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We have probed the fragmentation dynamics in a bent triatomic molecule, water, a non-planar molecule, methanol, and a planar ring-structured molecule, benzene, using 100 fs duration pulses of linearly and circularly polarized, infrared,…

原子物理 · 物理学 2009-11-10 F A Rajgara , M Krishnamurthy , D Mathur

The laser-induced fragmentation dynamics of this most fundamental polar molecule HeH$^+$ are measured using an ion beam of helium hydride and an isotopologue at various wavelengths and intensities. In contrast to the prevailing…

化学物理 · 物理学 2018-08-21 P. Wustelt , F. Oppermann , Lun Yue , M. Möller , T. Stöhlker , S. Gräfe , M. Lein , G. G. Paulus , A. M. Sayler

The electronic and nuclear dynamics in methanol, following 156~nm photoexcitation, are investigated by combining a detailed analysis of time-resolved photoelectron spectroscopy experiments with electronic structure calculations. The…

We investigate dissociative single and double ionization of HeH+ induced by intense femtosecond laser pulses. By employing a semi-classical model with nuclear trajectories moving on field-dressed surfaces and ionization events treated as…

原子物理 · 物理学 2018-10-24 Lun Yue , Philipp Wustelt , A. Max Sayler , Gerhard G. Paulus , Stefanie Gräfe

We experimentally and theoretically investigated the deprotonation process on nanosecond to microsecond timescale in ethylene and acetylene molecules, following their double ionization by a strong femtosecond laser field. In our experiments…

Laser-driven rescattering of electrons is the basis of many strong-field phenomena in atoms and molecules. Here, we will show how this mechanism operates in extended atomic systems, giving rise to effective energy absorption. Rescattering…

原子与分子团簇 · 物理学 2008-04-07 Ulf Saalmann , Jan M. Rost

Energetic H$_2^+$ ions are formed as a result of intra-molecular rearrangement during fragmentation of linear alcohols (methanol, ethanol, propanol, hexanol, and dodecanol) induced by intense optical fields produced by 100 fs long,…

原子物理 · 物理学 2009-11-10 M. Krishnamurthy , F. A. Rajgara , D. Mathur

We study the breakup of $\text{H}_2^+$ exposed to super-intense, femtosecond laser pulses with frequencies greater than that corresponding to the ionization potential. By solving the time-dependent Schr\"odinger equation in an extensive…

原子物理 · 物理学 2016-04-12 Lun Yue , Lars Bojer Madsen

We study theoretically the photoelectron emission in noble gases using plasmonic enhanced near-fields. We demonstrate that these fields have a great potential to generate high energy electrons by direct mid-infrared laser pulses of the…

Nonradiative energy dissipation in electronically excited polyatomic molecules proceeds through conical intersections, loci of degeneracy between electronic states. We observe a marked enhancement of laser-induced double ionization in the…

We present a combined experimental and theoretical study on strong-field ionization of a three-dimensionally oriented asymmetric top molecule, benzonitrile (C$_7$H$_5$N), by circularly polarized, nonresonant femtosecond laser pulses. Prior…

We present experimental results on the ionization/dissociation of methane in femtosecond pulses of radiation. Angular and intensity dependent yields of singly and doubly charged species were measured using an imaging mass spectrometer. The…

原子物理 · 物理学 2015-06-18 J Strohaber , F Zhu , A A Kolomenskii , H A Schuessler

To realize efficient nonlinear metamaterials, we investigate a method for enhancing the local electric field in a metamolecule composed of two radiatively coupled cut-wire resonators where resonance of the cut-wire resonators and…

应用物理 · 物理学 2021-08-11 Yasuhiro Tamayama , Ryosuke Yamada

The presence of methyl alcohol or methanol (CH$_3$OH) in several astrophysical environments has been characterized by its high abundance that depends on both the production rate and the destruction rate. In the present work, the…

天体物理学 · 物理学 2008-11-26 S. Pilling , R. Neves , A. C. F. Santos , H. M. Boechat-Roberty

We present ab initio studies of photoelectron spectra for above threshold detachment (ATD) of F$^-$ anions in short, 1300 nm and 1800 nm laser pulses. We identify and assess the importance of electron rescattering in strong-field…

原子物理 · 物理学 2015-04-30 O. Hassouneh , S. Law , S. F. C. Shearer , A. C. Brown , H. W. van der Hart

We study the interaction of strong femtosecond laser pulses with the C$_{60}$ molecule employing time-dependent density functional theory with the ionic background treated in a jellium approximation. The laser intensities considered are…

原子与分子团簇 · 物理学 2009-11-07 D. Bauer , F. Ceccherini , A. Macchi , F. Cornolti

Recently, the extremely sensitive torsion-rotation transitions in methanol have been used to set a tight constraint on a possible variation of the proton-to-electron mass ratio over cosmological time scales. In order to improve this…

High-resolution photoelectron momentum distributions of Xe atoms ionized by 800-nm linearly polarized laser fields have been traced at intensities from 1.1*1013 to 3.5*1013W/cm2 using velocity-map imaging techniques. At certain laser…

原子物理 · 物理学 2015-12-09 Min Li , Peng Zhang , Siqiang Luo , Yueming Zhou , Qingbin Zhang , Pengfei Lan , Peixiang Lu

We present a novel approach to calculating strong field ionization dynamics of multielectron molecular targets. Adopting a multielectron wavefunction ansatz based on field-free ab initio neutral and ionic multielectron states, a set of…

原子物理 · 物理学 2015-05-14 Michael Spanner , Serguei Patchkovskii

In molecular photofragmentation processes by soft X-rays, a number of ionic fragments can be produced, each having a different abundance and correlation with the emitted electron kinetic energy. For investigating these fragmentation…

原子物理 · 物理学 2007-05-23 G. Pruemper , K. Ueda
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