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Rare-earth titanates RTiO$_3$ are Mott insulators displaying a rich physical behavior, featuring most notably orbital and spin orders in their ground state. The origin of their ferromagnetic to antiferromagnetic transition as a function of…

We report on a study of various RVO3 single-crystal samples (R = La, Nd, Sm, Gd, Er and Y) which show temperature-induced magnetization reversal. For compounds with lighter rare-earths (R = La, Nd and Sm), magnetization reversal can be…

强关联电子 · 物理学 2007-05-23 L D Tung , M R Lees , G Balakrishnan , D McK Paul

Starting from the Mott insulator picture for cubic vanadates, we derive and investigate the model of superexchange interactions between V$^{3+}$ ions, with nearly degenerate $t_{2g}$ orbitals occupied by two electrons each. The…

强关联电子 · 物理学 2007-06-19 Andrzej M. Oles , Peter Horsch , Giniyat Khaliullin

We investigate the highly frustrated spin and orbital superexchange interactions in cubic vanadates. The fluctuations of $t_{2g}$ orbitals trigger a {\it novel mechanism of ferromagnetic interactions} between spins S=1 of V$^{3+}$ ions…

强关联电子 · 物理学 2009-11-07 G. Khaliullin , P. Horsch , A. M. Oles

The orthovanadate DyVO3 crystal, known to exhibit multiple structural, spin and orbital ordering transitions, is presently investigated on the basis of magnetization, heat capacity, resistivity, dielectric and polarization measurements. Our…

强关联电子 · 物理学 2014-07-24 Q. Zhang , K. Singh , C. Simon , L. D. Tung , G. Balakrishnan , V. Hardy

Magnetic control of correlated spin systems is central to the development of next-generation spin-based technologies. Rare-earth orthoferrites provide an interesting platform in which exchange coupling between rare-earth 4f and…

We present a neutron diffraction study of FeV2O4, which is rare in exhibiting spin and orbital degrees of freedom on both cation sublattices of the spinel structure. Our data confirm the existence of three structural phase transitions…

强关联电子 · 物理学 2012-09-03 G. J. MacDougall , V. O. Garlea , A. A. Aczel , H. D. Zhou , S. E. Nagler

We present the main features of the spin-orbital superexchange which describes the magnetic and optical properties of Mott insulators with orbital degrees of freedom. In contrast to the SU(2) symmetry of spin superexchange, the orbital part…

强关联电子 · 物理学 2022-01-25 Andrzej M. Oles

Evidence has been found for a change in the ordered occupation of the vanadium d-orbitals at the 77K phase transition in YVO3, manifested by a change in the type of Jahn-Teller distortion. The orbital ordering above 77K is not destroyed at…

强关联电子 · 物理学 2009-11-07 G. R. Blake , T. T. M. Palstra , Y. Ren , A. A. Nugroho , A. A. Menovsky

Rare-earth nickelates RNiO3 (R=rare-earth element) exhibit three kinds of phase transitions with decreasing temperature: a structural transition from a pseudo-cubic to a monoclinic phase, a metal- insulator transition (MIT), and a magnetic…

We investigate the effect of alloying at the 3d transition metal site of a rare-earth-transition metal oxide, by considering NdFe0.5Cr0.5O3 alloy with two equal and random distribution of 3d ions, Cr and Fe, interacting with an early 4f…

We investigate the frustrated magnetic interactions in cubic transition metal oxides with orbital degeneracy. The $e_g$ orbitals order easier and their ordering explains the $A$-type antiferromagnetic phase in KCuF$_3$ and LaMnO$_3$. In…

强关联电子 · 物理学 2016-08-31 Andrzej M. Oles

The magnetic properties of iron pnictide superconductors with magnetic rare-earth ions under strong magnetic field are investigated based on the cluster self-consistent field method. Starting from an effective Heisenberg model, we present…

强关联电子 · 物理学 2017-01-13 Lei-Lei Yang , Da-Yong Liu , Dong-Meng Chen , Liang-Jian Zou

We study the mechanism of orbital-order melting observed at temperature T_OO in the series of rare-earth manganites. We find that many-body super-exchange yields a transition-temperature T_KK that decreases with decreasing rare-earth…

强关联电子 · 物理学 2012-01-27 Andreas Flesch , Guoren Zhang , Erik Koch , Eva Pavarini

Spin correlations in metallic and insulating phases of $V_2O_3$ and its derivatives are investigated using magnetic neutron scattering. Metallic samples have incommensurate spin correlations varying little with hole doping. Paramagnetic…

强关联电子 · 物理学 2009-10-28 Wei Bao , C. Broholm , G. Aeppli , P. Dai , J. M. Honig , P. Metcalf

Multiferroic TbMnO3 is investigated using x-ray diffraction in high magnetic fields. Measurements on first and second harmonic structural reflections due to modulations induced by the Mn and Tb magnetic order are presented as function of…

We present our theoretical results on the mechanism of two transitions in vanadium spinel oxides $A$V$_2$O$_4$ ($A$=Zn, Mg, or Cd) in which magnetic V cations constitute a geometrically-frustrated pyrochlore structure. We have derived an…

强关联电子 · 物理学 2007-05-23 Yukitoshi Motome , Hirokazu Tsunetsugu

Motivated by the recent neutron diffraction experiment on $YVO_3$, we consider a microscopic model where each $V^{3+}$ ion is occupied by two 3d electrons of parallel spins with two fold degenerate orbital configurations. The mean field…

强关联电子 · 物理学 2007-05-23 Theja N. De Silva , Anuvrat Joshi , Michael Ma , Fu Chun Zhang

The mixed rare-earth orthochromite Nd$_{0.5}$Dy$_{0.5}$CrO$_{3}$ has a N\'eel temperature ($T_\mathrm{{N}}$) of ${\sim}$ 175\,K, resulting in the G-type antiferromagnetic ordering of Cr$^{3+}$ spins. The inverse susceptibility shows a…

Spin reorientation and magnetisation reversal are two important features of the rare-earth orthorhombic provskites ($RM$O$_{3}$'s) that have attracted a lot of attention, though their exact microscopic origin has eluded researchers. Here,…

材料科学 · 物理学 2021-08-25 Alireza Sasani , Jorge Iñiguez , Eric Bousquet
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