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A combined study of transport, thermodynamic, neutron diffraction, nuclear magnetic resonance measurements and first principles calculation were performed for $\beta$-V$_2$PO$_5$ single crystal. It was shown to be a semiconductor with a…

By applying measurements of the dielectric constants and relative length changes to the dimerized molecular conductor $\kappa$-(BEDT-TTF)$_2$Hg(SCN)$_2$Cl, we provide evidence for order-disorder type electronic ferroelectricity which is…

Displacive martensitic phase transition is potentially promising in semiconductor based data storage applications with fast switching speed. In addition to traditional phase transition materials, the recently discovered two-dimensional…

材料科学 · 物理学 2021-01-26 Jian Zhou , Shunhong Zhang

Layered van der Waals materials have risen as powerful platforms to artificially engineer correlated states of matter. Here we show the emergence of a multiferroic order in a twisted dichalcogenide bilayer superlattice at quarter-filling.…

强关联电子 · 物理学 2022-09-07 Mikael Haavisto , J. L. Lado , Adolfo O. Fumega

There is great interest in hybrid organic-inorganic materials such as metal-organic frameworks (MOFs). The compounds [C(NH$_{2}$)$_{3}$]M(HCOO)$_{3}$, where M=Cu$^{2+}$ or Cr$^{2+}$ are Jahn-Teller (JT) active ions, are MOF with perovskite…

For the Sn$_2$P$_2$S$_6$ crystalline compound with a rich temperature--pressure phase diagram that contains the ferroelectric phase, semiconductor-to-metal transition, and superconductive state, \mbox{\textit{ab initio}} molecular dynamics…

Two-dimensional (2D) multiferroic materials are ideal systems for exploring new coupling mechanisms between different ferroic orders and producing novel quantum phenomena with potential applications. We employed first-principles density…

材料科学 · 物理学 2022-09-20 Weiwei Gao , Jijun Zhao , James R. Chelikowsky

Resonant and non-resonant X-ray scattering studies on HoFe3(BO3)O4 reveal competing magnetic ordering of Ho and Fe moments. Temperature and X-ray polarization dependent measurements employed at the Ho L3 edge directly reveal a spiral spin…

We report a neutron diffraction study of the multiferroic mechanism in (ND4)2FeCl5D2O, a molecular compound that exhibits magnetically induced ferroelectricity. This material exhibits two successive magnetic transitions on cooling: a…

Strong coupling among spontaneous structural symmetric breaking, magnetism and metallicity in an intrinsic polar magnetic metal can give rise to novel physical phenomena and holds great promise for applications in spintronics. Here, we…

材料科学 · 物理学 2025-11-04 Hong-Fei Huang , Houssam Sabri , Jiadong Zang , Jie-Xiang Yu

We report on the low-frequency optical excitations in the multiferroic ground state of polycrystalline FeCr2S4 in the frequency range 0.3-3~THz and their changes upon applying external magnetic fields up to 7~T. In the ground state below…

强关联电子 · 物理学 2020-10-12 A. Strinic , S. Reschke , K. V. Vasin , M. Schmidt , A. Loidl , V. Tsurkan , M. V. Eremin , J. Deisenhofer

At ambient conditions, the Fe$_3$O$_4$(001) surface shows a $(\sqrt{2}\times \sqrt{2})R45^o$ reconstruction that has been proposed as the surface analog of the bulk phase below the Verwey transition temperature, T$_V$. The reconstruction…

强关联电子 · 物理学 2014-11-26 Ivan Bernal-Villamil , Silvia Gallego

An outstanding challenge in materials science and physics is the harnessing of light for switching charge order in e.g., ferroelectrics. Here we propose a mechanism through which electrons in ferroelectric bilayers excited with light cause…

材料科学 · 物理学 2025-04-08 Haoyu Wei , Daniel Kaplan , Haowei Xu , Ju Li

Using one- and two-dimensional NMR spectroscopy applied to $^{13}$C spin-labeled (TMTTF)$_2$AsF$_6$ and (TMTTF)$_2$PF$_6$, we demonstrate the existence of an intermediate charge-ordered phase in the TMTTF family of charge-transfer salts. At…

强关联电子 · 物理学 2009-10-31 D. S. Chow , F. Zamborszky , B. Alavi , D. J. Tantillo , A. Baur , C. A. Merlic , S. E. Brown

We report coupling between magnetic and electric orders for antiferromagnetic polycrystalline FeVO4 in which magnetism-induced polarization has been recently found in noncollinear antiferromagnetic state below the second antiferromagnetic…

材料科学 · 物理学 2009-11-17 Bohdan Kundys , Christine Martin , Charles Simon

The heavy-fermion superconductor CeRh2As2 exhibits a non-superconducting phase transition that precedes the emergence of superconductivity. The nature of the corresponding order parameter remains under debate, with competing proposals…

强关联电子 · 物理学 2026-04-06 Koki Numa , Eri Matsuda , Akimitsu Kirikoshi , Junya Otsuki

Density functional theory calculations have been performed for the structural, electronic, magnetic and ferroelectric properties of a mixed-valence Fe(II)-Fe(III) formate framework [NH$_2$(CH$_3$)$_2$][Fe$^{\rm III}$Fe$^{\rm II}$(HCOO)$_6$]…

材料科学 · 物理学 2019-10-15 Gang Tang , Wei Ren , Jiawang Hong , Alessandro Stroppa

The nature of the charge order in the charge frustrated compound LuFe$_2$O$_4$ and its effect on magnetocapacitance were examined on the basis of first-principles electronic structure calculations and Monte Carlo simulations of…

材料科学 · 物理学 2011-11-09 H. J. Xiang , M. -H. Whangbo*

Fundamental block and staggered orders of magnetic Fe multipoles in Na2FeSe2 are classified by their symmetry and magnetoelectric properties. Our structure model incorporates ferromagnetic or antiferromagnetic coupling between chains. The…

强关联电子 · 物理学 2021-04-28 S. W. Lovesey , D. D. Khalyavin

Ferroic orders describe spontaneous polarization of spin, charge, and lattice degrees of freedom in materials. Materials featuring multiple ferroic orders, known as multiferroics, play important roles in multi-functional electrical and…

介观与纳米尺度物理 · 物理学 2023-12-19 Tonghang Han , Zhengguang Lu , Giovanni Scuri , Jiho Sung , Jue Wang , Tianyi Han , Kenji Watanabe , Takashi Taniguchi , Liang Fu , Hongkun Park , Long Ju