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The bulk photovoltaic effect in noncentrosymmetric materials is an intriguing physical phenomenon that holds potential for high-efficiency energy harvesting. Here, we study the shift current bulk photovoltaic effect in the transition metal…

材料科学 · 物理学 2021-01-28 Aaron M. Schankler , Lingyuan Gao , Andrew M. Rappe

The bulk photovoltaic effect is a photocurrent generation from alternating electric field, which is a promising candidate for future efficient solar cell technology. It is the second-order optical current, which is the injection current or…

介观与纳米尺度物理 · 物理学 2025-05-22 Motohiko Ezawa

Shift current---a photocurrent induced by light irradiating noncentrosymmetric materials in the absence of any bias voltage or built-in electric field---is one of the mechanisms of the so-called bulk photovoltaic effect. It has been…

介观与纳米尺度物理 · 物理学 2019-03-28 U. Bajpai , B. S. Popescu , P. Plechac , B. K. Nikolic , L. E. F. Foa Torres , H. Ishizuka , N. Nagaosa

We investigate the shift current bulk photovoltaic response of materials close to a band inversion topological phase transition. We find that the bulk photocurrent reverses direction across the band inversion transition, and that its…

介观与纳米尺度物理 · 物理学 2016-09-08 Liang Z. Tan , Andrew M. Rappe

We compute the shift current bulk photovoltaic effect (BPVE) in bulk BaTiO$_3$ and two-dimensional monochalcogenide SnSe considering quasi-particle corrections and exciton effects. We explore changes in shift current peak position and…

材料科学 · 物理学 2020-01-15 Ruixiang Fei , Liang Z. Tan , Andrew M. Rappe

Realization of giant and continuously tunable second-order photocurrent is desired for many nonlinear optical (NLO) and optoelectronic applications, which remains to be a great challenge. Here, based on a simple two-band model, we propose a…

材料科学 · 物理学 2023-07-05 Xiao Jiang , Lei Kang , Jianfeng Wang , Bing Huang

The shift current effect, in materials lacking inversion symmetry, may potentially allow the performance of photovoltaics to surpass the Shockley-Queisser limit for traditional p-n junction-based photovoltaics. Although the shift-current…

材料科学 · 物理学 2022-07-11 Fuxiang He , Xinguo Ren , Sheng Meng , Lixin He

The bulk photovoltaic effect (BPVE) refers to the phenomenon of generating photocurrent or photovoltage in homogeneous noncentrosymmetric materials under illumination, and the intrinsic contribution to the BPVE is known as the shift current…

材料科学 · 物理学 2023-02-01 Gan Jin , Lixin He

Shift current and ballistic current have been proposed to explain the bulk photovoltaic effect (BPVE), and there have been experiments designed to separate the two mechanisms. These experiments are based on the assumption that under…

材料科学 · 物理学 2023-05-24 Zhenbang Dai , Andrew M. Rappe

The correlation between the shift current mechanism for the bulk photovoltaic effect (BPVE) and the structural and electronic properties of ferroelectric perovskite oxides is not well understood. Here, we study and engineer the shift…

材料科学 · 物理学 2015-03-03 Fenggong Wang , Steve M. Young , Fan Zheng , Ilya Grinberg , Andrew M. Rappe

Steady illumination of a non-centrosymmetric semiconductor results in a bulk photovoltaic current, which is contributed by real-space displacements (`shifts') of charged quasiparticles as they transit between Bloch states. The shift induced…

介观与纳米尺度物理 · 物理学 2025-08-12 Penghao Zhu , A. Alexandradinata

We discuss the photovoltaic effect at a p-n heterojunction, in which the illuminated side is a doped Mott insulator, using the simplest description of a Mott insulator within the Hubbard model. We find that the internal quantum efficiency…

强关联电子 · 物理学 2015-05-14 Efstratios Manousakis

Designing materials with controlled photovoltaic response may lead to improved solar cells or photosensors. In this regard, ferroelectric superlattices have emerged as a rich platform to engineer functional properties. In addition,…

材料科学 · 物理学 2025-02-20 Francesco Delodovici , Charles Paillard

We investigate the bulk photovoltaic effect, which rectifies light into electric current, in a collective quantum state with correlation driven electronic ferroelectricity. We show via explicit real-time dynamical calculations that the…

强关联电子 · 物理学 2021-09-21 Tatsuya Kaneko , Zhiyuan Sun , Yuta Murakami , Denis Golež , Andrew J. Millis

The bulk photovoltaic effect is an experimentally verified phenomenon by which a direct charge current is induced within a non-centrosymmetric material by light illumination. Calculations of its intrinsic contribution, the shift current,…

材料科学 · 物理学 2023-08-21 M. A. García-Blázquez , J. J. Esteve-Paredes , A. J. Uría , J. J. Palacios

Flat bands typically describe energy bands whose energy dispersion is entirely or almost entirely degenerate. One effective method to form flat bands is by constructing Moir\'e superlattices. Recently, there has been a shift in perspective…

光学 · 物理学 2024-11-07 Linyang Zou , Hao Hu , Haotian Wu , Yang Long , Yidong Chong , Baile Zhang , Yu Luo

This paper presents a study of dc photocurrents in biased insulators to the third order in the electric field. We find three photocurrents which are characterized by physical divergences of the third-order free-electron polarization…

介观与纳米尺度物理 · 物理学 2019-08-07 Benjamin M. Fregoso

We analyze the effect of acoustic phonons on the photocurrent and the spectral characteristics of a simplified photovoltaic setup made of Mott insulating layers between two metallic leads among which a bias voltage is applied. We include…

强关联电子 · 物理学 2024-09-12 Paolo Gazzaneo , Enrico Arrigoni

A bulk material without inversion symmetry can generate a direct current under illumination. This interface-free current generation mechanism, referred to as the bulk photovoltaic effect (BPVE), does not rely on $p$-$n$ junctions. Here, we…

材料科学 · 物理学 2023-05-01 Zhuang Qian , Jian Zhou , Hua Wang , Shi Liu

The Mott insulator provides an excellent foundation for exploring a wide range of strongly correlated physical phenomena, such as high-temperature superconductivity, quantum spin liquid, and colossal magnetoresistance. A Mott insulator with…

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