…

材料科学 · 物理学 2020-07-03 I. B. Elius , B. M. Asif , J. Maudood , T. K. Datta , A. K. M. Zakaria , S. Hossain , M. S. Aktar , I. Kamal

We report direct experimental evidence of antiferroelectric to paraelectric phase transition under pressure in NaNbO3 using neutron diffraction at room temperature. The paraelectric phase is found to stabilize above 8 GPa and its crystal…

材料科学 · 物理学 2015-06-11 S. K. Mishra , M. K. Gupta , R. Mittal , S. L. Chaplot , Thomas Hansen

Chalcogenides materials are being considered as some of the most promising systems for energy harvesting and energy conversion. Among them, the orthorhombic family of compounds X2Y3 (with X= Bi, Sb and Y= S, Se) has attracted special…

The magnetic structure of RuO2 and the Ru atomic configuration are unknown. A magnetic structure is inferred by confronting measured and calculated Bragg diffraction patterns and adjusting the latter to achieve satisfactory agreement. An…

强关联电子 · 物理学 2023-06-22 S. W. Lovesey , D. D. Khalyavin , G. van der Laan

Electronic Raman scattering measurements have been performed on $HgBa_{2}Ca_{2}Cu_{3}O_{8+\delta} $ single crystals in the superconducting state. Pure electronic Raman spectra with no phonon structures hindering the analysis of the…

超导电性 · 物理学 2009-10-31 A. Sacuto , R. Combescot , N. Bontemps , C. A. Müller , V. Viallet , D. Colson

The structure of dielectric perovskite BaZrO$_3$, long known to be cubic at room temperature without any structural phase transition with variation of temperature, has been recently disputed to have different ground state structures with…

Even though, the crystal structure of the intermediate (S') and the equilibrium S (Al2CuMg) phase were subject of many investigations by using mostly imaging or diffraction techniques, the results remain still controversial. In this study,…

材料科学 · 物理学 2019-05-09 Danny Petschke , Frank Lotter , Torsten E. M. Staab

A method is suggested for estimation of structural properties of amorphous fullerene and its derivatives produced by vacuum annealing. The method is based on the fitting of the neutron or x-ray powder diffraction patterns for scattering…

材料科学 · 物理学 2014-12-24 V. S. Neverov , P. A. Borisova , A. B. Kukushkin , V. V. Voloshinov

Ba(Fe$_{1/2}$Nb$_{1/2}$)O$_3$ (BFN) ceramics are considered to be promising for technological applications owing to their high dielectric constant over a wide range of temperatures. However, there exists considerable discrepancy over the…

The mixed crystal of a para-dibromobenzene with a para-chloronitrobenzene is investigated at concentration of components from 0% up to 60% of a para-chloronitrobenzene by the method of Low-Frequency Raman spectroscopy. It is shown, that in…

光学 · 物理学 2007-05-23 M. A. Korshunov

During past years, a number of reports have been published on synthesis of tetragonal allotrope of boron, t-B52 phase. However, no unambiguous characterization of the crystal structure has been performed to the present time, while…

材料科学 · 物理学 2013-02-20 Oleksandr O. Kurakevych , Vladimir L. Solozhenko

Suspended specimens of 2D crystals and their heterostructures are required for a range of studies including transmission electron microscopy (TEM), optical transmission experiments and nanomechanical testing. However, investigating the…

We investigated the crystal structure and lattice excitations of the ternary intermetallic stannide Ca3Ir4Sn13 using neutron and x-ray scattering techniques. For T > T* ~ 38 K the x-ray diffraction data can be satisfactorily refined using…

Crystalline phase structure is essential for understanding the performance and properties of a material. Therefore, this study identified and quantified the crystalline phase structure of a sample based on the diffraction pattern observed…

材料科学 · 物理学 2023-09-27 Ryo Murakami , Yoshitaka Matsushita , Kenji Nagata , Hayaru Shouno , Hideki Yoshikawa
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