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Optimizing the interfaces in perovskite solar cells (PSCs) is essential for enhancing their performance, improving their stability, and making them commercially viable for large-scale deployment in solar energy harvesting applications.…

The use of mixed cation absorber composition was considered as an efficient strategy to mitigate the degradation effects in halide perovskite solar cells. Despite the reports about partial stabilization at elevated temperatures, unfavorable…

While perovskite solar cells (PSCs) are now reaching high power conversion efficiencies (PCEs), further performance improvement requires a fine management and an optimization of the light pathway and harvesting in the cells. These go…

Surface ligand exchange on all-inorganic perovskite nanocrystals of composition CsPbBrI$_{2}$ reveals improved optoelectronic properties due to strong interactions of the nanocrystal with mono-functionalized porphyrin derivatives. The…

Lead-halide perovskites emerged as novel semiconducting materials suitable for a variety of optoelectronic applications. However, fabrication of reliable perovskite field-effect transistors (FETs), the devices necessary for the fundamental…

In the heavy fermion materials, the characteristic energy scales of many exotic strongly correlated phenomena (Kondo effect, magnetic order, superconductivity, etc.) are at milli-electron-volt order, implying that the heavy fermion…

强关联电子 · 物理学 2021-05-11 Yue-Chao Wang , Yuan-Ji Xu , Yu Liu , Xing-Jie Han , Xie-Gang Zhu , Yi-feng Yang , Yan Bi , Hai-Feng Liu , Hai-Feng Song

The performance of organometallic perovskite solar cells has rapidly surpassed that of both conventional dye-sensitised and organic photovoltaics. High power conversion efficiency can be realised in both mesoporous and thin-film device…

In this work, we study the effect of various deposition methods for phosphonic acid interface modifiers commonly pursued as self-assembled monolayers in high-performance metal halide perovskite photovoltaics and light-emitting diodes. We…

Perovskite alkaline earth stannates, such as $BaSnO_3$ and $SrSnO_3$, showing light transparency and high electrical conductivity (when doped), have become promising candidates for novel optoelectrical devices. Such devices are mostly based…

In high performance perovskite based solar cells, CH3NH3PbI3 is the key material. We carried out a study on charge diffusion in spin-coated CH3NH3PbI3 perovskite thin film by transient fluorescent spectroscopy. A thickness-dependent…

化学物理 · 物理学 2015-10-02 Yu Li , Weibo Yan , Yunlong Li , Shufeng Wang , Wei Wang , Zuqiang Bian , Lixin Xiao , Qihuang Gong

We report high-pressure photoluminescence, Raman scattering, and x-ray diffraction measurements on a lead-free halide perovskite $Cs_3Sb_2Br_9$. At about 3 GPa, an electronic transition manifests itself through a broad minimum in linewidth,…

We report that device architecture engineering has a substantial impact on the reverse bias instability that has been reported as a critical issue in commercializing perovskite solar cells. We demonstrate breakdown voltages exceeding -15 V…

Extensive studies have focused on degradation of perovskite at low charge carrier density (<10^16 cm^-3), but few have surveyed the degradation mechanism at high charge carrier density (~10^18 cm^-3). Here, we investigate the degradation…

Organic-inorganic perovskite as a promising candidate for solar energy harvesting has attracted immense interest for its low-cost preparation and extremely high quantum efficiency. However, the fundamental understanding of the photophysics…

应用物理 · 物理学 2018-11-05 Yanwen Chen , Tianmeng Wang , Zhipeng Li , Huanbin Li , Tao Ye , Christian Wetzel , Hanying Li , Su-Fei Shi

Perovskite solar cells (PSCs) are the fastest-growing photovoltaic (PV) technology in the solar cell community and have reached an efficiency close to that of commercial silicon (Si) solar cells. The organic-inorganic halide perovskite…

材料科学 · 物理学 2024-11-28 Kashimul Hossain

Halide perovskites belong to an important family of semiconducting materials with unique electronic properties that enable a myriad of applications, especially in photovoltaics and optoelectronics. Their optical properties, including…

Lead (Pb) halide perovskites have achieved great success in recent years due to their excellent optoelectronic properties, which is largely attributed to the lone-pair s orbital-derived antibonding states at the valence band edge. Guided by…

材料科学 · 物理学 2021-05-07 Gang Tang , Philippe Ghosez , Jiawang Hong

It is now widely recognized that surface and interfacial defects exhibit distinct behavior compared to bulk defects in metal halide perovskites. However, the transition from bulk to surface behavior and the spatial extent of the surface's…

材料科学 · 物理学 2024-12-23 Bilal Ahmad , Md Salman Rabbi Limon , Zeeshan Ahmad

Focused ion beam (FIB) techniques have been frequently used to section metal-halide perovskites for microstructural investigations. However, the ion beams directly irradiated to the sample surface may alter the properties far different from…

Non-radiative recombination processes are the biggest hindrance to approaching the radiative limit of the open-circuit voltage for wide-band gap perovskite solar cells. In addition, to high bulk quality, good interfaces and good energy…

材料科学 · 物理学 2021-02-09 Zhifa Liu , Johanna Siekmann , Benjamin Klingebiel , Uwe Rau , Thomas Kirchartz