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In this work we study the stabilization of the orthorhombic phases in small Hf0.5Zr0.5O2 nanoparticles (average size ~ 7 nm) annealed under different oxygen partial pressures. Concentration of the oxygen vacancies, which is determined by…

We reveal a colossal dielectric response of small (5 - 10 nm) oxygen-deficient HfxZr1-xO2 nanoparticles (x = 1 - 0.4), prepared by the solid-state organonitrate synthesis. The effective dielectric permittivity of the pressed HfxZr1-xO2…

Nd_0.67Sr_0.33MnO_3 nanoparticles with the grain size of about 30 nm are prepared by sol-gel method.These nanopowders are annealed at four different temperatures viz. 800 oC, 900 oC, 1000 oC and 1100 oC to study the effect of particle size…

强关联电子 · 物理学 2007-05-23 S. S. Rao , Subhasis Sarangi , G. Venkataiah , Venu Gopala Reddy , S. V. Bhat

Electron paramagnetic resonance (EPR) study of air-physisorbed defective carbon nano-onions evidences in favor of microwave assisted formation of weakly-bound paramagnetic complexes comprising negatively-charged O2- ions and edge carbon…

介观与纳米尺度物理 · 物理学 2016-06-10 D. W. Boukhvalov , V. Yu. Osipov , A. I. Shames , K. Takai , T. Hayashi , T. Enoki

Epitaxial ferroelectric Hf0.5Zr0.5O2 films have been successfully integrated in a capacitor heterostructure on Si(001). The orthorhombic Hf0.5Zr0.5O2 phase, [111] out-of-plane oriented, is stabilized in the films. The films present high…

应用物理 · 物理学 2019-02-15 Jike Lyu , Ignasi Fina , Josep Fontcuberta , Florencio Sánchez

HfO2-based ferroelectric films have attracted considerable attention as their nanoscale ferroelectricity and compatibility with cmos technology, fulfilling demands of emerging memory technologies. However, as films scale down,…

The ambient-temperature high-pressure behaviour of (La0.2Nd0.2Sm0.2Gd0.2Yb0.2)2Zr2O7 zirconate (HEZ) nanopowders with three different average particle sizes (~25nm, ~45 nm and ~ 68nm) were studied using synchrotron X-ray diffraction…

材料科学 · 物理学 2025-06-03 Yogendar Singh , Xinghua Su , Vivek Kumar , H. K. Poswal , K. K. Pandey , Pawan Kumar Kulriya

Lithium doped sodium niobate is an ecofriendly piezoelectric material that exhibits a variety of structural phase transitions with composition and temperature. We have investigated the phase stabilities of an important composition…

The structure of Na0.5CoO2, the low temperature insulator that separates the magnetic and superconducting regions in the NaxCoO2.yH2O phase diagram, is studied by high resolution powder neutron diffraction at temperatures between 10 and 300…

强关联电子 · 物理学 2007-05-23 A. J. Williams , J. P. Attfield , M. L. Foo , R. J. Cava

Study of nanoscale hafnia-zirconia physical properties is the key topic in fundamental and applied science. However, charge transport mechanisms and magnetic properties of hafnia-zirconia nanoparticles are very poorly studied both…

A wake-up free Hf0.5Zr0.5O2 (HZO) ferroelectric film with the highest remnant polarization (Pr) value to-date was achieved through tuning of the ozone pulse duration, the annealing process, and the metal/insulator interface. The ozone…

材料科学 · 物理学 2021-01-14 Alireza Kashir , Hyung Woo Kim , Seungyeol Oh , Hyunsang Hwang

We report on exchange bias effects in 10 nm particles of Pr0.5Ca0.5MnO3 which appear as a result of competing interactions between the ferromagnetic (FM)/anti-ferromagnetic (AFM) phases. The fascinating new observation is the demonstration…

介观与纳米尺度物理 · 物理学 2012-04-05 S. Narayana Jammalamadaka , S. S. Rao , S. V. Bhat , J. Vanacken , V. V. Moshchalkov

Nanoparticles (size 20, 40 and 60 nm) of Pr_0.5Sr_0.5MnO_3 are prepared by sol-gel technique and their magnetic properties are studied using ferromagnetic resonance and magnetization measurements. A comparison with the properties of the…

强关联电子 · 物理学 2007-06-13 S. S. Rao , S. V. Bhat

We present angular dependent EPR measurements in NaV2O5 at X-band frequencies in the temperature range 4.2 K < T < 670 K. A detailed analysis in terms of the antisymmetric Dzyaloshinski-Moriya and the anisotropic exchange interactions…

强关联电子 · 物理学 2009-10-31 M. Lohmann , H. -A. Krug von Nidda , M. V. Eremin , A. Loidl , G. Obermeier , S. Horn

We report direct experimental evidence of antiferroelectric to paraelectric phase transition under pressure in NaNbO3 using neutron diffraction at room temperature. The paraelectric phase is found to stabilize above 8 GPa and its crystal…

材料科学 · 物理学 2015-06-11 S. K. Mishra , M. K. Gupta , R. Mittal , S. L. Chaplot , Thomas Hansen

Electrical transport measurements are used to study the Rh-doped NaFeAs superconductor series with a focus on the tetragonal phase. The resistivity curvature has an anomalous temperature dependence evidencing in the phase diagram two…

Unconventional ferroelectricity, robust at reduced nanoscale sizes, exhibited by hafnia-based thin-films presents tremendous opportunities in nanoelectronics. However, the exact nature of polarization switching remains controversial. Here,…

We present results of an electron paramagnetic resonance (EPR) study of Nd$_{1-x}$Sr$_x$MnO$_3$ with x = 0.5 across the paramagnetic to ferromagnetic, insulator to metal transition at 260 K (T$_c$) and the antiferromagnetic, charge ordering…

强关联电子 · 物理学 2007-05-23 Janhavi P. Joshi , A. K. Sood , S. V. Bhat , A. R. Raju , C. N. R. Rao

The solid-state reaction was used to synthesize CoO2 nanostructured material. Cobalt nitrate tetrahydrate and sodium oxide (NaOH) were combined to produce CoO2 nanostructured material. The three synthesized working electrodes were each…

材料科学 · 物理学 2025-02-12 Shoaib Akram , Muneeb ur Rahman , Fazli Maula , Osama Tariq Satti , Shahbaz Afzal , Fawad Ali

We studied single-crystals of the antiferromagnetic compound UNi0.5Sb2 (TN ~ 161 K) by means of measurements of magnetic susceptibility (chi), specific heat (Cp), and electrical resistivity (rho) at ambient pressure, and resistivity under…

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