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Resonant optical excitation of certain molecular vibrations in $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br has been shown to induce transient superconducting-like optical properties at temperatures far above equilibrium $T_c$. Here, we report…

A few organic conductors show a diversity of exciting properties like Mott insulating behaviour, spin liquid, antiferromagnetism, bad metal or unconventional superconductivity controlled by small changes in temperature, pressure or chemical…

强关联电子 · 物理学 2014-02-05 Johannes Ferber , Kateryna Foyevtsova , Harald O. Jeschke , Roser Valenti

The polarized optical reflectance spectra of the quasi two dimensional organic correlated electron system $\kappa$-(BEDT-TTF)$_{2}$Cu[N(CN)$_{2}$]$Y$, $Y =$ Br and Cl are measured in the infrared region. The former shows the…

超导电性 · 物理学 2007-05-23 T. Sasaki , I. Ito , N. Yoneyama , N. Kobayashi , N. Hanasaki , H. Tajima , T. Ito , Y. Iwasa

We present an ab initio analysis for the ground-state properties of a correlated organic compound $\kappa$-(BEDT-TTF)2Cu(NCS)2. First, we derive an effective two-dimensional low-energy model from first principles, having short-ranged…

强关联电子 · 物理学 2012-03-09 Hiroshi Shinaoka , Takahiro Misawa , Kazuma Nakamura , Masatoshi Imada

The fascinating electronic properties of the family of layered organic molecular crystals kappa-(BEDT-TTF)2X where X is an anion (e.g., X=I3, Cu[N(CN)2]Br, Cu(SCN)2) are reviewed. These materials are particularly interesting because of…

强关联电子 · 物理学 2007-05-23 Ross H. McKenzie

It has been more than 40 years since superconductivity was discovered in organic conductors, and the way scientists view organic superconductors has changed over time. At first, the fact that organic conductors exhibit superconductivity was…

超导电性 · 物理学 2023-07-20 Hiroshi Oike , Hiromi Taniguchi , Kazuya Miyagawa , Kazushi Kanoda

We have studied the interlayer resistivity of the prototypical quasi-two-dimensional organic superconductor $\kappa$-(BEDT-TTF)$_2$Cu(NCS)$_2$ as a function of temperature, current and magnetic field, within the superconducting state. We…

The dimer Mott insulator $\kappa$-(BEDT-TTF)$_2$Cu$_2$(CN)$_3$ exhibits unusual electrodynamic properties. Numerical investigations of the electronic ground state and the molecular and lattice vibrations reveal the importance of the…

强关联电子 · 物理学 2016-02-02 M. Dressel , P. Lazic , A. Pustogow , E. Zhukova , B. Gorshunov , J. A. Schlueter , O. Milat , B. Gumhalter , S. Tomic

Partial suppression of superconductivity by fast cooling has been observed in the organic superconductor $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br by two means: a marked sample size effect on the magnetic susceptibility and direct imaging of…

超导电性 · 物理学 2007-05-23 N. Yoneyama , T. Sasaki , N. Kobayashi , Y. Ikemoto , H. Kimura

The Mott insulator \kappa-(BEDT-TTF)2Cu[N(CN)2]Cl consists of molecular dimers arranged on an anisotropic triangular lattice and develops a canted antiferromagnetic ground state. It has recently been suggested that this system features…

(BEDT-TFF)$_2$I$_3$ charge transfer salts are reported to show superconductivity and pressure induced quasi two-dimensional Dirac cones at the Fermi level. By performing state of the art ab initio calculations in the framework of density…

We theoretically study the competition among different electronic phases in molecular conductors $\kappa$-(BEDT-TTF)$_2$X. The ground-state properties of a 3/4-filled extended Hubbard model with the $\kappa$-type geometry are investigated…

超导电性 · 物理学 2017-02-10 Hiroshi Watanabe , Hitoshi Seo , Seiji Yunoki

Low temperature scanning tunneling spectroscopy reveals the local density of states of the organic superconductor $\kappa$-(BEDT-TTF)$_2$Cu[N(CN)$_2$]Br, that was cut in-situ in ultra-high vacuum perpendicular to the superconducting…

The dimer Mott insulator $\kappa$-(BEDT-TTF)$_2$Cu$_2$(CN)$_3$ can be tuned into a metallic and superconducting state upon applying pressure of 1.5 kbar and more. We have performed dielectric spectroscopy measurements (7 kHz to 5 MHz) on…

Utilizing infrared vibrational spectroscopy we have investigated dimerized two-dimensional organic salts in order to search for possible charge redistribution that might cause electronic dipoles and ferroelectricity: the quantum spin liquid…

The two-dimensional organic conductor $\alpha$-(BEDT-TTF)$_2$I$_3$ undergoes a metal-insulator transition at $T_{\rm CO}=135$ K due to electronic charge ordering. We have conducted time-resolved investigations of its electronic properties…

强关联电子 · 物理学 2016-06-15 Tobias Peterseim , Tomislav Ivek , Dieter Schweitzer , Martin Dressel

Starting from an {\it ab initio}-derived two-site dimer Hubbard hamiltonian on a triangular lattice, we calculate the superconducting gap functions and critical temperatures for representative $\kappa$-(BEDT-TTF)$_2$X superconductors by…

超导电性 · 物理学 2018-02-02 Karim Zantout , Michaela Altmeyer , Steffen Backes , Roser Valenti

The thermal conductivity of organic superconductor kappa-(BEDT-TTF)2Cu(NCS)2 (Tc =10.4 K) has been studied in a magnetic field rotating within the 2D superconducting planes with high alignment precision. At low temperatures (T < 0.5 K), a…

超导电性 · 物理学 2009-11-07 Koichi Izawa , Hidemasa Yamaguchi , Takahiko Sasaki , Yuji Matsuda

We report high-sensitivity AC susceptibility measurements of the penetration depth in the Meissner state of the layered organic superconductor kappa-(BEDT-TTF)2Cu[N(CN)2]Br. We have studied nominally pure single crystals from the two…

凝聚态物理 · 物理学 2009-11-07 M. Pinteric , S. Tomic , M. Prester , D. Drobac , K. Maki

The electronic properties of molecular conductors can be readily varied via physical or chemical pressure as it increases the bandwidth W; this enables crossing the Mott insulator-to-metal phase transition by reducing electronic…

强关联电子 · 物理学 2019-11-18 Y. Saito , R. Rösslhuber , A. Löhle , M. Sanz Alonso , M. Wenzel , A. Kawamoto , A. Pustogow , M. Dressel
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