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The charge frustration with the mixed-valence state inherent to LiTi$_2$O$_4$, which is found to be a unique spinel oxide superconductor, is the impetus for paying special attention to reveal the existence of intriguing superconducting…

超导电性 · 物理学 2023-01-18 Huanyi Xue , Lijie Wang , Zhongjie Wang , Guanqun Zhang , Wei Peng , Shiwei Wu , Chunlei Gao , Zhenghua An , Yan Chen , Wei Li

The spinel oxide superconductor LiTi2O4 (LTO) is an intriguing material platform where the electronic structure near the Fermi energy (EF) is derived from 3d elections on the geometrically frustrated Ti pyrochlore network. A recent…

This review discusses the multifaceted electronic properties of spinel oxides with a particular focus on Lithium Vanadate (LiV2O4), Lithium Titanate (LiTi2O4), and Magnesium Titanate (MgTi2O4). We selected LiTi2O4, LiV2O4, and MgTi2O4…

材料科学 · 物理学 2025-12-03 Jagadis Prasad Nayak , Raju Saini , Sourav Dash , Gopi Nath Daptary

The existence of rich Fermiology in anomalous metal phase in exotic superconductors has attracted considerable interests, as exemplified in copper, iron-based, and intermetallic frustrated kagome-based compounds. A common feature in these…

Transition-metal oxides offer an opportunity to explore unconventional superconductors, where the superconductivity (SC) is often interrelated with novel phenomena such as spin/charge order, fluctuations, and Fermi surface instability…

The pyrochlore lattice, a three-dimensional network of corner-sharing tetrahedra, is a promising material playground for correlated topological phases arising from the interplay between spin-orbit coupling (SOC) and electron-electron…

The phenomenon of frustration, which gives rise to many fascinating phenomena, is conventionally associated with the topology of non-bipartite lattices, where nearest-neighbor (nn) interactions and global connectivity compete in the…

强关联电子 · 物理学 2009-11-11 J. Kunes , W. E. Pickett

Magnetic systems are fertile ground for the emergence of exotic states when the magnetic interactions cannot be satisfied simultaneously due to the topology of the lattice - a situation known as geometrical frustration. Spinels, AB2O4, can…

强关联电子 · 物理学 2015-05-13 M. Matsuda , H. Ueda , A. Kikkawa , Y. Tanaka , K. Katsumata , Y. Narumi , T. Inami , Y. Ueda , S. -H. Lee

LiTi2O4 is a unique material in that it is the only known oxide spinel superconductor. Although bulk studies have demonstrated that superconductivity can be generally described by the Bardeen-Cooper-Schreiffer theory, the microscopic…

超导电性 · 物理学 2010-05-27 Rajesh V. Chopdekar , Elke Arenholz , Yuri Suzuki

Electronic flat bands associated with quenched kinetic energy and heavy electron mass have attracted great interest for promoting strong electronic correlations and emergent phenomena such as high-temperature charge fractionalization and…

Metastable Co$_2$Ti$_3$O$_8$ was synthesized through a topochemical reaction using Li$_2$CoTi$_3$O$_8$ as the precursor, resulting in a vacancy-ordered spinel structure. Crystal structure analysis confirmed that Co ions selectively occupy…

Among hundreds of spinel oxides, LiTi2O4 (LTO) is the only one that exhibits superconductivity (Tc ~13 K). Although the general electron-phonon coupling is still the main mechanism for electron pairing in LTO, unconventional behaviors such…

Spinel compounds have demonstrated rich functionalities but rarely shown superconductivity. Here, we report the emergence of superconductivity in the spinel $\mathrm{MgTi}_2\mathrm{O}_4$, known to be an insulator with a complicated order.…

Geometric frustration has long been a subject of enduring interest in condensed matter physics. While geometric frustration traditionally focuses on magnetic systems, little attention is paid to the "frustrated superconductivity" which…

超导电性 · 物理学 2025-10-16 Hong-Min Jiang , Wen-Qian Dong , Shun-Li Yu , Z. D. Wang

Magnetic frustration, the competition among exchange interactions, often leads to novel magnetic ground states with unique physical properties which can hinge on details of interactions that are otherwise difficult to observe. Such states…

Neutron scattering measurements have been performed on polycrystalline samples of the newly discovered layered superconductor LaO$_{0.5}$F$_{0.5}$BiS$_{2}$, and its nonsuperconducting parent compound LaOBiS$_{2}$. The crystal structures and…

超导电性 · 物理学 2013-06-17 J. Lee , M. B. Stone , A. Huq , T. Yildrim , G. Ehlers , Y. Mizuguchi , O. Miura , Y. Takano , K. Deguchi , S. Demura , S. -H. Lee

Structural, electronic, and magnetic properties of modified cubic spinel compound LiNi$_{0.5}$Mn$_{1.5}$O$_{4}$ are studied via x-ray diffraction, resistivity, DC and AC magnetization, heat capacity, neutron diffraction, $^7$Li nuclear…

材料科学 · 物理学 2020-12-02 S. S. Islam , Vikram Singh , K Somesh , Prashanta K Mukharjee , A. Jain , S. M. Yusuf , R. Nath

Localized spins and itinerant electrons rarely coexist in geometrically-frustrated spinel lattices. We show that the spinel CoV2O4 stands at the crossover from insulating to itinerant behavior and exhibits a complex interplay between…

强关联电子 · 物理学 2018-07-31 J. H. Lee , J. Ma , S. E. Hahn , H. B. Cao , Tao Hong , M. S. Yeom , S. Okamoto , H. D. Zhou , M. Matsuda , R. S. Fishman

We combine $GW$ plus extended dynamical mean field theory ($GW$+EDMFT) with the density functional theory for superconductors (SCDFT) framework to study the electronic properties of LiTi$_2$O$_4$. Excellent agreement with experiment is…

超导电性 · 物理学 2026-01-27 Francesco Petocchi , Viktor Christiansson , Ryotaro Arita , Philipp Werner

Reproducing the electronic structure of AM$_4$X$_8$ lacunar spinels with a breathing pyrochlore lattice is a great theoretical challenge due to the interplay of various factors. The character of the M$_4$X$_4$ cluster orbitals is critically…

强关联电子 · 物理学 2020-02-20 S. Reschke , F. Meggle , F. Mayr , V. Tsurkan , L. Prodan , H. Nakamura , J. Deisenhofer , C. A. Kuntscher , I. Kézsmárki
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