相关论文: Multiphase buffering by ammonia sustains sulfate p…
Despite surface liquid water's importance to habitability, observationally diagnosing its presence or absence on exoplanets is still an open problem. Inspired within the Solar System by the differing sulfur cycles on Venus and Earth, we…
Molecular oxygen, O$_2$, is vital to life on Earth and possibly on other planets. Although the biogenic processes leading to its accumulation in Earth's atmosphere are well understood, its abiotic origin is still not fully established.…
Sulfur-water chemistry plays an important role in the middle atmosphere of Venus. Ground based observations have found that simultaneously observed SO2 and H2O at ~64 km vary with time and are temporally anti-correlated. To understand these…
Fundamental inorganic chemistry shows that increasing concentrations of atmospheric CO2 will have no harmful effect on organisms that live in the natural waters of the Earths, and may well benefit them. Alkalinity and dissolved CO2 give…
The atmosphere of Venus remains mysterious, with many outstanding chemical connundra. These include: the unexpected presence of ~10 ppm O2 in the cloud layers; an unknown composition of large particles in the lower cloud layers; and hard to…
While largely studied on the macroscopic scale, the dynamics leading to nucleation and fission processes in atmospheric aerosols are still poorly understood at the molecular level. Here, we present a joint experimental-theoretical study of…
Organic aerosols (OA) comprise a major fraction of atmospheric particulate matter and frequently contain acidic species, yet their contribution to overall aerosol acidity has not been explicitly considered in global climate models. We…
Sulfur is an abundant element in the cosmos and it is thus an important contributor to astrochemistry in the interstellar medium and in the Solar System. Astronomical observations of the gas and of the solid phases in the dense…
New routes for transforming nitrogen into ammonia at ambient conditions would be a milestone toward an energy efficient and economically attractive production route in comparison to the traditional Haber-Bosch process. Recently, the…
Phosphorus is an essential element for life, and the phosphorous cycle is widely believed to be a key factor limiting the extent of Earth's biosphere and its impact on remotely detectable features of Earth's atmospheric chemistry.…
We have developed the first gas-grain chemical model for oxygen fractionation (also including sulphur fractionation) in dense molecular clouds, demonstrating that gas-phase chemistry generates variable oxygen fractionation levels, with a…
Sulfur-bearing species play crucial roles in atmospheric physical-chemical processes, atmosphere-surface interactions, and the geological evolution of Venus. This chapter provides a comprehensive overview of (1) instrumental data on the…
The key kinetic barrier to dolomite formation is related to the surface Mg2+-H2O complex, which hinders binding of surface Mg2+ ions to the CO3 2- ions in solution. It has been proposed that this reaction can be catalyzed by dissolved…
Organic material in anoxic sediment represents a globally significant carbon reservoir that acts to stabilize Earth's atmospheric composition. The dynamics by which microbes organize to consume this material remain poorly understood. Here…
The Sun exhibits a depletion in $^{17,18}$O relative to $^{16}$O by 6 % compared to the Earth and Moon$^{1}$. The origin of such a non-mass-dependent isotope fractionation has been extensively debated since the three-isotope-analysis$^{2}$…
Heterogeneous nucleation and subsequent growth of surface water occur on the natural substrate when the water vapor concentration reached the point of super-saturation. This study focuses on the parameterization of super-saturation on the…
In the framework of the model inter-comparison study - Asia Phase II (MICS2), where eight models are compared over East Asia, this paper studies the influence of different parameterizations used in the aerosol module on the aerosol…
Aerosol opacity has emerged as a critical factor controlling transmission and emission spectra. We provide a simple guideline for the effects of aerosol morphology on opacity and residence time in the atmosphere, as it pertains to transit…
Harvesting organic matter from wastewater is widely applied to maximize energy recovery; however, it limits the applicability of secondary treatment for acceptable effluent discharge into surface water bodies. To turn this bottleneck issue…
Underground storage of hydrogen and ammonia in geological formations is essential for renewable energy integration, but salt precipitation during gas injection may threaten storage performance. While extensively studied for CO2 systems,…