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相关论文: Probing Instantaneous Single-Molecule Chirality in…

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Ferroelectric nematic liquid crystals are formed by achiral molecules with large dipole moments. Its three-dimensional orientational order is universally described as unidirectionally polar. We demonstrate that the ground state of…

软凝聚态物质 · 物理学 2024-04-01 Priyanka Kumari , Bijaya Basnet , Maxim O. Lavrentovich , Oleg D. Lavrentovich

We analyze two simple model planar molecules: an ionic molecule with D3 symmetry and a covalent molecule with D6 symmetry. Both symmetries allow the existence of chiral molecular orbitals and normal modes that are coupled to each other in a…

介观与纳米尺度物理 · 物理学 2025-11-05 Ivan Pasqua , Gregorio Staffieri , Michele Fabrizio

Molecular chirality has traditionally been viewed as a binary property where a molecule is classified as either chiral or achiral, yet in the recent decades mathematical methods for quantifying chirality have been explored. Here we use toy…

化学物理 · 物理学 2024-11-28 Ethan Abraham , Abraham Nitzan

We introduce a gauge-invariant model of planar, square molecules coupled to a quantized spatially-varying cavity electromagnetic vector potential A(r). Specifically, we choose a temporally chiral cavity hosting a uniform magnetic field B,…

In many biological materials with a hierarchical structure there is an intriguing and unique mechanism responsible for the 'propagation' of order from the molecular to the nano- or micro-scale level. Here we present a much simpler molecular…

The fundamental issues of symmetry related to chirality are discussed and applied to simple situations relevant to liquid crystals. We show that any chiral measure of a geometric object is a pseudoscalar (invariant under proper rotations…

统计力学 · 物理学 2009-10-31 A. B. Harris , Randall D. Kamien , T. C. Lubensky

The development of quantitative methods for characterizing molecular chirality can provide an important tool for studying chirality induced phenomena in molecular systems. Significant progress has been made in recent years toward…

化学物理 · 物理学 2025-03-06 Jichen Feng , Ethan Abraham , Joseph Subotnik , Abraham Nitzan

In soft matter, the polar orientational order of molecules can facilitate the coexistence of structural chirality and ferroelectricity. The ferroelectric nematic (NF) state, exhibited by achiral calamitic molecules with large dipole…

软凝聚态物质 · 物理学 2025-03-13 Hiroya Nishikawa , Yasushi Okumura , Dennis Kwaria , Atsuko Nihonyanagi , Fumito Araoka

Molecular chirality is conventionally understood as space-inversion-symmetry breaking in the equilibrium structure of molecules. Less well known is that achiral molecules can be made chiral through extreme rotational excitation. Here, we…

化学物理 · 物理学 2018-11-14 Alec Owens , Andrey Yachmenev , Sergei N. Yurchenko , Jochen Küpper

We propose an approach to sensitively probe the chirality of molecules by measuring their coherent optical absorption spectra. It is shown that quantum dynamics of the cyclic three-level chiral molecules driven by appropriately-designed…

量子物理 · 物理学 2015-05-28 W. Z. Jia , L. F. Wei

Molecular chirality leads to a wonderful variety of equilibrium structures, from the simple cholesteric phase to the twist-grain-boundary phases, and it is responsible for interesting and technologically important materials like…

软凝聚态物质 · 物理学 2007-05-23 T. C. Lubensky , A. B. Harris , Randall D. Kamien , Gu Yan

To understand the relationship between the chirality of individual cells and that of tissues and organisms, we have developed a chiral polarized particle model to investigate the movement of cell populations on substrates. Our model…

生物物理 · 物理学 2024-07-02 Xi Li , Bin Chen

A multiflavor model for dynamical chiral breaking reveals a solution highly suitable for stimulation of flavor mass hierarchy and mixings. The mechanism triggering the both phenomena simultaneously suppresses flavor changings. Thus, the…

高能物理 - 唯象学 · 物理学 2009-09-25 I. T. Dyatlov

Biomolecules are often very long with a definite chirality. DNA, xanthan and poly-gamma-benzyl-glutamate (PBLG) can all form columnar crystalline phases. The chirality, however, competes with the tendency for crystalline order. For chiral…

凝聚态物理 · 物理学 2009-10-28 Randall D. Kamien , David R. Nelson

Major advances in X-ray sources including the development of circularly polarized and orbital angular momentum pulses make it possible to probe matter chirality at unprecedented energy regimes and with Angstr\"om and femtosecond…

化学物理 · 物理学 2022-09-20 Jeremy R. Rouxel , Shaul Mukamel

Ultracold LiCs molecules in the absolute ground state X$^1\Sigma^+$, v"=0, J"=0 are formed via a single photo-association step starting from laser-cooled atoms. The selective production of v"=0, J"=2 molecules with a 50-fold higher rate is…

量子物理 · 物理学 2010-08-09 J. Deiglmayr , A. Grochola , M. Repp , K. Mörtlbauer , C. Glück , J. Lange , O. Dulieu , R. Wester , M. Weidemüller

Chirality is a pervasive property of matter that underpins many important phenomena across physics, chemistry and biology. Given its broad significance, the development of protocols for rational control of chirality in solid state systems…

材料科学 · 物理学 2025-10-27 Z. Zeng , M. Först , M. Fechner , X. Deng , A. Cavalleri , P. G. Radaelli

In equilibrium liquid crystals, chirality leads to a variety of spectacular three-dimensional structures, but chiral and achiral phases with the same broken continuous symmetries have identical long-time, large-scale dynamics. In this…

软凝聚态物质 · 物理学 2021-06-23 S. J. Kole , Gareth P. Alexander , Sriram Ramaswamy , Ananyo Maitra

Chiral phonons have been proposed to be involved in various physical phenomena, yet the chirality of molecular normal modes has not been well defined mathematically. Here we examine two approaches for assigning and quantifying the chirality…

介观与纳米尺度物理 · 物理学 2025-01-07 Ethan Abraham , Abraham Nitzan

A microwave experiment has been realized to measure the phase difference of the oscillating electric field at two points inside the cavity. The technique has been applied to a dissipative resonator which exhibits a singularity -- called…

混沌动力学 · 物理学 2009-03-24 C. Dembowski , B. Dietz , H. -D. Graef , H. L. Harney , A. Heine , W. D. Heiss , A. Richter
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