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Charge transport layers (CTLs) are key components of diffusion controlled perovskite solar cells, however, they can induce additional non-radiative recombination pathways which limit the open circuit voltage (V_OC) of the cell. In order to…

Selecting suitable charge transport layers and suppressing non-radiative recombination at interfaces to the absorber layer are vital to maximize the efficiency of halide perovskite solar cells. In this work, high-quality perovskite thin…

Halide perovskite light absorbers have great advantages for photovoltaics such as efficient solar energy absorption, but charge accumulation and recombination at the interface with an electron transport layer (ETL) remains a major challenge…

Perovskite photovoltaics has witnessed an unprecedented increase in power conversion efficiency over the last decade. The choice of transport layers, through which photo-generated electrons and holes are transported to the electrodes, is a…

应用物理 · 物理学 2020-07-10 Eline M. Hutter , Thomas Kirchartz , Bruno Ehrler , David Cahen , Elizabeth von Hauff

The charge accumulation properties of p-i-n perovskite solar cells were investigated using three representative organic and inorganic hole transporting layer (HTLs): a) Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS, Al…

应用物理 · 物理学 2018-07-20 Fedros Galatopoulos , Achilleas Savva , Ioannis T. Papadas , Stelios A. Choulis

Perovskite solar cells (PSCs) are the fastest-growing photovoltaic (PV) technology in the solar cell community and have reached an efficiency close to that of commercial silicon (Si) solar cells. The organic-inorganic halide perovskite…

材料科学 · 物理学 2024-11-28 Kashimul Hossain

The extraction of photogenerated charge carriers and the generation of a photovoltage belong to the fundamental functionalities of any solar cell. These processes happen not instantaneously but rather come with finite time constants, e.g.,…

材料科学 · 物理学 2023-02-08 Lisa Krückemeier , Zhifa Liu , Thomas Kirchartz , Uwe Rau

Fundamental electronic processes such as charge-carrier transport and recombination play a critical role in determining the efficiency of hybrid perovskite solar cells. The presence of mobile ions complicates the development of a clear…

材料科学 · 物理学 2020-12-17 Sebastian Reichert , Katelyn Goetz , Christopher Wöpke , Yana Vaynzof , Carsten Deibel

Perovskite solar cells (PSCs) based on methylammonium lead iodide (MAPbI3) exhibit remarkable photovoltaic performance, where interface engineering with hole transport layers (HTLs) is crucial for optimizing charge transfer and device…

材料科学 · 物理学 2025-12-30 Somayyeh Alidoust , V. Ongun Özçelik

Charge carrier recombination in the perovskite solar cells (PSCs) has a deep influence on the electrical performance, such as open circuit voltage, short circuit current, fill factor and ultimately power conversion efficiency. The impacts…

介观与纳米尺度物理 · 物理学 2018-03-28 Lin Xing Shi , Zi Shuai Wang , Zengguang Huang , Wei E. I. Sha , Haoran Wang , Zhen Zhou

Hybrid organic-inorganic halide perovskites are low-cost solution-processable solar cell materials with photovoltaic properties that rival those of crystalline silicon. The perovskite films are typically sandwiched between thin layers of…

Interplays between charge and electric field, which play a critical role in determining the charge transport, recombination, storage and hysteresis in the perovskite solar cell, have been systematically investigated by both electrical…

材料科学 · 物理学 2017-10-31 Jiangjian Shi , Huiyin Zhang , Xin Xu , Dongmei Li , Yanhong Luo , Qingbo Meng

Using a representative translational dimer model, high throughput calculations are implemented for fast screening of a total of 74 diacenaphtho-extended heterocycle (DAH) derivatives as hole transport layer (HTL) materials in perovskite…

Interfaces between the perovskite active layer and the charge-transport layers (CTLs) play a critical role in both efficiency and stability of halide-perovskite photovoltaics. One of the major concerns is that surface defects of perovskite…

A model is derived for the frequency- and time-domain opto-electronic response of perovskite solar cells (PSCs) that emphasizes the role of charge carrier exchange, .i.e. extraction and injection, from (to) the perovskite through the…

材料科学 · 物理学 2023-11-10 Sandheep Ravishankar , Zhifa Liu , Yueming Wang , Thomas Kirchartz , Uwe Rau

Organic-inorganic lead halide perovskites containing a mixture of iodide and bromide anions consistently perform better in donor-acceptor heterojunction solar cells than the standard methylammonium lead triiodide material. This observation…

We compare three representative high performance PV materials: halide perovskite MAPbI3, CdTe, and GaAs, in terms of photoluminescence (PL) efficiency, PL lineshape, carrier diffusion, and surface recombination, over multiple orders of…

Perovskite semiconductors have demonstrated outstanding external luminescence quantum yields, enabling high power conversion efficiencies (PCE). However, the precise conditions to advance to an efficiency regime above monocrystalline…

While transient photoluminescence measurements are a very popular tool to monitor the charge-carrier dynamics in the field of halide perovskite photovoltaics, interpretation of data obtained on multilayer samples is highly challenging due…

材料科学 · 物理学 2021-02-18 Lisa Krückemeier , Benedikt Krogmeier , Zhifa Liu , Uwe Rau , Thomas Kirchartz

In perovskite solar cells (PSCs) energy levels alignment and charge extraction at the interfaces are the essential factors directly affecting the device performance. In this work, we present a modified interface between all-inorganic…

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