相关论文: Topotactic Reduction-Driven Crystal Field Excitati…
Mixed-valence perovskite manganites (Re$_{1-x}$A$_{x}$MnO$_{3}$ where Re=rare earth, A=alkaline earth) provide a unique opportunity to study the relationships between the structure and the magnetotransport properties due to an interplay…
Oxygen vacancies play a crucial role in controlling the physical properties of complex oxides. In La0.7Sr0.3MnO3-{\delta}, the topotactic phase transition from Perovskite (PV) to Brownmillerite (BM) can be triggered e.g. via oxygen removal…
Topotactic transformations between related crystal structures are a powerful emerging route for the synthesis of novel quantum materials. Whereas most such "soft chemistry" experiments have been carried out on polycrystalline powders or…
Structural study of orbital-ordered manganite thin films has been conducted using synchrotron radiation, and a ground state electronic phase diagram is made. The lattice parameters of four manganite thin films, Nd0.5Sr0.5MnO3 (NSMO) or…
Oxygen stoichiometry is one of the most important elements in determining the physical properties of transition metal oxides (TMOs). A small fractional change in the oxygen content, resulting in the variation of valence state of the…
We present a detailed magnetic study of the perovskite manganite Pr0.7Ca0.3MnO3 at low temperatures including magnetization and a.c. susceptibility measurements. The data appear to exclude a conventional spin glass phase at low fields,…
Infinite-layer nickelates stand as a promising frontier in the exploration of unconventional superconductivity. Their synthesis through topotactic oxygen reduction from the parent perovskite phase remains a complex and elusive process. This…
Transition-metal perovskite oxides constitute a series of functional material systems for electronics, catalysis and energy-conversion processes, in which oxygen migration and evolution play a key role. However, the stable metal-oxygen…
Magnetic and magnetotransport properties of oriented polycrystalline Pr0.58Ca0.42MnO3 thin films prepared in flowing oxygen and air ambient has been investigated. The magnetic ground state of both the films is a frozen cluster glass. In the…
The perovskite manganites of general formula RE_1-xAe_xMnO_3 (RE= rare earth,AE=Ca, Sr, Ba and Pb)have drawn considerable attention, especially following the discovery of colossal magnetoresistance (CMR). They exhibit extraordinary large…
Topotactic reduction utilizing metal hydrides as reagents emerges as an effective approach to achieve exceptionally low oxidization states of metal ions and unconventional coordination networks. This method opens avenues to the development…
Atomically engineered oxide heterostructures provide a fertile ground for creating novel states. For example, a two-dimensional electron gas at the interface between two oxide insulators, giant thermoelectric Seebeck coefficient, emergent…
We present a detailed dielectric study of the relaxation effects that occur in several perovskite rare-earth manganites, including the multiferroics TbMnO3 and DyMnO3. We demonstrate that the strong magnetocapacitive effects, observed for…
Control of materials through custom design of ionic distributions represents a powerful new approach to develop future technologies ranging from spintronic logic and memory devices to energy storage. Perovskites have shown particular…
We review recent studies of spin dynamics in rare-earth orthorhombic perovskite oxides of the type $RM$O$_3$, where $R$ is a rare-earth ion and $M$ is a transition-metal ion, using single-crystal inelastic neutron scattering (INS). After a…
Infinite layer nickelates provide a new route beyond copper oxides to address outstanding questions in the field of unconventional superconductivity. However, their synthesis poses considerable challenges, largely hindering experimental…
We present a systematic optical study for a bandwidth-controlled series of nearly half doped colossal magnetoresistive manganites RE$_{0.55}$AE$_{0.45}$MnO$_3$ (RE and AE being rare earth and alkaline earth ions, respectively) under the…
The recent observation of superconductivity in Nd$_{0.8}$Sr$_{0.2}$NiO$_{2}$ calls for further investigation and optimization of the synthesis of this metastable infinite-layer nickelate structure. Here, we present our current understanding…
The physical properties of manganites depend strongly on sample morphology, probably due to strain. We investigate the influence of NdGaO3 substrates on the limit of the ferromagnetic-metallic phase field in La1-xCaxMnO3, doping with x=1%…
Transition metal oxides are promising candidates for thermoelectric applications, because they are stable at high temperature and because strong electronic correlations can generate large Seebeck coefficients, but their thermoelectric power…