相关论文: Modeling Complex Organic Molecules Formation in Co…
We present a chemical kinetics model of the solid-phase chemical evolution of a comet, beginning with a long period of cold-storage in the Oort Cloud, followed by five orbits that bring the comet close to the Sun. The chemical model is…
To correctly model the abundances of interstellar complex organic molecules (iCOMS) in different environments, both formation and destruction routes should be appropriately accounted for. While several scenarios have been explored for the…
Observations of the circumgalactic medium (CGM) often display coincident absorption from species with widely varying ionization states, providing direct evidence for complex, multiphase interactions. Motivated by these measurements, we…
Massive star-forming regions exhibit an extremely rich and diverse chemistry, which in principle provides a wealth of molecular probes, as well as laboratories for interstellar prebiotic chemistry. Since the chemical structure of these…
The chemical differentiation of seven COMs in the extended region around Sgr B2 has been observed: CH$_2$OHCHO, CH$_3$OCHO, t-HCOOH, C$_2$H$_5$OH, and CH$_3$NH$_2$ were detected both in the extended region and near the hot cores Sgr B2(N)…
Atomic carbon in its ground electronic state, C(3P), is expected to be present at high abundances during the evolution of dense molecular clouds. Consequently, its reactions with other interstellar species could have a strong influence on…
Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…
Complex Organic Molecules (COMs) in the form of prebiotic molecules are potentially building blocks of life. Using Atacama Large Millimeter/submillimeter Array (ALMA) Band 7 observations in spectral scanning mode, we carried out a deep…
The results of a survey of 63 galactic star-forming regions in the 6_K-5_K and 5_K-4_K methyl acetylene lines at 102 and 85 GHz, respectively, are presented. Fourty-three sources were detected at 102 GHz, and twenty-five at 85 GHz. Emission…
The chemical pathways linking the small organic molecules commonly observed in molecular clouds to the large, complex, polycyclic species long-suspected to be carriers of the ubiquitous unidentified infrared emission bands remain unclear.…
Massive stars play a pivotal role in shaping their galactic surroundings due to their high luminosity and intense ionizing radiation. However, the precise mechanisms governing the formation of massive stars remain elusive. Complex organic…
Cold cores are an early step of star formation, characterized by densities > 10$^4$ cm$^{-3}$, low temperatures (< 15 K), and very low external UV radiation. We investigate the physico-chemical processes at play to tracing the origin of…
Designing metal-organic frameworks (MOFs) synthesis protocols is currently largely driven by trial-and-error, since we lack fundamental understanding of the molecular level mechanisms that underlie their self-assembly processes. Previous…
We investigate the formation and evolution of interstellar dust-grain ices under dark-cloud conditions, with a particular emphasis on CO2. We use a three-phase model (gas/surface/mantle) to simulate the coupled gas--grain chemistry,…
Observations of exoplanet atmospheres have revealed the presence of cloud particles in their atmospheres. 3D modelling of cloud formation in atmospheres of extrasolar planets coupled to the atmospheric dynamics has long been a challenge. We…
The molecular dynamics in the ambient-pressure solid phase of (1,1,2)-trichloroethane is studied by means of broadband dielectric spectroscopy and molecular dynamics simulations. The dielectric spectra of polycrystalline samples obtained by…
Methanol and complex organic molecules have been found in cold starless cores, where a standard warm-up scenario would not work because of the absence of heat sources. A recent chemical model attributed the presence of methanol and large…
High quality archival spectra of interstellar absorption from C I toward 9 stars, taken with the Goddard High Resolution Spectrograph on the Hubble Space Telescope, were analyzed. Our sample was supplemented by two sight lines, 23 Ori and…
Complex organic molecules (COMs) in starless cores provide critical insights into the early stages of star formation and prebiotic chemistry. We present a chemical survey of 16 starless cores (including five prestellar cores) in the Orion A…
The recent unexpected detection of terrestrial complex organic molecules in the cold (~ 10 K) gas has cast doubts on the commonly accepted formation mechanisms of these species. Standard gas-phase mechanisms are inefficient and tend to…