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相关论文: Epitaxial Growth of Rutile GeO$_2$ via MOCVD

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Rutile Germanium Dioxide (GeO2) has been recently theoretically identified as an ultrawide bandgap (UWBG) semiconductor with bandgap 4.68 eV similar to Ga2O3 but having bipolar dopability and ~2x higher electron mobility, Baliga figure of…

材料科学 · 物理学 2024-05-14 Imteaz Rahaman , Hunter D. Ellis , Kathy Anderson , Michael A. Scarpulla , Kai Fu

Rutile germanium dioxide (r-GeO$_2$) is a promising ultra-wide bandgap (UWBG) semiconductor, offering a high theoretical Baliga figure of merit, potential for p-type doping, and favorable thermal and electrical properties. In this work, we…

材料科学 · 物理学 2025-08-05 Imteaz Rahaman , Anthony Bolda , Botong Li , Hunter D. Ellis , Kai Fu

Rutile germanium dioxide (r-GeO2) has recently emerged as a promising ultrawide-bandgap (UWBG) semiconductor owing to its wide bandgap (~4.4-5.1 eV), ambipolar doping potential, and high theoretical thermal conductivity. However,…

Ultrawide bandgap (UWBG) semiconductors are promising for next-generation power electronics, largely attributed to their substantial bandgap and exceptional breakdown electric field. Rutile GeO2 (r-GeO2) emerges as a promising alternative,…

材料科学 · 物理学 2024-10-18 Imteaz Rahaman , Botong Li , Hunter D. Ellis , Brian Roy Van Devener , Randy C Polson , Kai Fu

Rutile germanium oxide (r-GeO2) has shown potential for ultrawide bandgap semiconductor applications such as power conversion and UV optoelectronics. Homoepitaxial substrates will be key for achieving phase pure and doped r-GeO2 thin films…

材料科学 · 物理学 2026-04-07 Avery-Ryan Ansbro , John T. Heron

Rutile germanium dioxide (r-GeO2) is an ultra-wide bandgap semiconductor with potential for ambipolar doping, making it a promising candidate for next-generation power electronics and optoelectronics. Growth of phase-pure r-GeO2 films by…

Germanium dioxide (r-GeO2) is an emerging new ultrawide bandgap (UWBG) semiconductor with significant potential for power electronics, thanks to its large-size substrate compatibility and ambipolar doping capability. However, phase…

材料科学 · 物理学 2025-06-12 Imteaz Rahaman , Botong Li , Bobby Duersch , Hunter D. Ellis , Kai Fu

Rutile germanium dioxide (r-GeO$_2$) is a recently predicted ultrawide-band-gap semiconductor with potential applications in high-power electronic devices, for which the carrier mobility is an important material parameter that controls the…

材料科学 · 物理学 2020-11-10 Kyle Bushick , Kelsey A. Mengle , Sieun Chae , Emmanouil Kioupakis

Ultra-wide-band-gap (UWBG) semiconductors have tremendous potential to advance electronic devices as device performance improves superlinearly with increasing gap. Ambipolar doping, however, has been a major challenge for UWBG materials as…

材料科学 · 物理学 2019-03-15 Sieun Chae , Jihang Lee , Kelsey A. Mengle , John T. Heron , Emmanouil Kioupakis

Ultrawide-bandgap (UWBG) semiconductors, such as GeO$_2$, are gaining significant attention for their potential in high-performance applications, particularly in piezoelectric devices. Despite extensive research, a comprehensive…

材料科学 · 物理学 2025-06-12 Botong Li , Imteaz Rahaman , Hunter Ellis , Bobby G. Duersch , Kathy Anderson , Kai Fu

Rutile GeO2 has been predicted to be an ultra-wide bandgap semiconductor suitable for future power electronics devices while quartz-like GeO2 shows piezoelectric properties. To explore these crystalline phases for application and…

Two-dimensional crystals are an important class of materials for novel physics, chemistry, and engineering. Germanane (GeH), the germanium-based analogue of graphane (CH), is of particular interest due to its direct band gap and spin-orbit…

Ultrawide-band-gap (UWBG) semiconductors are promising for fast, compact, and energy-efficient power-electronics devices. Their wider band gaps result in higher breakdown electric fields that enable high-power switching with a lower energy…

材料科学 · 物理学 2021-08-11 S. Chae , K. A. Mengle , K. Bushick , J. Lee , N. Sanders , Z. Deng , Z. Mi , P. F. P. Poudeu , H. Paik , J. T. Heron , E. Kioupakis

A seemingly simple oxide with a rutile structure, RuO2 has been shown to possess several intriguing properties ranging from strain-stabilized superconductivity to a strong catalytic activity. Much interest has arisen surrounding the…

Rutile GeO$_2$ is a visible and near-ultraviolet-transparent oxide that has not been explored for semiconducting applications in electronic and optoelectronic devices. We investigate the electronic and optical properties of rutile GeO$_2$…

材料科学 · 物理学 2019-08-27 Kelsey A. Mengle , Sieun Chae , Emmanouil Kioupakis

Germanium-based oxides such as rutile GeO2 are garnering attention owing to their wide band gaps and the prospects for ambipolar doping for application in high-power devices. Here, we present the use of germanium tetraisopropoxide (GTIP)…

GeO$_2$ has an $\alpha$-quartz-type crystal structure with a very wide fundamental band gap of 6.6 eV and is a good insulator. Here we find that the stable rutile-GeO$_2$ polymorph with a 4.6 eV band gap has a surprisingly low $\sim$6.8 eV…

材料科学 · 物理学 2020-11-19 Christian A. Niedermeier , Keisuke Ide , Takayoshi Katase , Hideo Hosono , Toshio Kamiya

Metal organic chemical vapor deposition (MOCVD) is one of the main methodologies used for thin film fabrication in the semiconductor industry today and is considered one of the most promising routes to achieve large-scale and high-quality…

Rutile GeO$_2$ is a promising ultra-wide bandgap semiconductor for future power electronic devices whose alloy with the wide bandgap semiconductor rutile-SnO$_2$ enables bandgap engineering and the formation of heterostructure devices. The…

Recently, Bi2O2Se is discovered as a promising two-dimensional (2D) semiconductor for next generation electronics, due to its moderate bandgap size, high electron mobility and pronounced ambient stability. Meanwhile, it has been predicted…

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