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The ability to minimize the thermal conductivity of dielectrics with minimal structural intervention that could affect electrical properties is an important capability for engineering thermoelectric efficiency in low-cost materials such as…

Prevailing nanostructuring strategies focus on increasing phonon scattering and reducing the mean-free-path of phonons across the spectrum. In nanoporous Si materials, for example, boundary scattering reduces thermal conductivity…

介观与纳米尺度物理 · 物理学 2020-12-02 Laura de Sousa Oliveira , S. Aria Hosseini , Alex Greaney , Neophytos Neophytou

Nanostructuring on length scales corresponding to phonon mean free paths provides control over heat flow in semiconductors and makes it possible to engineer their thermal properties. However, the influence of boundaries limits the validity…

Boundary-engineering in nanostructures has the potential to dramatically impact the development of materials for high-efficiency conversion of thermal energy directly into electricity. In particular, nanostructuring of semiconductors can…

材料科学 · 物理学 2016-10-04 Giuseppe Romano , Alexie M. Kolpak

Computationally efficient modeling of the thermal conductivity of materials is crucial to thorough experimental planning and theoretical understanding of thermal properties. We present a modeling approach in this work that utilizes…

介观与纳米尺度物理 · 物理学 2017-09-28 Long Chen , Jeffrey L. Braun , Brian F. Donovan , Patrick E. Hopkins , S. Joseph Poon

Achieving low thermal conductivity and good electrical properties is a crucial condition for thermal energy harvesting materials. Nanostructuring offers a very powerful tool to address both requirements: in nanostructured materials,…

介观与纳米尺度物理 · 物理学 2018-09-14 Giuseppe Romano , Jesús Carrete , Alexie M. Kolpak , David Broido

Tailoring thermal properties with nanostructured materials can be of vital importance for many applications. Generally classical phonon size effects are employed to reduce the thermal conductivity, where strong phonon scattering by…

应用物理 · 物理学 2019-10-14 Yue Xiao , Qiyu Chen , Dengke Ma , Nuo Yang , Qing Hao

Nanostructured semiconducting alloys obtain ultra-low thermal conductivity as a result of the scattering of phonons with a wide range of mean-free-paths (MFPs). In these materials, long-MFP phonons are scattered at the nanoscale boundaries…

This review summarizes recent studies of thermal transport in nanoscaled semiconductors. Different from bulk materials, new physics and novel thermal properties arise in low dimensional nanostructures, such as the abnormal heat conduction,…

介观与纳米尺度物理 · 物理学 2013-01-14 Nuo Yang , Xiangfan Xu , Gang Zhang , Baowen Li

In nanostructures phonon transport behaviour is distinctly different to transport in bulk materials such that materials with ultra low thermal conductivities and enhanced thermoelectric performance can be realized. Low thermal…

材料科学 · 物理学 2019-03-01 Dhritiman Chakraborty , Samuel Foster , Neophytos Neophytou

Introducing hierarchical disorder from multiple defects into materials through nanostructuring is one of the most promising directions to achieve extremely low thermal conductivities and thus improve thermoelectric performance. The success…

材料科学 · 物理学 2019-09-16 Laura de Sousa Oliveira , Vassilios Vargiamidis , Neophytos Neophytou

Nanostructured materials exhibit low thermal conductivity because of the additional scattering due to phonon-boundary interactions. As these interactions are highly sensitive to the mean free path (MFP) of a given phonon mode, MFP…

材料科学 · 物理学 2016-01-13 Giuseppe Romano , Keivan Esfarjani , David A. Strubbe , David Broido , Alexie M. Kolpak

Thermal conductivity measurements over variable lengths on nanostructures such as nanowires provide important information about the mean free paths (MFPs) of the phonons responsible for heat conduction. However, nearly all of these…

介观与纳米尺度物理 · 物理学 2015-02-23 Hang Zhang , Chengyun Hua , Ding Ding , Austin J. Minnich

Boundary scattering in hierarchically disordered nanomaterials is an effective way to reduce the thermal conductivity of thermoelectric materials and increase their performance. In this work we investigate thermal transport in silicon based…

材料科学 · 物理学 2019-02-27 Dhritiman Chakraborty , Laura de Sousa Oliveira , Neophytos Neophytou

It has been proposed for a long time now that the reduction of the thermal conductivity by reducing the phonon mean free path is one of the best way to improve the current performance of thermoelectrics. By measuring the thermal conductance…

At micro- to nano-scales, classical size effects in heat conduction play an important role in suppressing the thermal transport process. Such effects occur when the characteristic lengths become commensurate to the mean free paths (MFPs) of…

应用物理 · 物理学 2019-05-08 Qing Hao , Yue Xiao , Qiyu Chen

Tuning thermal transport in nanostructured materials is a powerful approach to develop high-efficiency thermoelectric materials. Using a recently developed approach based on the phonon mean free path dependent Boltzmann transport equation,…

介观与纳米尺度物理 · 物理学 2015-06-22 Giuseppe Romano , Jeffrey C. Grossman

Nanoporous materials are of broad interest for various applications, in particular advanced thermoelectric materials. The introduction of nanoscale porosity, even at modest levels, has been known to drastically reduce a materials thermal…

介观与纳米尺度物理 · 物理学 2019-07-31 Laura de Sousa Oliveira , Neophytos Neophytou

Thermoelectric materials convert heat into electricity through thermally driven charge transport in solids, or vice versa for cooling. To be competitive with conventional energy-generation technologies, a thermoelectric material must…

Nanostructured semiconducting materials are promising candidates for thermoelectrics due to their potential to suppress phonon transport while preserving electrical properties. Modeling phonon-boundary scattering in complex geometries is…

材料科学 · 物理学 2017-10-02 Giuseppe Romano , Alexie M. Kolpak
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