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We present a novel approach to model ultrafast time-dependent nonlinear optical polarization sensitive signals emitted from randomly-oriented molecules. By projecting the laboratory-frame analyzer polarization axis into the molecular frame…

化学物理 · 物理学 2025-07-17 R. L. Thurston , N. Shivaram , Th. Weber , L. Z. Tan , D. S. Slaughter

In most cases the ultrafast dynamics of resonantly excited molecules are considered, and almost always computed in the molecular frame, while experiments are carried out in the laboratory frame. Here we provide a formalism in terms of a lab…

化学物理 · 物理学 2022-11-09 Margaret Gregory , Simon Neville , Michael Schuurman , Varun Makhija

Inducing and controlling the ultrafast molecular rotational dynamics using shaped laser fields is essential in numerous applications. Several approaches exist that allow following the coherent molecular motion in real-time, including…

Transient absorption is a very powerful observable in attosecond experiments on atoms, molecules and solids and is frequently used in experiments employing phase-locked few-cycle infrared and XUV laser pulses derived from high harmonic…

原子物理 · 物理学 2020-08-26 Lorenz Drescher , Marc J. J. Vrakking , Jochen Mikosch

The requirement of high space-time resolution and brightness is a great challenge for imaging atomic motion and making molecular movies. Important breakthroughs in ultrabright tabletop laser, x-ray and electron sources have enabled the…

原子物理 · 物理学 2022-02-10 Ming Zhang , Zhenning Guo , Xiaoyu Mi , Zheng Li , Yunquan Liu

The advent of ultrafast pulsed X-ray free-electron lasers with very high brightness has enabled the determination of transient molecular structures of small and medium-sized organic molecules in excited states and undergoing chemical…

化学物理 · 物理学 2025-10-07 Peter M. Weber , Brian Stankus , Adam Kirrander

Alignment and orientation of molecules by intense, ultrashort laser fields are crucial for a variety of applications in physics and chemistry. These include control of high harmonics generation, molecular orbitals tomography, control of…

Impacts of quantum stochasticity on the dynamics of an ultra-relativistic electron beam head-on colliding with a linearly polarized ultra-intense laser pulse are theoretically investigated in a quasi-classical regime. Generally, the angular…

等离子体物理 · 物理学 2020-10-21 Guang Hu , Wei-Qiang Sun , Bing-Jun Li , Yan-Fei Li , Wei-MinWang , Meng Zhu , Hua-Si Hu , Yu-Tong Li

Photoassociation of ultracold atoms is shown to lead to alignment of the product molecules along the excitation laser polarization axis. We theoretically investigate pulsed photoassociation of $^{87}Rb$ atoms into a specific weakly-bound…

量子物理 · 物理学 2017-11-15 S. Kallush , J. L. Carini , P. L. Gould , R. Kosloff

The development of attosecond technology has enabled the real-time observation of coherent electron motion in atoms, molecules and condensed phases. Experimentally, it is now possible to generate laser pulses of durations of only a few tens…

化学物理 · 物理学 2017-05-18 David Ayuso

We resolve the real-time electric field of a femtosecond third-order nonlinear optical signal in the molecular frame. The electric field emitted by the induced third-order polarization from impulsively pre-aligned gas-phase molecules at…

Time-resolved investigations of ultrafast electronic and molecular dynamics were not possible until recently. The typical time scale of these processes is in the picosecond to attosecond realm. The tremendous technological progress in…

原子物理 · 物理学 2013-05-14 Stefan Pabst

Ultrafast electronic dynamics are typically studied using pulsed lasers. We demonstrate a complementary experimental approach: quantum simulation of ultrafast dynamics using trapped ultracold atoms. Counter-intuitively, this technique…

Dynamics of an electron beam head-on colliding with an ultraintense focused ultrashort circularly-polarized laser pulse are investigated in the quantum radiation-dominated regime. Generally, the ponderomotive force of the laser fields may…

等离子体物理 · 物理学 2018-11-21 Yan-Fei Li , Yong-Tao Zhao , Karen Z. Hatsagortsyan , Christoph H. Keitel , Jian-Xing Li

The real and imaginary parts of the susceptibility are fundamentally associated with the molecular dispersion and absorption, respectively. Measurement of the molecular dispersion has given insight into underlying molecular dynamics such as…

化学物理 · 物理学 2019-01-15 Rachel Glenn

We review on the theoretical status of intense laser orientation and alignment. The evolution of the rotational wave packet and its dynamics leading to orientation and alignment is the topic of the present discussion. The major part of the…

原子物理 · 物理学 2021-04-14 Vijit V. Nautiyal , Sumana Devi , Ashish Tyagi , Bhawna Vidhani , Anjali Maan , Vinod Prasad

In recent years it became possible to align molecules in free space using ultrashort laser pulses. Here we explore two schemes for controlling molecule-surface scattering process, which are based on the laser-induced molecular alignment. In…

化学物理 · 物理学 2015-05-28 Yuri Khodorkovsky , J. R. Manson , Ilya Sh. Averbukh

Present photoionization experiments cannot measure molecular frame photoelectron angular distributions (MFPAD) from the outermost valence electrons of molecules. We show that details of the MFPAD can be retrieved with high-order harmonics…

原子物理 · 物理学 2009-05-24 Anh-Thu Le , R. R. Lucchese , M. T. Lee , C. D. Lin

We examine x-ray scattering from an isolated organic molecule from the linear to nonlinear absorptiveregime. In the nonlinear regime, we explore the importance of both the elastic and inelastic channelsand observe the onset of nonlinear…

化学物理 · 物理学 2021-06-09 Phay J. Ho , Adam E. A. Fouda , Kai Li , Gilles Doumy , Linda Young

We introduce a new scheme for controlling the sense of molecular rotation. By varying the polarization and the delay between two ultrashort laser pulses, we induce unidirectional molecular rotation, thereby forcing the molecules to rotate…

量子物理 · 物理学 2015-05-13 Sharly Fleischer , Yuri Khodorkovsky , Yehiam Prior , Ilya Sh. Averbukh
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