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Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly-interacting environment, leading to the formation of discrete layers of charges at interfaces. Here, we propose a continuum theory that captures the…

Model macroion solutions next to a charged wall show interface \textit{true overcharging}, charge reversal and inversion, and layering. Macroion layering is present, even if the wall or the macroparticle are \textit{uncharged} or if the…

化学物理 · 物理学 2007-05-23 Marcelo Lozada-Cassou , Felipe Jimenez-Angeles

Distinct from familiar $s$-, $p$-, or $d$-wave pairings, the monopole superconducting order represents a novel class of pairing order arising from nontrivial monopole charge of the Cooper pair. In the weak-coupling regime, this order can…

超导电性 · 物理学 2024-11-26 Grayson R. Frazier , Junjia Zhang , Junyi Zhang , Xinyu Sun , Yi Li

A theory is constructed for dense ionic solutions near charged planar walls that is valid for strong inter-ionic correlations. This theory predicts a fluctuation-induced, first-order transition and spontaneous charge density ordering at the…

介观与纳米尺度物理 · 物理学 2016-06-24 David T. Limmer

A layered system of charges with logarithmic interaction parallel to the layers and random dipoles in each layer is studied via a variational method and an energy rationale. These methods reproduce the known phase diagram for a single layer…

无序系统与神经网络 · 物理学 2009-11-10 Baruch Horovitz , Pierre Le Doussal

We investigate the interplay between electronic screening inside a metal and screening by a polar molecular solvent, focusing on their impact on the charge induced by an ion and the solvent structure at the interface. To that end, we…

化学物理 · 物理学 2025-03-17 Swetha Nair , Guillaume Jeanmairet , Benjamin Rotenberg

Surface sensitive synchrotron x-ray scattering studies were performed to obtain the distribution of monovalent ions next to a highly charged interface. A lipid phosphate (dihexadecyl hydrogen-phosphate) was spread as a monolayer at the…

软凝聚态物质 · 物理学 2007-05-23 Wei Bu , David Vaknin , Alex Travesset

Dynamics of ionic-to-neutral and neutral-to-ionic phase transitions induced by intrachain charge-transfer photoexcitations are studied in a quasi-one-dimensional extended Hubbard model with alternating potentials and an electron-lattice…

强关联电子 · 物理学 2007-05-23 Kenji Yonemitsu

We present systematic ab initio calculations of the charge carrier correlations between adjacent layers of two-dimensional materials in the presence of both charged impurity and strain disorder potentials using the examples of monolayer and…

材料科学 · 物理学 2019-06-17 Martin-Isbjörn Trappe , Derek Y. H. Ho , Shaffique Adam

We study the deformation of a Fermi surface (FS) near charge-ordering (CO) transition. By applying a fluctuation-exchange approximation to the two-dimensional extended Hubbard model, we show that the FS is largely modified by strong charge…

材料科学 · 物理学 2011-11-28 Kazuyoshi Yoshimi , Takeo Kato , Hideaki Maebashi

The origin of the charge ordering in organic compounds $\theta$-(BEDT-TTF)$_2 X$ ($X=MM'$(SCN)$_4$, $M=$Tl,Rb,Co, $M'=$Cs,Zn) is studied using an extended Hubbard model. Calculating the charge susceptibility within random phase…

强关联电子 · 物理学 2009-11-11 Kazuhiko Kuroki

Triangular-lattice systems attract a lot of attention due to various frustration-induced and strongly correlated effects. Here, we focus on the charge-ordering phenomenon by means of investigation of the extended Hubbard model with…

强关联电子 · 物理学 2026-05-19 Aleksey Alekseev , Agnieszka Cichy , Konrad Jerzy Kapcia

A recent study revealed the dynamics of the charge sector of a one-dimensional quarter-filled electronic system with extended Hubbard interactions to be that of an effective pseudospin transverse-field Ising model (TFIM) in the strong…

强关联电子 · 物理学 2009-11-13 Siddhartha Lal , Mukul S. Laad

Understanding overcharging and charge inversion is one of the long-standing challenges in soft matter and biophysics. To study these phenomena, we employ the modified Gaussian renormalized fluctuation theory, which allows for the…

软凝聚态物质 · 物理学 2024-01-01 Nikhil R. Agrawal , Chao Duan , Rui Wang

The study of the electrical double layer lies at the heart of colloidal and interfacial science. The standard mean-field Poisson-Boltzmann (PB) theory is incapable of modeling many phenomena originated from ion correlation. An important…

软凝聚态物质 · 物理学 2022-09-26 Nikhil R. Agrawal , Rui Wang

Charge-order-driven ferroelectrics are an emerging class of functional materials, distinct from conventional ferroelectrics, where electron-dominated switching can occur at high frequency. Despite their promise, only a few systems…

材料科学 · 物理学 2020-02-19 Se Young Park , Karin M. Rabe , Jeffrey B. Neaton

We show that charge inversion, i.e. interfacial charges attracting counterions in excess of their own nominal charge, is a general effect that takes place in most charged systems next to aqueous solutions with multivalent ions and identify…

软凝聚态物质 · 物理学 2007-05-23 J. Faraudo , A. Travesset

We theoretically investigate an electric-field-driven system of charged spheres as a primitive model of concentrated electrolytes under an applied electric field. First, we provide a unified formulation for the stochastic charge and density…

软凝聚态物质 · 物理学 2025-01-15 Hiroshi Frusawa

Various phase transitions in models for coupled charge-density waves are investigated by means of the $\epsilon$-expansion, mean-field theory, and Monte Carlo simulations. At zero temperature the effective action for the system with…

强关联电子 · 物理学 2009-11-10 Minchul Lee , Eun-Ah Kim , Jong Soo Lim , M. Y. Choi

Ion bombardment has been shown to be capable of enhancing the interlayer exchange coupling in a trilayer system that exhibits giant magnetoresistance. We demonstrate that this phenomenon can be derived from the phase coherence among…

介观与纳米尺度物理 · 物理学 2015-05-19 Ching-Hao Chang , Tzay-Ming Hong
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